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Paired electrolysis offers an auspicious strategy for the generation of high‐value chemicals, at both the anode and cathode, in an integrated electrochemical reactor. Through efficient electron utilization, routine product misuse at overlooked electrodes can be prevented. Here, an original paired electrosynthetic system is reported that can convert CO2 to ethylene (C2H4) at the cathode, and water to hydrogen peroxide (H2O2) at the anode under a single pass of electric charge. Amongst various investigated copper (Cu) nanomorphologies, the bespoke mixed Cu nanowire/nanoparticle catalyst recorded a peak C2H4 Faraday efficiency (FE) of 60% following 370 h of electrolysis at 200 mA cm−2, while the tailored boron‐doped diamond (BDD) anode accumulated an unprecedented ≈1% w/w of H2O2 in 4 m K2CO3 upon applying 300 mA cm−2 for 10 h. When paired, the dual C2H4‐H2O2 electrochemical cell attains a combined FE of 120% for 50 h at 200 mA cm−2, a combined energy efficiency (EE) of 69%, and a 50% decrease in the overall electrical energy consumption (EEC) compared to the individual electrosynthesis of C2H4 and H2O2. [ABSTRACT FROM AUTHOR]

The electrochemical reduction of CO2 continues to see significant interest as a viable means of both producing important chemical materials and lowering carbon emissions. The primary challenge to making this process economically viable is the design of catalyst, electrode and reactor components that can selectively produce just one of the many possible CO2 reduction products. In this work, we report the use of hydrophobic 1-octadecanethiol coatings at copper coated gas diffusion electrodes to enhance the production of ethylene. This thiol coating gives a substantial increase in the production of ethylene at low current densities as well as a change in the rate determining step, as indicated by the substantial reduction in the Tafel slope. The observed changes to the CO2 reduction reaction indicate that the thiol layer provides a triphasic interface within the gas diffusion electrode catalyst layer. [ABSTRACT FROM AUTHOR]

We report for the first time on the impact of a printed indium tin oxide (ITO) layer inserted between a printed silver conductor and solution processed zinc oxide (ZnO) leading to an optimized semiconductor/contact scheme for full print integration. Introducing the ITO interlayer, the contact resistance is reduced by two orders of magnitude. Nanoparticle thin-film transistors (TFTs) in this Ag/ITO contact configuration show improved saturation mobility of 0.53 \cm^2\cdot \V ^-1 \cdot\s ^-1 with respect to 0.08 \cm^2 \cdot\V ^-1 \cdot\s ^-1 without ITO interlayer. The contact improvement can be attributed to either an increased charge carrier concentration or a reduction of band offsets at the ZnO/electrode interface. [ABSTRACT FROM PUBLISHER]

Energy services are especially expensive on remote islands due to longer and more unstable fuel supply chains. In this paper, different renewable energy systems utilizing locally available biomass and solar energy are proposed as alternatives for a hotel resort on Neil Island, India. Based on local demand data, commercial information, and scientific literature, four cases are modelled with the simulation software HOMER and their economic, energetic, as well as ecological (3E) performances are compared. The robustness of each case configuration is tested with a sensitivity analysis. The results show that a biomass-based, solar-assisted combined cooling, heating, and power (CCHP) system offers an economic saving potential of more than 500,000 USD over twenty years and could decrease CO2 emissions by 365 t per year. When not applying CCHP measures, system performance is significantly worsened. A solar and battery-assisted diesel generator system shows similar economic outcomes as the CCHP system but worse ecological performance. Implementing the biomass-based CCHP system could improve the ecological footprint of the island, substantially decrease expenditure for the hotel owner, and generate a new source of income for surrounding farmers through biomass selling. [ABSTRACT FROM AUTHOR]

CO 2 reduction offers an attractive alternative green synthetic route for ethylene, especially where CO 2 could be sourced from industrial exhausts and in combination with green power sources. However, practical applications are currently limited due to the unfortunately low selectivity of cathode materials towards ethylene. This work uses polymers with intrinsic microporosity (PIMs) to improve the performance of copper gas diffusion electrodes for CO 2 reduction to ethylene. We report an improved selectivity and activity towards ethylene with the addition of a thin PIMs layer, which is seen as improved Faradaic efficiency, increased stability and a shift in the reduction to lower overpotential. This improvement is highly dependent on the thickness of the added polymer layer, with too thick a layer having a detrimental impact on the hydrophobicity of the gas diffusion layer. With a compromise in loading, PIMs can be used to enhance the activity and selectivity of catalysts for targeted CO 2 reduction to ethylene. Image 10694 • Gas diffusion electrodes allow CO 2 reduction to ethylene, but selectivity is low. • Polymers with intrinsic microporosity can increase ethylene production. • Using too much polymer has a detrimental impact. • A compromise polymer thickness increases ethylene yield and electrode stability. [ABSTRACT FROM AUTHOR]