1. Understanding the near-field photoacoustic spatiotemporal profile from nanostructures
- Author
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Hanwei Wang, Yun-Sheng Chen, and Yang Zhao
- Subjects
Gold nanostructures ,Nanoparticles ,Photoacoustics ,Photothermal effect ,Anisotropy ,Nano-transducer ,Physics ,QC1-999 ,Acoustics. Sound ,QC221-246 ,Optics. Light ,QC350-467 - Abstract
Understanding the mechanism of photoacoustic generation at the nanoscale is key to developing more efficient photoacoustic devices and agents. Unlike the far-field photoacoustic effect that has been well employed in imaging, the near-field profile leads to a complex wave-tissue interaction but is understudied. Here we show that the spatiotemporal profile of the near-field photoacoustic waves can be shaped by laser pulses, anisotropy, and the spatial arrangement of nanostructure(s). Using a gold nanorod as an example, we discovered that the near-field photoacoustic amplitude in the short axis is ∼75 % stronger than the long axis, and the anisotropic spatial distribution converges to an isotropic spherical wave at ∼50 nm away from the nanorod's surface. We further extend the model to asymmetric gold nanostructures by arranging isotropic nanoparticles anisotropically with broken symmetry to achieve a precisely controlled near-field photoacoustic ''focus'' largely within an acoustic wavelength.
- Published
- 2022
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