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• Power-to-gas has a strong potential in the transition to a renewable network. • Advanced CO 2 capture process allows to reduce the energy consumption. • Heat integration improves the competitiveness of the global Power-to-Gas chain. • Attractiveness of Power-to-gas is economically sensitive to electricity cost. The Power-to-Gas strategy has become a mainstream topic for decarbonization and development of renewables and flexibility in energy systems. One of the key arguments for decarbonizing the gas network is to take advantage of existing network infrastructure, gradually transitioning to lower fossil carbon sources of methane from Power-to-Gas. This work proposes the techno-economic investigation of an integrated system considering an advanced CO 2 capture process, in terms of solvent and process configuration, to treat about 10% of a cement plant's flue gas and convert the captured CO 2 into synthetic natural gas using renewable hydrogen generated from a large-scale wind powered electrolyzer. An optimized heat recovery system is proposed, drastically decreasing the external hot utility demand of the CO 2 capture unit. In addition, it leads to the production of complementary electricity (about 1.06 MW), reducing thus also the electrical demand of the integrated process. The synthetic natural gas produced has a composition (CH 4 92.9 mol.%, CO 2 3.7 mol.%, and H 2 3.4 mol.%) and a Wobbe index (46.72 MJ/m3), corresponding to specification for gas grid injection at 50 bar in Germany. With an overall system efficiency of 72.6%, the process produces 0.40 ton synthetic natural gas per ton of captured CO 2. The cost of the synthetic natural gas produced is higher when compared to the present natural gas market price, but cost reductions and possible commercial use of coproducts like oxygen, represent a likely alternative. Costs are mainly driven by high capital investments (the electrolyzer), and the price of renewable electricity, which is expected to decrease in the coming years. [ABSTRACT FROM AUTHOR]

Direct Air Capture (DAC) technologies are gaining interest in the concept of carbon utilization and Power-to-Gas (PtG), as the economic valorization of the CO 2 into methane provides a viable pathway to allow DAC systems to mature. However, research on DAC mainly focuses on isolated systems, and the system performance depends on parameters that are highly uncertain. To study the integration of DAC in PtG, we developed a DAC-PtG model, performed an Energy, Exergy, Economic and Environmental (4E) analysis and implemented uncertainty quantification to consider the uncertain environment. The results illustrate that the DAC-PtG system is autothermal when introducing a two-stage mechanical vapor recompression unit at the DAC outlet. The exergy efficiency ranges between 51.3% and 52.6% within 3 standard deviations, for which the uncertainty is driven by the ambient conditions and the uncertain heat of desorption. The methane issued from DAC-PtG has a lower carbon footprint than fossil methane when the carbon footprint of the electricity supply is below or equal to 0.12 kg˙CO˙2-eq /kWh. The Levelized Cost of Synthetic Natural Gas (LCSNG) ranges between 130 €/ MWh and 744 €/ MWh, following an uncertain electricity price and uncertain expenses related to DAC and electrolysis. Therefore, bulk manufacturing, further maturing of these technologies and more demonstration projects are required to reduce the uncertainty of the LCSNG. Future works will consider intermittent renewable energy sources to supply power. • Integrated direct air capture and CO 2 methanation are investigated. • Exergy efficiency ranges between 51.3% and 52.6% within three standard deviations. • The levelized cost of synthetic natural gas ranges between 130 €/MWh and 744 €/MWh. • Electricity emission intensity below 0.12 kg CO2-eq /kWh results in carbon reduction. • To reduce uncertainty, bulk manufacturing and more pilot projects are needed. [ABSTRACT FROM AUTHOR]