1. Reaction Mechanisms of Well‐Defined Metal–N4 Sites in Electrocatalytic CO2 Reduction.
- Author
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Zhang, Zheng, Xiao, Jianping, Chen, Xue‐Jiao, Yu, Song, Yu, Liang, Si, Rui, Wang, Yong, Wang, Suheng, Meng, Xianguang, Wang, Ye, Tian, Zhong‐Qun, and Deng, Dehui
- Subjects
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ELECTROCATALYSTS , *CARBON dioxide , *METAL phthalocyanines , *PHTHALOCYANINES , *FARADAIC current - Abstract
Electrocatalytic CO2 reduction to CO emerges as a potential route of utilizing emitted CO2. Metal‐N‐C hybrid structures have shown unique activities, however, the active centers and reaction mechanisms remain unclear because of the ambiguity in true atomic structures for the prepared catalysts. Herein, combining density‐functional theory calculations and experimental studies, the reaction mechanisms for well‐defined metal–N4 sites were explored using metal phthalocyanines as model catalysts. The theoretical calculations reveal that cobalt phthalocyanine exhibits the optimum activity for CO2 reduction to CO because of the moderate *CO binding energy at the Co site, which accommodates the *COOH formation and the *CO desorption. It is further confirmed by experimental studies, where cobalt phthalocyanine delivers the best performance, with a maximal CO Faradaic efficiency reaching 99 %, and maintains stable performance for over 60 hours. To the "CO2RR": Metal phthalocyanines (MePcs) with well‐defined metal–N4 structures were used as model catalysts to study the active centers and reaction mechanisms for the electrocatalytic CO2 reduction reaction (CO2RR). Theoretical and experimental studies identify CoPc as the optimum catalyst for the selective electrocatalytic CO2RR to deliver CO. The Co site serves as the active center for achieving a Faradaic efficiency (FE) of up to 99 % with long‐term stability. [ABSTRACT FROM AUTHOR]
- Published
- 2018
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