Search

The Intergovernmental Panel on Climate Change (IPCC), which is the United Nations body for assessing the science related to climate change, has recently recognized the natural carbonation process as a way of carbon offsetting with mortar and concrete. Accordingly, this activity could be recognized as a carbon removal process for which certification should be granted. The aim of the certification of carbon removal is to promote the development of adequate and efficient new carbon removal processes. Therefore, the main objective of this study is to provide reliable results on carbon dioxide uptake by cement-based materials in Spain. Yearly, greenhouse gas emissions are reported to the United Nations Framework Convention on Climate Change (UNFCCC) by each country, and the natural carbonation should be added up to the carbon accounting. Therefore, natural carbonation should be included in the IPCC Guidelines for National Greenhouse Gas Inventories, and such accounting information should be made available promptly to the national regulatory authorities. This paper provides the results of carbon dioxide uptake by Spanish cement-based materials from 1990 to 2020 by using an easy method of estimating the net carbon dioxide emissions (simplified method) considering the carbon dioxide released by the calcination during clinker production (process emissions). The outcome of this study reveals that there was 93,556,000 tons of carbon dioxide uptake by the mortar and concrete manufactured in Spain from 1990 to 2020. [ABSTRACT FROM AUTHOR]

The knowledge of the soil variability is essential for its hydrologic characterization, for irrigation management and planning and especially for water movement modeling. Nevertheless, the scarcity of soil information in Spain precludes its use in irrigation management and, particularly, in the on-going irrigation modernization process. The Violada Irrigation District (VID) comprises 5234 ha and is located in a semi-arid gypsum-rich region in northeast Spain. VID has been under flood irrigation since the mid-20th Century and has been modernized recently to sprinkler irrigation. Since the early 1980s water balances in VID have been based on average soil properties and bulk irrigation data. The current irrigation system provides detailed irrigation data at plot level, thus allowing for performing distributed balances (in hydrologic homogenous zones) that require detailed or semi-detailed soil information in the form of a soil map. The objective of this two-part study is to define homogeneous zones in relation to hydrological properties relevant for irrigation management, first defining the soil variability within the VID and then analyzing the soils hydrologic and salinity features (in a companion paper). The specific objectives of this paper were (i) to draw the VID semi-detailed soil map; (ii) to explain the variability of soil properties; and (iii) to map the main soil characteristics related to irrigation management. Thirty four soil pits, located on all the different geomorphological areas, were opened and described. Samples were taken from all the horizons and analyzed for chemical and physical properties. The limits of soil units were drawn with the aid of 32 additional auger holes, the data from 72 pits opened during the irrigation transformation works, and all the previous soil information available. Finally the soils were classified down to family level. The main soil formation processes in VID were carbonation and gypsification. Thirteen soil units were defined, included in five soil subgroups and six particle size families. “Fine” particle sizes were dominant along the gypsum-rich valley bottoms. Coarser textures were found on the heights and showed higher CaCO 3 equivalent content and no presence of gypsum accumulations. A priori, the main limitation for irrigation in the valley soils was the limited drainage (due to fine textures and reduced slope) while in the highland soils it might be constrained by their low retention capacity. The high gypsum and carbonate content of the VID soils may prevent the development of infiltration problems. The soil properties map in this work will be the basis for a companion paper delineating the hydrologic properties of the soils, the basis for improved soil water balances. [ABSTRACT FROM AUTHOR]