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Ce,Tb,Gd:YAG-Al 2 O 3 eutectic crystal phosphor plates (ECPPs) were grown by the micro-pulling-down (μ-PD) method to adjust correlated color temperature (CCT) and color rendering index (Ra) for high-power warm white LED applications. Tb3+ and Gd3+ ions in Ce:YAG-Al 2 O 3 play a positive role in spectra adjustment based on the structural and luminescent properties investigations. Tb3+ ions enhance the fluorescence lifetime of Ce3+ ions from 61.1 to 63.8 ns and improve the luminescence efficiency, and the highest optical-optical conversion efficiency (OCE) is 270.56 lm/W. Corresponding luminescence shift from cold white to greenish yellow. Gd3+ ions increase the peak wavelength from 554 to 564 nm and improve the Ra value, and the maximum Ra is 75.5. Corresponding luminescence is shifted from cold white to reddish violet. In addition, the luminescence of Ce,Tb,Gd:YAG-Al 2 O 3 ECPPs is adjusted to warm white with CIE coordinate (0.374, 0.364) and CCT of 4102 K, and Ra of 73.0, which is of great significance for realizing the high-power warm white LED lighting. • Tb3+ ions increased the fluorescence lifetime of Ce3+ ions by ∼17%， and improved the luminescence efficiency with the highest OCE of 270.56 lm/W. And Gd3+ ions increased the peak wavelength of emission from 554 nm to 564 nm and improved the Ra from 65.5 to 75.5. • The Ce,Tb,Gd:YAG-Al 2 O 3 ECPP has excellent performance with a low CCT of ∼4100 K and a CIE coordinate of (0.374, 0.364). • The CRI of Ce,Tb,Gd:YAG-Al 2 O 3 ECPP reached 73.0. [ABSTRACT FROM AUTHOR]

• A series of 0.6 at% Pr:CaF 2 -RF 3 (R= Y3+, Gd3+, Lu3+) crystals were successfully grown by the temperature gradient technique(TGT) method. • By co-doping R3+ ion (R=Y3+, Gd3+, Lu3+), the spectral performance of the crystals could be significantly improved and the function effect is also different. • The spectral performance and spectral quality factor of the crystals were systematically described and compared for the first time. • The spectral modulation effect caused by Y3+, Gd3+ and Lu3+ co-doping ion was discussed. A series of 0.6 at% Pr:CaF 2 -RF 3 (R = Y3+, Gd3+, Lu3+) crystals have been successfully grown by the temperature gradient technique(TGT). The absorption spectra, fluorescence spectra, and fluorescence decay curves were measured and analyzed at room temperature. When the R3+ concentration is higher than a certain value, the diffraction peaks of Pr:CaF 2 -RF 3 crystals were well indexed to the (Ca,Y)F 2 phase. By co-doping R3+ ion (R=Y3+, Gd3+, Lu3+), the spectral performance of the crystals could be significantly improved and the function effect is also different. For 0.6 at% Pr, 28.5 at% Y:CaF 2 crystal, the fluorescence lifetime of 3P 0 energy level was fitted to be 45.46 µs, and the emission cross sections of 3P 0 →3H 6 (605 nm), and 3P 0 →3F 2 (641 nm) were calculated to be 1.78 × 10−20 cm2, and 4.61 × 10−20 cm2 with the full width at half (FWHM) of 20.1 nm and 6.8 nm, respectively. The 0.6 at% Pr, 28.5 at% Y:CaF 2 crystal could be favorble laser medium for ultra-fast laser opreration at 605 nm and 641 nm. For 0.6 at% Pr, 18 at% Gd:CaF 2 and 0.6 at% Pr, 10 at% Lu:CaF 2 crystals, the spectral quality factors σ em• τ f of 3P 0 →3F 2 transition (642 nm) were calculated to be 614.18 × 10−20 cm2•µs and 506.36 × 10−20 cm2•µs with the FWHM of 3.7 nm and 5.3 nm. All the results show that 0.6 at% Pr, 18 at% Gd:CaF 2 and 0.6 at% Pr, 10 at% Lu:CaF 2 crystals are promising gain media for high-efficiency visible laser output at 642 nm, which would compete with commercial Pr: YLF crystal in the future. [ABSTRACT FROM AUTHOR]

Yb,Pr:CaF 2 crystals have been grown successfully by the temperature gradient technique(TGT). The absorption spectra, fluorescence spectra, fluorescence decay lifetime of Pr3+ ions in CaF 2 crystal sensitized by different Yb3+ ions concentration have been measured. The effective J-O intensity parameters were fitted to be Ω 2 =0.36 × 10−20cm2, Ω 4 =2.89 × 10−20cm2, Ω 6 =6.69 × 10−20cm2 for 0.3 at.%Pr,1.5 at.%Yb:CaF 2. And the emission cross sections of 3P 1 →3H 5 (535 nm), and 3P 0 →3F 4 (750 nm) are calculated to be 2.02 × 10−20cm2, and 2.50 × 10−20cm2 with the FWHM of 17.2 nm, and 10.5 nm, respectively. The fluorescence lifetime of 3P 0 has achieved great increasing by sensitizing of Yb3+ ion. Not only the up-conversion luminescence can be achieved, but also the broad band emission from 1D 2 energy level can be observed. The results show that Yb,Pr:CaF 2 could be a potential laser gain medium for visible and near-IR laser operation. • Not only the up-conversion luminescence can be achieved, but also the broad band emission from 1D 2 energy level can be observed by Yb3+ ion sensitizing. • Spectral properties and Judd-Ofelt parameters of Yb,Pr:CaF 2 crystal were investigated and analysed. [ABSTRACT FROM AUTHOR]

We report on the comparative growth and spectroscopy of Eu3+-doped Y 3 Al 5 O 12 (YAG) and Y 3 ScAl 4 O 12 crystals grown by the micro-pulling-down (μ-PD) method. The structure of the as-grown crystals was determined by X-ray diffraction (XRD) and Raman spectroscopy. The absorption spectra of the crystals are dominated by a strong line centered at 395 nm, matching well with the emission of commercial ultraviolet laser diodes. The Eu:YAG and Eu:Y 3 ScAl 4 O 12 crystals exhibit strongest red emission centered at 710 nm and the full width at half maximum (FWHM) was calculated to be 2.03 and 3.19 nm, respectively. The fluorescence decay curves of 5D 0 levels were measured and discussed. All the results indicate that the Eu:YAG and Eu:Y 3 ScAl 4 O 12 crystals are promising candidates for red luminescent/laser materials. • Eu:YAG and Eu:Y 3 ScAl 4 O 12 crystals were successfully grown by the micro-pulling-down technique for the first time. • The structure parameters of Eu:YAG and Eu:Y 3 ScAl 4 O 12 crystals were investigated by XRD. • Spectral parameters of Eu:YAG and Eu:Y 3 ScAl 4 O 12 crystals were obtained and compared. [ABSTRACT FROM AUTHOR]