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Due to a lack of toxicity reference values that match the regional environmental characteristics, the ecological risk of metals in water bodies cannot be accurately assessed. The Fen River is the second-largest tributary of the Yellow River in China, and the sustainability of this area is threatened by heavy metal pollution caused by intensive industrial and agricultural activities. In this study, site-specific water quality criteria (WQCs) for heavy metals in the Fen River were derived considering toxicity data from native aquatic organisms and regional water quality factors (e.g., water hardness). Short-term WQCs for Mn, Cu, Cd, Zn, Cr, Pb, and Ni were 2026.15, 98.62, 10.02, 63.07, 6.06, 166.74, and 132.73 μg/L, respectively, and long-term WQCs were 166.53, 29.71, 2.18, 19.29, 4.15, 6.38, and 14.76 μg/L, respectively. The distribution characteristics of these metals during the wet season in 2020 were explored, and their average concentrations in the river water did not exceed the environmental quality standards for surface water in China but were higher than the world average levels. Cr was the main pollutant in the sampling sites of Yaodu region, Hongdong Shitan, Xiao River, and Duanchun River, as was Pb in Duanchun River. Based on the site-specific WQCs, using hazardous quotient (HQ) and margin of safety (MOS10) approaches, a high risk of Pb was identified in the Duanchun River, and a medium risk of Cr might occur at midstream and downstream of Yaodu and Xiaodian. The results will provide a reference basis for heavy metal pollution control and water quality management in the Fen River. [ABSTRACT FROM AUTHOR]

The increasing exploitation and application of rare earth elements (REEs) may induce hazardous risks to freshwater aquatic organisms. Due to the lack of water quality criteria (WQC) and sufficient reliable toxicity data, little information is available on the ecological risk of REEs in surface water. In this study, lanthanum (La) toxicity data were collected from published toxicological studies, and the data quality was assessed using a toxicological data reliability assessment tool. To obtain more toxicity data, Daphnia magna, Cyprinus carpio, and Dania rerio embryos were selected as surrogate species, and an interspecies correlation estimation (ICE) model was used to predict the toxicity of La for untested species. The species sensitivity distributions (SSDs) of La toxicity and WQC were investigated. Differences were observed in the hazardous concentrations for 5% of species (HC5), but no statistically significant differences were noted in the SSD curves between the measured acute toxicity data and the predicted data. For the SSDs constructed from the measured toxicity data, the ICE-predicted toxicity data and all acute data supplemented with the ICE-predicted data, the acute WQC values of La were 88, 1022 and 256 μg/L, respectively. According to the SSD and corresponding HC5 of chronic toxicity data, the chronic WQC was 14 μg/L. The results provide a scientific reference for establishing WQC for freshwater aquatic organisms and ecological risk assessments of REEs. [ABSTRACT FROM AUTHOR]

Extensive use of the herbicide glyphosate leads to a high detection rate in the environment and potential risks to nontarget aquatic life. China ranks first globally in the production and consumption of glyphosate, but there are no glyphosate water quality criteria (WQCs) for protecting aquatic life. Here, data on the acute and chronic toxicity of glyphosate and glyphosate-based formulations (GBFs) to freshwater aquatic life were collected and screened. Significant differences in species sensitivity distributions (SSDs) and toxicity values for acute or chronic toxicity were found between glyphosate and GBFs. The hazardous concentrations for 5% of species (HC5) of glyphosate or GBFs between native and nonnative species were different, and native species were found to be more sensitive to the toxicity of glyphosate. The acute and chronic WQCs derived with the SSD method for glyphosate based on the toxicity data for native species in China were 3.35 and 0.26 mg/L, respectively, and those found for GBFs were 0.21 and 0.005 mg/L, respectively. The WQCs in this study were quite different from those estimated using similar statistical extrapolation methods in other countries, which reflects the differences in species sensitivity to glyphosate toxicity in different regions. The hazard quotients (HQs) were calculated based on the WQCs and concentrations of glyphosate in some surface waters in China and indicated that glyphosate exhibits medium or high hazard risk in some samples of Tai Lake, surface water in Guiyang, fishpond water in Chongqing, rural drinking water, and surface water and reservoir water in Henan Province. The WQCs of glyphosate and GBFs have scientific significance for the exposure and pollution control of herbicide formulations and the protection of aquatic life in China. [ABSTRACT FROM AUTHOR]

Acute toxicity of antimony pentavalent to neonatal Daphnia magna and the influence of water quality parameters were investigated, and enzymatic activities of organisms at environmentally relevant levels of antimony were determined. EC 50 values of antimony to neonatal D. magna were 90.3 and 63.8 mg/L at 24 and 48 h of exposure, respectively. Dissolved organic matter (FA and HA) and cation (Ca2+, Mg2+ or Na+) had significant protective effects on D. magna against antimony toxicity. With increasing pH in the range from 7.4 to 8.5, increase of EC 50 were observed due to the competition of OH- on biotic ligands. Based on the biotic ligand model (BLM) concept, stability constants for the binding of Sb(OH) 6 - and OH- to the biotic ligand were estimated, and the Log K XSb (OH) 6 - and Log K XOH - were 3.137 and 2.859, respectively. Moreover, antimony exposure in low concentrations significantly increased MDA levels and maybe exert oxidative stress to the organisms. Antimony can also induce toxicity in D. magna by affecting oxidative stress and neurotransmitter systems. The relatively comprehensive toxicological data can contribute to the toxicity prediction and ecological risk assessments of antimony. [Display omitted] • FA and HA weaken Sb toxicity to Daphnia magna. • Ca2+, Mg2+ and Na+ have significant protective effects against Sb toxicity. • Low levels of Sb exhibit oxidative stress and neurotoxicity on Daphnia magna. • Constants for the binding of Sb(OH) 6 - with the competition of OH- was calculated. [ABSTRACT FROM AUTHOR]

Zinc is a widely distributed environmental pollutants and has been listed as priority heavy metal pollutant in China. Similar as other heavy metals, toxicity of zinc to aquatic organisms affects by environmental factors such as water hardness. It is necessary to develop regional water quality criteria (WQC) to protect native aquatic life against zinc due to the diversity of aquatic organisms' variability across different water systems, as a concretization and supplement for national zinc WQC. This study derived WQC for zinc by species sensitivity distribution (SSD) curve method. The zinc toxicity data of the aquatic organisms in Taihu Lake used in SSD curve was collected based on published toxicity data for zinc with hardness values and supplemented with acute toxicity tests conducted in this study. Six aquatic organism natives to Taihu Lake were selected to conduct zinc acute toxicity test in a range of hardness conditions. The relationship between water hardness and zinc toxicity was constructed. The criterion maximum concentration (CMC) and criterion continuous concentration (CCC) for zinc in Taihu Lake were then derived, which considered the water quality and taxonomic groups in Taihu Lake. The CMC and CCC were 100.69 μg/L and 30.79 μg/L, respectively. The environmental risk of zinc to Taihu Lake are acceptable, at moderate to low levels. This study has provided a basis for regional water quality criterion derivation and risk assessment in China. [Display omitted] • Acute toxicity of zinc to aquatic organisms in Taihu Lake was investigated. • Acute toxicity of zinc reduces with the increasing of water hardness. • The criterion maximum concentration of zinc for Taihu lake is 100.69 μg/L. • The criterion continuous concentration of zinc for Taihu Lake is 30.79 μg/L. • The environmental risk of zinc to Taihu Lake are at moderate to low levels. [ABSTRACT FROM AUTHOR]