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Here, we present a new diacetoxy-functionalized UiO-66 metal-organic framework (MOF) for the trace level detection of hydrazine in water. The MOF material (1) was solvothermally prepared by the reaction between ZrOCl2·8H2O and 2,5-diacetoxy-1,4-benzenedicarboxylic acid (H2BDC-(OCOCH3)2). The desolvated material (1') showed a highly selective fluorescent turn-on signal towards hydrazine in water, which can be visualized by the naked eye under a UV lamp. Within 1 min of hydrazine addition, there was 14-fold fluorescence enhancement. The probe can detect hydrazine up to the nanomolar level (detection limit = 78.8 nM) in water. This detection limit is the lowest among MOF-based fluorescent probes for hydrazine. The material was also utilized for the sensing of hydrazine in paper strips and environmental water samples. Hydrazine-selective deprotection of ester groups anchored with the ligand is the principal reason behind the switch-on nature of sensing.

The field of paper-based microfluidics has experienced rapid growth over the past decade. Microfluidic paper-based analytical devices (μPADs), originally developed for point-of-care medical diagnostics in resource-limited settings, are now being applied in new areas, such as environmental analyses. Low-cost paper sensors show great promise for on-site environmental analysis; the theme of ongoing research complements existing instrumental techniques by providing high spatial and temporal resolution for environmental monitoring. This review highlights recent applications of μPADs for environmental analysis along with technical advances that may enable μPADs to be more widely implemented in field testing.

This paper considers a twelve-year period (2008-2019) and examines to what extent conference presentations and journal publications from three leading literacy and language professional organizations addressed the topic of climate change. Despite it being perhaps the most significant "mega-problem" of the 21st century (Martin, 2007), findings from this study demonstrate that climate change was largely invisible across the thousands of presentations and publications in this data set. It is time literacy and language educators and corresponding professional associations reckon with this troubling reality.

Rare earth elements (REEs) are widely distributed in low concentrations in all parts of the biosphere. REEs are not at all rare, their concentration in the earth’s crust is close to 0.015%. REEs include the elements scandium, yttrium and the lanthanides from lanthanum to lutetium. REEs show similar physical and chemical properties. Today REEs are applied in industries and technologies, in agriculture as microfertilizers and feed additives and they are also used in medicine. REEs are dispersed especially as accessory minerals in pegmatites, granites and associated metamorphic volcanic rocks. Out of more than 250 kinds of minerals containing REEs, only bastnaesite and monazite are of economic importance. Their concentration in the soil varies widely and depends on their presence in parental materials, soil texture, organic matter content, pedogenetic processes and anthropogenic activities. REEs are found in small concentrations in surface stagnant and flowing waters as well as in underground waters. They are found in water in both suspended and dissolved form. REEs enter the atmosphere from various sources, largely owing to human activities. The majority of REEs in the atmosphere are carried by microscopic particles. The uptake and consequently accumulation of REEs in plants are affected by numerous biotic factors, such as plant species and genotype, and abiotic factors such as their concentration in the soil and some chemical and physical soil characteristics. They can enter plants via both root and foliage tissues. There are plant species called hyperaccumulators that are able to accumulate significant amounts of REEs without adverse consequences. RREs are not biogenic for higher plants or for other living organisms, but can influence their life processes. Experi­ments show that REEs can be beneficial for growth, yield and biochemical composition of cultivated plants. They can also alleviate some ecological stress in plants. It is not clear enough how they affect human and animal health. The wide-spread application of REEs in different industries as well as in agriculture lead to a constant increase of the concentrations of these elements in the environment. Therefore, studies on the uptake, accumulation, dis­tribution of REEs in cultivated plant species and their entrance into the food chain as well as their stimulating or toxic effect on living organisms, can be very significant in the future.

This paper examines the Confucian concept of learning, or xue ([character omitted]), from the perspective of ecological humanism. Through a comparative interpretation, this paper attempts to disclose the significance of Confucian xue conceived as a practice of aesthetic appreciation and creativity, emphasizing in particular its function within an eco-centric worldview. The author reviews the relevant concepts of ecological humanism as expressed in the ideas of John Dewey and Thomas Alexander, then applies these as a theoretical framework for interpreting xue and its related concepts and practices as they appear in the Confucian text the Lunyu ([characters omitted] ). It is argued that xue is a process of developing and expressing virtuosity and artistry in the "arts of life," and that its practice was understood as a direct participation in the creative development of nature. The significance of such a concept of learning for contemporary educational philosophy is discussed in conclusion.

Background: Through a close reading of the four issues of The Bowater Papers, this article aims to understand the rise of a paper modernity and to reinsert it--as material and infrastructure-- into media studies. Analysis: Producing wood paper is a strain on the landscape and the environment. The Bowater Papers showcases the histories and material possibilities of paper media products. A paper-dependent modernity can be understood as an infrastructural assemblage of harvesting, production, circulation, and consumption. Conclusion and implications: Paper calls for a natural history and geography of media. Thinking about the mediations from tree to paper through the encompassing notion of "xylomedia" is a way of articulating the intersection of the material, environmental, and infrastructural in media studies. Today is still a paper world, one that is also the age of lignin, package, and Amazon. [ABSTRACT FROM AUTHOR]

"Landscapes of Learning," in the conference title, prompts a literal reading of landscape and its place in film analysis. This article considers landscape's mental and emotional dimensions and the discovery of landscape as a malleable analytical concept. A critique of film as a visual text is invited. Particular analytical approaches to film follow, through notions of soundscape and, using Gilles Deleuze's work on cinema, through orientations such as 'the tectonics of sensation' (percept and affect) and 'the mise-en-scène of the brain' (landscape as a mental construct). These concerns and their implications put us in a position to approach the rest of the conference title's focus on hearts, minds and stories, both in terms of film study in the English classroom and in the light of questions and approaches that open up a film for students.

Enriched environments are beneficial to neurobiological development; specifically, rodents exposed to complex, rather than standard laboratory, environments exhibit evidence of neuroplasticity and enhanced cognitive performance. In the present study, the nature of elements placed in the complex environment was investigated. Accordingly, rats (n = 8 per group) were housed either in a natural environment characterised by stimuli such as dirt and rocks, an artificial environment characterised by plastic toys and synthetic nesting materials, a natural/artificial environment characterised by a combination of artificial and natural stimuli or a laboratory standard environment characterised by no enrichment stimuli. Following exposure to emotional and cognitive behavioural tasks, including a cricket hunting task, a novel object preference task and a forced swim task, brains were processed for glial fibrillary acidic protein (GFAP)-, neuronal nuclei (NeuN)- and brain-derived neurotrophic factor (BDNF) immunoreactivity. Baseline and stress foecal samples were collected to assess corticosterone (CORT) and dehydroepiandrosterone (DHEA). Natural environment animals exhibited shorter diving latencies and increased diving frequencies in the second forced swimming task, along with higher DHEA/CORT ratios, and higher GFAP immunoreactivity in the hippocampus. The type of environmental enrichment did not influence levels of BDNF immunoreactivity in the CA1, CA3 and dentate gyrus of the hippocampus; however, natural environment animals exhibited higher levels of NeuN immunoreactivity in the retrosplenial cortex, an area involved in spatial memory and other cognitive functions. These results suggest that, in addition to enhancing behavioural and endocrinological variables associated with resilience, exposure to natural stimuli might alter plasticity in brain areas associated with cortical processing and learning., (© 2016 British Society for Neuroendocrinology.)

The pulp and paper industry is one of the most significant industrial water polluters, generating large volumes of wastewater with high levels of organic pollutants, suspended solids, and other contaminants. Catalytic ozonation has emerged as a promising technique for the treatment of pulp and paper industry wastewater. Numerous reviews have presented the research on catalytic ozonation; however, open literature is missing a bibliometric analysis. Therefore, this article presents a bibliometric analysis of the research available on catalytic ozonation in pulp and paper industry wastewater treatment. A total of 578 documents extracted from the Scopus database have been examined via VOSviewer, MS Excel, and Rstudio to identify the research trends, influential authors, and research institutions in the field. The results reveal that the number of publications on the topic has increased significantly in recent years. This study also identified several influential authors, institutions, and highlighted future research directions in the field. Overall, the study provides insights into the state of research on catalytic ozonation in pulp and paper industry wastewater treatment and could help guide future research efforts in this area. [ABSTRACT FROM AUTHOR]

The environmental impact of magnetic resonance imaging (MRI) has recently come into focus. This includes its enormous demand for electricity compared to other imaging modalities and contamination of water bodies with anthropogenic gadolinium related to contrast administration. Given the pressing threat of climate change, addressing these challenges to improve the environmental sustainability of MRI is imperative. The purpose of this review is to discuss the challenges, opportunities, and the need for action to reduce the environmental impact of MRI and prepare for the effects of climate change. The approaches outlined are categorized as strategies to reduce greenhouse gas (GHG) emissions from MRI during production and use phases, approaches to reduce the environmental impact of MRI including the preservation of finite resources, and development of adaption plans to prepare for the impact of climate change. Co-benefits of these strategies are emphasized including lower GHG emission and reduced cost along with improved heath and patient satisfaction. Although MRI is energy-intensive, there are many steps that can be taken now to improve the environmental sustainability of MRI and prepare for the effects of climate change. On-going research, technical development, and collaboration with industry partners are needed to achieve further reductions in MRI-related GHG emissions and to decrease the reliance on finite resources. LEVEL OF EVIDENCE: 5 TECHNICAL EFFICACY: Stage 6., (© 2023 The Authors. Journal of Magnetic Resonance Imaging published by Wiley Periodicals LLC on behalf of International Society for Magnetic Resonance in Medicine.)

This paper responds directly to the question, how do we communicate our philosophy of art education? It does this by drawing upon previous research with "House of Imagination, School Without Walls" and doctoral research exploring children's learning identity as artists, to illuminate a philosophical approach to art education and its pedagogy that highlights both human and more-than-human dimensions of learning in communities of practice involving artists, researchers and educators working alongside children and young people where spaces of possibility for practice and innovation emerge. The paper focuses particularly on current and creative research in the "Forest of Imagination," a long-term participatory contemporary arts and architecture event in Bath, UK. "Forest of Imagination" offers an alternative, creative approach to learning, focusing on ecological imagination and nature connection. As a new aesthetic imaginary, the Forest of Imagination is a living, breathing art classroom, inspiring curiosity, imagination and a deeper connection with the natural world.

The aim of this study was to investigate the properties of concrete with waste paper ash (WPA) as cement replacing material. The chemical composition of WPA was reported, and Portland cement was partially replaced with 0%, 5%, 10%, 15%, and 20% of WPA to explore its effect on both fresh and hardened properties of C—25 concrete. The result of this study indicated that the chemical compositions of WPA were not classified as Pozzolanic material. Setting times of blended cement paste with WPA were lengthened and its consistency was also increased. The cement paste with replacement up to 10% showed a normal consistency within the standard range. The workability of concrete was tested immediately after preparing the concrete mix, whereas the compressive strength was tested after 7 and 28 days of curing. The results indicated that the workability of concrete containing WPA decreases as the WPA content increases. This study also revealed that there is a significant improvement in the compressive strength of concrete. Replacement of ordinary Portland cement by WPA up to 10% results in better compressive strength than that of the control mix. An improvement of 5.6% & 1.2% was observed, respectively, when compared with the 28-day compressive strength of the control mix. But the compressive strength decreases as the WPA replacement increases over 10%. Maximum compressive strength of 37.89 MPa was obtained for concrete containing 5% of WPA.

The advent of digitalization has brought about profound changes in the global value chain, raising significant concerns about environmental sustainability. However, the environmental consequences resulting from the interplay between global value chain participation and digitalization have not been adequately explored, particularly in the Middle East and North Africa region (MENA). To address this gap, our research delves into the impact of global value chain participation on environmental sustainability in 15 MENA countries from 1996 to 2018. We also investigate the moderating effects of two critical policy variables: digitization and institutional quality, employing the SYS-GMM Panel method and Random Effects method. Empirical findings reveal that participating in the global value chain has positive environmental implications for MENA countries. These results hold true and remain consistent when considering forward value participation linkages and oil-importing nations. Furthermore, we observe that the proposed moderators play a significant role in shaping the environmental impact of the global value chain. Specifically, institutions and global value chains work in synergy to promote environmental sustainability in MENA, encompassing both oil-importing and oil-exporting groups. However, the interaction between the global value chain and digitalization generates a negative net effect, which diminishes beyond a specific digitalization threshold of 10.23%. Consequently, implementing complementary policies becomes crucial when digitization is below this threshold. Additionally, our study supports the resource curse hypothesis for the MENA region, suggesting that natural resources contribute to environmental degradation. These insights offer valuable guidance for enhancing global value chain integration while preserving a sustainable environment in MENA., (© 2023. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.)

There is a growing interest in examining alterations in telomere length as a reliable biomarker of general health, as well as a marker for predicting later morbidity and mortality. Substantial evidence shows that telomere length is associated with aging; telomere shortening acts as a “counting mechanism” that drives replicative senescence by limiting the mitotic potential of normal (but not malignant) cells. In this Correspondence, we attempt to answer the question of why recently published papers about telomere length alterations increase our uncertainty rather than reduce it. This discussion includes three major research areas regarding telomere length: environmental stressors, aging, and life span. Our review suggests that activation of telomerase activity due to stressors in space might be a double-edged sword with both favorable and unfavorable consequences. The selection of an effect’s consequence must clearly elucidate the experimental conditions as well as associated stressors. In this Correspondence, we attempt to answer the question of why recently published papers about telomere length alterations increase our uncertainty rather than reduce it. The selection of an effect’s consequence must clearly elucidate the experimental conditions as well as associated stressors. Both positive and negative consequences must be clearly addressed in order to bolster the conclusions, as well as identify future research directions.

Mass production of paper is one of the significant factors that are contributing to increase in carbon outrush in the global ecological system. The paper trade releases large volumes of air, water, and soil pollutants, which pony up to green house gasses. The rotted paper releases methane gas, which is many times more hazardous than carbon dioxide. Paperless business is a vital environmental business practice that is better for the upliftment of the current degrading environment. Global corporations are promoting paperless workplaces to move a step forward towards a sustainable ecological system and achieve the sustainable development goals of the United Nations. The research study after observation opined that although various challenges are being portrayed by employing digitalization of workplaces still working paperless is quite fruitful for the global ecological system. The digital innovations are the only alternatives available in the current times for the paper based job places. In this research study fairly was also studied the critical aspect of paperless workplace. On analyzing the dark data of the global corporeal world it was depicted that digitalization is also enhancing the carbon footprint. It is thus concluded in this research study that sensible and secure use of digital technology could only make paperless working successful. [ABSTRACT FROM AUTHOR]

The aim of this study was to investigate the properties of concrete with waste paper ash (WPA) as cement replacing material. The chemical composition of WPA was reported, and Portland cement was partially replaced with 0%, 5%, 10%, 15%, and 20% of WPA to explore its effect on both fresh and hardened properties of C—25 concrete. The result of this study indicated that the chemical compositions of WPA were not classified as Pozzolanic material. Setting times of blended cement paste with WPA were lengthened and its consistency was also increased. The cement paste with replacement up to 10% showed a normal consistency within the standard range. The workability of concrete was tested immediately after preparing the concrete mix, whereas the compressive strength was tested after 7 and 28 days of curing. The results indicated that the workability of concrete containing WPA decreases as the WPA content increases. This study also revealed that there is a significant improvement in the compressive strength of concrete. Replacement of ordinary Portland cement by WPA up to 10% results in better compressive strength than that of the control mix. An improvement of 5.6% & 1.2% was observed, respectively, when compared with the 28-day compressive strength of the control mix. But the compressive strength decreases as the WPA replacement increases over 10%. Maximum compressive strength of 37.89 MPa was obtained for concrete containing 5% of WPA. [ABSTRACT FROM AUTHOR]

Land cover dynamics is a challenging and vigorous process that associates natural and human systems that have undeviating effects on atmosphere, water and soil which lead to many environmental problems worldwide. Urbanization is one of a major land cover change that is highly correlated with many environmental problems that need emphasis. This paper aimed to review and present level and effect of land use land cover changes, urbanization, factors affecting land cover change and application of geographic information system & remote sensing in monitoring land cover changes. Over the past 300 years, about 1.2 million kilometer square of forests and 5.6 million kilometer square of pasture and rangeland were replaced by other uses worldwide, while cultivated land increased by 12 million km2. In 1950, only 30 percent of the world population lived in urban settings, the fraction raised to 55% by 2018. This led to about roughly 60% of the ecosystem services are being destroyed or used in unsustainable ways worldwide. Population expansion, change of technology, high land value, corruption, lack of awareness, migration of people and political pressure are among major driving force of land cover changes. Geo-informatics technology specially GIS and Remote Sensing is found to be an excellent tool for study of land cover change that enables observation across large area of earth’s surface with low cost, better efficient and high accuracy. Therefore monitoring, analyzing and evaluation of land cover dynamics with the help of geo-informatics is decisive for improved management & characterizing land cover alteration processes, and determining its environmental consequences.