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We demonstrate an environmentally stable femtosecond laser for industrial application based on all polarization‐maintaining Yb‐doped laser and experimentally explore the effect of the net cavity dispersion (NCD) on output characteristics. The oscillator emits pulses with 5.1 ps and a 23 nm spectral bandwidth, then the pulse is compressed to 88 fs. The instabilities over 120 h gives 0.32% relative root mean square noise, indicating high stability of the pulse laser. With effective regulation of NCD, we obtained the maximum spectral bandwidth of 27 nm. Such broadband oscillator with compact all‐fiber configurations provide extremely high stability should be very attractive for long‐term industrial application. [ABSTRACT FROM AUTHOR]

Single‐crystal halide perovskites are among the most promising semiconductor candidates for highly efficient optoelectronic devices due to their higher stability against moisture and light radiation and lower trap density than their polycrystalline counterparts. In this work, single‐crystal MAPbBr3 microcavities with controllable geometries and sizes are fabricated using a template‐limited method combined with an anti‐solvent diffusion growth method. The single‐crystal microcavities emit lasers around 550 nm under femtosecond laser excitation, with a lasing threshold of ≈35 µJ cm−2 and a quality factor of 1135, as well as excellent long‐term operation stability. The temporal‐spatial evolution of the lasing process in an individual microcavity is achieved by the microscopic optical Kerr‐gating technique. The temporal behaviors including pulse duration and build‐up time, emission spectra shift, and lasing mode evolution as a function of pump fluence are unveiled, and the complex relationship between the light‐induced carrier dynamics and lasing properties is clarified. Spatial heterogeneous lasing dynamics are also observed in an individual microdisk, which is attributed to the non‐uniform optical losses and carrier densities driven by structural imperfections. This study can provide a fabrication strategy for perovskite on‐chip optoelectronic devices, as well as a deeper understanding of the carrier‐density‐driven lasing dynamics in microcavities. [ABSTRACT FROM AUTHOR]

A femtosecond pulse laser was used to fabricate carbon nanodots (CDs), of which the particle size and photoluminescence (PL) properties could be effectively controlled by adjusting ambient pressure. By increasing the reaction pressure, the particle size of CDs gradually decreased and finally reached less than 1 nm at 4 MPa. Simultaneously, the fluorescence intensity of the CDs first increased and then decreased by further increasing the pressure. By examining the PL dynamics and the chemical structure of the CDs, we found that the PL change of products was attributed to the quantity change of functional groups attached to the CDs due to the surface area change of the carbonic core. [ABSTRACT FROM AUTHOR]

In this paper, we propose a demodulation method for refractive index (RI) sensing with tilted fiber Bragg gratings (TFBGs). It operates by monitoring the TFBG cladding mode resonance “cut-off wavelengths.” The idea of a “cut-off wavelength” and its determination method are introduced. The RI sensitivities of TFBGs are significantly enhanced in certain RI ranges by using our demodulation method. The temperature-induced cross sensitivity is eliminated. We also demonstrate a parallel-double-angle TFBG (PDTFBG), in which two individual TFBGs are inscribed in the fiber core in parallel using a femtosecond laser and a phase mask. The RI sensing range of the PDTFBG is significantly broader than that of a conventional single-angle TFBG. In addition, its RI sensitivity can reach 1023.1 nm/refractive index unit in the 1.4401–1.4570 RI range when our proposed demodulation method is used. [ABSTRACT FROM AUTHOR]

The nonlinear optical response of gold nanoparticles/reduced graphene oxide (AuNPs/rGO) nanocomposites prepared by laser ablation method was studied using a femtosecond laser open-aperture (OA) Z-scan method, and an enhanced nonlinear absorption effect was observed. Using the femtosecond time-resolved pump-probe measurements, the nonlinear response mechanism in the hybrid was studied. When graphene was excited by an ultrashort laser pulse, the bleaching of valence band (VB) and the filling of conduction band (CB) took place, causing a saturable absorption (SA) effect. When decorated with gold nanoparticles, the excited carriers from the CB of graphene could transfer to the sp band of the metal before returning to the VB of graphene. This process would take place in a much longer time scale (∼50 ps) than the direct relaxation in pure graphene, causing the enhancement of the SA effect. The excited carrier dynamics were further demonstrated using femtosecond time-resolved transient absorption spectroscopy, and the interband relaxation of the excited electrons from the sp band of AuNPs to the CB of graphene was observed, resulting in the further filling of the CB of graphene and enhancement of the SA effect. [ABSTRACT FROM AUTHOR]

Zinc oxide (ZnO) nanoparticles (NPs) are synthesized by one-step femtosecond laser ablation of zinc powders in n-methyl pyrrolidone (NMP) at room temperature. The as-prepared ZnO NPs are fairly stable, water-soluble and have abundant surface functional groups resulting in a strong fluorescence in the visible region. By further annealing the ZnO NPs in the reacting solvent up to 120∘C, the photoluminescence (PL) intensity of material can be significantly enhanced. Besides, the PL of ZnO NPs can change from blue to green by controlling the annealing temperature. The products exhibit excellent temperature sensing with high temperature sensitivity and a 1.3% change per ∘C response over a linear temperature sensing range (6–84 ∘ C) in aqueous buffer, which matches well with the physiologically relevant temperatures. Hence, the ZnO nanoparticle system can serve as a promising candidate for practical fluorescent temperatures nanosensors which can be used for accurate temperature monitoring within biological systems. Water-soluble and photoluminescent ZnO NPs are synthesized by femtosecond laser ablation of zinc powders at room temperature. By further annealing, the photoluminescence intensity of the products can be significantly enhanced. The ZnO NPs exhibit excellent temperature sensing with a high sensitivity of 1.3% change per ∘C over a linear range of 6–84∘C in aqueous buffer, which can serve as a promising candidate for fluorescent temperature nanosensors to be used for accurate temperature monitoring within biological systems. [ABSTRACT FROM AUTHOR]

Two-dimensional (2D) periodic structures were fabricated on silicon surfaces by femtosecond laser irradiation in air and water, with the assistance of a microlens array (MLA) placed in the beam's path. By scanning the laser beam along the silicon surface, multiple grooves were simultaneously fabricated in parallel along with smaller laser-induced ripples. The 2D periodic structures contained long-periodic grooves and perpendicular short-periodic laser-induced ripples, which had periods of several microns and several hundred nanometers, respectively. We investigated the influence of laser power and scanning velocity on the morphological evolution of the 2D periodic structures in air and water. Large-area grid-like structures with ripples were fabricated by successively scanning once along each direction of the silicon's surface, which showed enhanced optical absorption. Hydrofluoric acid was then used to remove any oxygen and laser-induced defects for all-silicon structures. [ABSTRACT FROM AUTHOR]

The influence of the size parameter of the scatterers on ultrafast optical Kerr gate (OKG) imaging is investigated in highly scattering poly-disperse turbid media. The results show that in a poly-disperse turbid medium, which in our case, is a suspension of two different sized mono-disperse microspheres, the temporal and spatial behaviors of the light pulses transmitted through it are dominated by the smaller microspheres. The contrasts of the OKG images for the poly-disperse microsphere sample are closer to the contrasts of the OKG images for the smaller sized mono-disperse microsphere sample. [ABSTRACT FROM PUBLISHER]

We studied the structural and elemental evolutions during the femtosecond laser percussion drilling of high-aspect-ratio diamond microholes. Microholes 225-μm-deep having an aspect ratio of 15 were drilled with an exposure time of 100 s and a laser power of 60 mW. It is found that when the specimen was machined by femtosecond laser at low power and short exposure time, the laser-affected zone (LAZ) may be still solid in the interior rather being void, even it reached the bottom of the diamond. A clear crack appeared between the solid portion and pristine diamond. Elemental analysis revealed that oxygen was incorporated into the solid portion of the LAZs, and its atomic percentage reached 6.5% for a laser power of 10 mW at initial position and decreased as the depth increased in the solid portion. The wall of the void contained nearly no oxygen. Furthermore, nanoripples were observed on the sidewall surface of the hole. [ABSTRACT FROM AUTHOR]

Supercontinuum (SC) generation using multiple thin plates is demonstrated with a femtosecond laser pulse. We propose an improved technique to obtain larger spectrum broadening and higher spectral intensity by employing mixed multiple thin plates with different thicknesses and materials. Furthermore, the spectrum has good stability, which is superior to that of the spectrum induced by the traditional single filament in bulk material. Our approach offers a route towards simple and stable SC generation for potential applications. [ABSTRACT FROM AUTHOR]

We demonstrated a linear-cavity fiber laser using a fiber Bragg grating (FBG) fabricated by femtosecond laser and a Sagnac loop as cavity mirrors. The temperature sensing response of the fiber laser was characterized by placing the FBG in a high-temperature environment. The stability of the fiber laser at high temperature was improved after the FBG was annealed at 1100 °C. The fiber laser can work stably as a temperature sensor at 1000 °C and its temperature sensing sensitivity is approximately 15.9 pm/°C from 300 °C to 1000 °C. • A fiber laser based on an FBG fabricated by femtosecond laser and a Sagnac loop as cavity mirrors is demonstrated. • The fiber laser can work stably as a temperature sensor at 1000 °C after the FBG was annealed at 1100 °C. • The wavelength of the fiber laser had a quadratic dependence on temperature from room temperature to 1000 °C. • The temperature–wavelength had a good linear relationship from 300 °C to 1000 °C. Its sensing sensitivity was about 15.9 pm/°C. [ABSTRACT FROM AUTHOR]

Gold nanorod (GNR) and reduced graphene oxide (rGO) hybrids are synthesized using photochemical method based on femtosecond laser ablation without the usage of strong chemical reducing agents. The products are characterized by absorption spectra, transmission electron microscopy (TEM) and X-ray photoelectron spectroscopy (XPS). The formed GNR are well located on the surface of rGO sheets. By adjusting the laser ablation time, the aspect ratio and optical properties of GNR can be well controlled. The produced nanocomposites exhibited an excellent near-infrared (NIR) photothermal performance with a photothermal conversion efficiency of 77.8%, suggesting that the hybrids have large potential as agents in photothermal therapy. • Gold nanorod and graphene hybrids are synthesized using femtosecond laser. • The aspect ratio of gold nanorod can be well controlled by adjusting laser ablation time. • The produced hybrids exhibited an excellent photothermal performance at 808 nm. [ABSTRACT FROM AUTHOR]

Gradient-index modulation prefabrication in the cladding of standard telecom fibers was proposed for femtosecond laser processing of Type II-IR fiber Bragg gratings. The refractive index of the prefabricated region in the cladding had a large gradient across the laser beam, which could act as a cylindrical lens to enhance the focusing of laser beam when writing Type II-IR gratings. With the help of prefabrication, the threshold pulse energy for processing Type II-IR FBGs was lowered from 750 μJ to 520 μJ. The fabricated FBGs showed good thermal stability at temperatures over 900 °C. [ABSTRACT FROM AUTHOR]

A compact 51.6-W, 26- μ J all-fiber integrated Yb-doped femtosecond laser source with pulse durations of 692 fs despite ∼ 18 π nonlinear phase shift accumulation in the main amplifier is demonstrated by using fiber quasi-rectangular pulse pre-shaping. The numerical results are in good agreement with the experiment. Due to the advantages of an all-fiber spliced structure and a minimal pulse stretching ratio (from 26.3 ps to ∼ 70 ps), just a small size of gratings and a short separation distance between the two gratings in the compressor is required. Therefore, the laser source is exceedingly compact, robust, cost-effective, and easy to assemble. This technique is anticipated to accelerate the use of fiber femtosecond lasers in industrial applications. • All-fiber spliced structure with ∼ 18 π nonlinear phase shift in the main amplifier. • High peak power and density as much as 0.4 MW and 80 GW/cm 2 respectively in the main amplifier • Compact structure with small compressor makes the laser robust, reliable, and cost-effective. • Near-diffraction-limit beam quality suitable for micro-machining and related applications. [ABSTRACT FROM AUTHOR]

We demonstrate the control of femtosecond single-filament formation via feedback-based wavefront shaping. It is observed that the optimal phase profile forms a single-filament with closed-loop genetic algorithm. Using this method, the position stability of the filament can be significantly improved, and the position of the single filament can be flexibly adjusted. Additionally, a two-step approach combining the premodulation of pinhole with wavefront shaping is presented for forming a bright single filament rapidly. • Succeeded in getting a stable and bright single filament. • Optimization processes from multiple filaments to single filament are displayed. • A two-step strategy is an effective technique to fast control single filament. [ABSTRACT FROM AUTHOR]

In order to investigate the decay of nonadiabatic molecular unidirectional rotation (UDR) for nitrogen molecules, we measured the time-resolved rotational Doppler spectroscopy in first four revival periods after instantaneous excitation by a polarization shaped femtosecond laser. The results show that the rotational Doppler shifts decrease with increasing order of revival periods for full and half rotational revivals. Moreover, the maximum alignment of the molecular UDR at half rotational revivals was demonstrated to delay with revival periods increasing. This work is helpful to understand the kinetic processes of collisional decay for nonadiabatic molecular UDR, especially in the several revival periods after excitation. • Early collisional decay in nonadiabatic molecular UDR was observed. • The RDS at rotational revivals decrease with revival periods increasing. • Maximum alignment at half revivals delays with revival periods increasing. [ABSTRACT FROM AUTHOR]

Morphologies of high-aspect-ratio silicon grooves fabricated by using femtosecond laser irradiation and selective chemical etching of hydrofluoric acid (HF) were studied. Oxygen was deeply doped into silicon under femtosecond laser irradiation in air, and then the oxygen-doped regions were removed by HF etching to form high-aspect-ratio grooves. After HF etching, periodic nano-ripples which were induced in silicon by femtosecond laser were observed on the groove sidewalls. The ripple orientation was perpendicular or parallel to the laser propagation direction ( z direction), which depended on the relative direction between the laser polarization direction and the scanning direction. The formation of nano-ripples with orientations perpendicular to z direction could be attributed to the standing wave generated by the interference of the incident light and the reflected light in z direction. The formation of nano-ripples with orientations parallel to z direction could be attributed to the formation of self-organized periodic nanoplanes (bulk nanogratings) induced by femtosecond laser inside silicon. Materials in the tail portion of laser-induced oxygen doping (LIOD) regions were difficult to be etched by HF solution due to low oxygen concentration. The specimen was etched further in KOH solution to remove remaining materials in LIOD regions and all-silicon grooves were fabricated. [ABSTRACT FROM AUTHOR]

• We apply spectroscopy to monitor the real-time full evolution of molecular UDR for N 2 molecules under ambient conditions. • The time-dependent alignment degree of the molecular UDR and 1-D alignment have different features. • The rotational Doppler shift was observed to change according to these features at various rotational revivals. Molecular unidirectional rotation (UDR) induced by femtosecond lasers has attracted significant attention in recent years. We monitored the molecular UDR for nitrogen molecules under ambient conditions in real time by observing time-resolved spectroscopic probes, based on the rotational Doppler effect. The time-dependent alignment degree of the molecular UDR was experimentally observed to differ from that of the 1-D alignment. Moreover, the rotational Doppler shift exhibited different features at various rotational revivals. Finally, we used spectroscopy to demonstrate the manifestation of the quantum nature of the molecular UDR. [ABSTRACT FROM AUTHOR]