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Lacustrine shale, represented by the Middle Permian Lucaogou Formation in the Jimsar Depression in the eastern Junggar Basin, has become one of the main areas of shale oil exploration in China. In this study, we used 137 samples of shale from the Lucaogou Formation, drawn from 14 wells in the Jimsar Depression, to investigate their characteristics of pyrolysis, organic carbon and soluble organic matter content, biomarkers, organic microscopic composition, and vitrinite reflectance. Basin simulation and hydrocarbon generation thermal simulation experiments were also conducted in a closed system. The results of this study indicate that the input of an algae source was dominant in the source rocks of the Lucaogou Formation, that the water in which the rocks were deposited had high salinity and strong reducibility, and that the source rocks were oil-prone. The Lucaogou source rocks generally had good hydrocarbon generation capability, but showed significant heterogeneity. At the end of the Cretaceous period, the shales in the Lucaogou Formation entered the oil-generation window as a whole. Currently, the shales of the Lucaogou Formation are generally in the high-maturity stage in the deep part of the depression, producing a large amount of high-maturity oil and condensate gas, while those in the shallow part have relatively low maturity and can only produce a large amount of conventional crude oil. The maximum crude oil generation rate of the Lucaogou Formation shale obtained from the thermal simulation results was 220.2 mg/g of the total organic carbon (TOC), and the maximum hydrocarbon expulsion efficiency was estimated to be 59.3–76.4%. [ABSTRACT FROM AUTHOR]

The shale oil of the Lucaogou Formation in the Jimusaer Sag of the Junggar Basin was divided into two sweet spots for exploration and development. Crude oil in the upper and lower sweet spots comes from the upper and lower source rocks. After years of exploration, it has been found that the crude oil in the lower sweet spot has worse physical properties than that of the upper sweet spot. In this study, through the physical and geochemical analysis of crude oil in the upper and lower sweet spots, combined with the organic petrological observation of the upper and lower source rocks, the cause of the poor physical properties of the crude oil in the lower sweet spot has been identified. n-Alkanes in the saturated hydrocarbons of crude oil in the upper and lower sweet were complete while odd-to-even predominance was evident, indicating that the poor physical properties of the crude oil are unrelated to biodegradation. In addition, the correlation between the biogenic parameters and the physical properties of crude oil was analyzed, finding that the difference in crude oil is mainly related to the composition of biogenic precursors of upper and lower source rocks. Combined with organic petrological observation, the lower source rock was found to be rich in telalginite (green algae), which is therefore the primary reason for the difference in physical properties. In comparing results from the characteristics of crude oil biomarkers from both the upper and lower sweet spots, crude oils in the upper sweet spot are similar to each other, indicating that the enrichment of crude oil has experienced a certain migration. In contrast, the differences in biomarkers between the crude oils of the lower sweet spot were relatively large and changed regularly with depth, suggesting the self-generated and self-stored characteristics of crude oil enrichment. At the same time, it was found that the crude oil in the lower sweet spot is also affected by the maturity of adjacent source rocks under the condition of a consistent parent material source. Overall, it was determined that the lower the maturity of source rocks, the poorer the physical property of the crude oil produced. [ABSTRACT FROM AUTHOR]

Crude oil has been discovered in the Paleogene and Neogene units of the Weixinan Sag in the Beibu Gulf Basin. To determine the source and accumulation mode of this crude oil, 12 crude oil samples and 27 source rock samples were collected and an extensive organic geochemical analysis was conducted on them. Based on the geological conditions and the analytical results, the types, origins and accumulation patterns of crude oil in the study area were elucidated. Except for a shallowly‐buried and biodegraded crude oil deposit in Neogene rocks, the crude oil samples in the study area were normal. All of the crude oils were derived from lacustrine source rocks. According to biomarker compositions, the crude oils could be divided into two families, A and B, distinctions that were reinforced by differences in carbon isotope composition and spatial distribution. Oil‐source correlation analysis based on biomarkers revealed that Family A oils were derived from the mature oil shale at the bottom of the second member of the Liushagang Formation, while the Family B oils formed in the mature shale of the Liushagang Formation. The Family A oils, generated by oil shale, mainly migrated laterally along sand bodies and were then redistributed in adjacent reservoirs above and below the oil shale layer, as well as in shallow layers at high structural positions, occupying a wide distribution range. The Family B oils were generated by other shale units before migrating vertically along faults to form reservoirs nearby, resulting in a narrow distribution range. [ABSTRACT FROM AUTHOR]

Abstract Source rocks are found in the Eocene Liushagang Formation (El 1: bottom , El 2 and El 3:top members), in the Weixi'nan sag, Beibuwan Basin. The source rocks are mainly mudrocks, except El 2 , which consists of organic-rich shales at the bottom and mudrocks in the middle-upper part. Total organic carbon (TOC) and Rock-Eval analyses of 146 samples indicate that El 2 rocks have the best hydrocarbon generating potential, especially for organic-rich shales that contain up to 10% TOC with HI > 800 mg/g. The vitrinite reflectance analysis suggests that El source rocks are marginally mature to mature. Geochemical analyses were conducted on 18 El rock extracts and 18 oil samples from the WZ12 field. El 2 and El 3 source rock have similar organic facies and are distinct from El 1. El 2 and El 3 have higher C 27 βα (20R + 20S) diasteranes/C 27 αββ (20R + 20S) steranes (C 27 DiaS/C 27 S), Gammacerane/Hopane (G/H) and (C 28 + C 29) tricyclic terpane/((C 28 + C 29) tricyclic terpane + Ts) (ETR), and low C 23 tricyclic terpane/hopane (C 23 /H) and C 24 tetracyclic terpanes/C 26 tricyclic terpane (C 24 /C 26). These biomarker distributions indicate that El 2 and El 3 rocks were deposited under more alkaline-saline environment and had less import of terrestrial organic matter relative to El 1. El 2 can be distinguished from El 3 as having higher 4-methylsteranes/C 29 ααα steranes (4MSI) and G/H. WZ12 oils all exhibit similar compositions and display biomarker characteristics that correlate with the El 2 and El 3 rock extracts. 1D thermal and burial history model shows that El 2 and El 3 began to generate a great deal of hydrocarbon at ∼11.5 Ma and 23 Ma, respectively. At this stage, traps formed and faults actively extended downwards into the El 2 and likely into El 3. Oils expelled from El 2 and El 3 migrated upward into shallow intervals along faults then laterally along the structural slopes and accumulated in areas with good fault sealing primarily in the Miocene age Nx and Nj strata. Meanwhile, under the effect of overpressure in the middle of organic-rich shales, oils from El 2 may have migrated downward into reservoirs in the upper part of El 3. Lithologic traps in El 1 reservoir may be charged with relatively immature oil derived from El 1. Highlights • Source rocks in El 2 , especially organic-rich shales in the bottom of El 2 are the most important source rocks. • Sedimentary environment of different intervals of El have been distinguished. • WZ12 oils generated from oil El 2 and El 3 source rocks based on biomarkers parameters of saturated hydrocarbon. • Faults and overpressure may be responsible for the distribution of WZ12 oils. [ABSTRACT FROM AUTHOR]

The Tu-Ha Basin is a typical Jurassic coal-derived petroliferous basin in western China. Seventeen natural gas samples were collected from the Jurassic Sanjianfang and Qiketai Formations, the Cretaceous Tugulu Formation, and the Paleogene Shanshan Formation to analyze the source and secondary alteration of natural gas. The natural gas samples were characterized by molecular and stable carbon (δ 13 C) and hydrogen (δD) isotope compositions. The results indicate that the natural gases are wet gases, in which methane is the main alkane component. Nitrogen (N 2 ) and carbon dioxide (CO 2 ) are the two non-hydrocarbons. The N 2 values (>12%) are relatively higher, which increase rapidly at the burial depth of 1500–2000 m. Some natural gases have suffered secondary alteration at this depth. The natural gases are thermal genetic coal-derived gases (humic gas), coming from the Jurassic coal measure source rocks, which are chiefly in the low mature to early mature stage. Nitrogen in the shallow is chiefly derived from the atmosphere, while nitrogen at the deeper burial depth is mainly derived from the thermal decomposition of organic matter (OM). The shallow natural gas samples have the heaviest carbon isotope composition of ethane (δ 13 C 2 ) and a carbon isotope sequence of (δ 13 C 1 < δ 13 C 2 > δ 13 C 3  > δ 13 n -C 4  < δ 13 i -C 4 ), which is mainly caused by the biodegradation. The higher nitrogen content illustrates that a large amount of surface water is running into the reservoirs. Water washing occurs in the reservoirs, which decreases the molecular methane content and increases the amount of heavier hydrocarbons at 1500–2000 m depth. [ABSTRACT FROM AUTHOR]

Shale oil exploration and development have been conducted in the Permian Lucaogou Formation in the Jimusaer Sag, Junggar Basin. The upper (P 2 l 2) and lower (P 2 l 1) members of the Lucaogou Formation developed with sand layers, which are the shale oil development sections in the Lucaogou Formation. In order to clarify the enrichment law of shale oil for these members, the geological conditions of the P 2 l 2 and P 2 l 1 members were analyzed. The focus of this study were oil-bearing sandstone and mudstone samples from the Lucaogou Formation. These samples were studied by casting thin section observation, total organic carbon, pyrolysis, and gas chromatography–mass spectrometry. The results showed that the upper and lower members of the Lucaogou Formation are mainly characterized as interbedded source rock and reservoir. An oil-source correlation showed that the crude oil in the upper member mainly originated from its adjacent source rock from a deeper position through secondary migration. However, no evidence of secondary migration was observed in the crude oil in the lower member which mainly originated from the adjacent source rock. For the sandbodies in the upper member, when burial is shallower than peak oil generation, the physical properties of the middle part of the sandbody are better than the top and bottom. When burial is deeper than peak oil generation, relatively good physical properties developed in the sandstone in the vicinity the source rock. The lower member has less reservoir thickness, poorer lateral continuity and horizontal permeability than the upper member. The high-quality reservoirs are represented in a single sandbody in the lower member that is mainly developed in the middle part. After the crude oil was discharged from the source rock enters the sandbody, and long-distance lateral migration was restricted. Thus, crude oil in the lower member is enriched and accumulated in situ. • The characteristics of the source rocks and reservoir of the upper and lower members of the Lucaogou Formation are described. • The oil-source correlation in the upper and lower reservoirs of the Lucaogou Formation have been discussed. • The oil accumulation model of the upper and lower member of the Lucaogou Formation is established. [ABSTRACT FROM AUTHOR]

Shale oil generated by the lower member of the Lucaogou Formation, which was deposited under saline lacustrine conditions within the Jimusaer Sag of the Junggar Basin (NW China), is generally characterized by high density and viscosity. However, a strong spatial heterogeneity of physical properties is observed as well. In this paper, these spatial variations and their controlling mechanisms are evaluated from the perspective of the primary depositional environment, source rock thermal evolution and fractionation effects of primary migration. Based on a detailed organic petrological and geochemical characterization of the target interval within the key well JHBE, hydrous pyrolysis experiments conducted on representative source rock samples from well JHBE, as well as established methods of oil-source correlation subjected to oil samples from several regionally distributed producing shale oil wells, a predictive model of density and viscosity changes of crude oil was established. According to the findings of this study, the thermal evolution and sedimentary environment of source rocks are the main factors affecting the quality of crude oil, and the fractionation effect of primary migration has little effect. Crude oil density and viscosity at first increase up to peak oil maturity, followed by a decrease with further increasing thermal evolution of the source rock. Furthermore, if the source rocks experienced similar thermal histories, it was discovered that relatively low density and corresponding viscosity values are characteristic for crudes from source rocks which were formed in a relatively high salinity environment. In contrast, hydrocarbon generation of source rocks formed under relatively low salinity environments is slightly retarded in direct comparison, and the density and viscosity of the generated crude oil are both relatively high. This highlights that a detailed organic petrographical and geochemical evaluation of the target formation is crucial for the assessment of shale oil potential and production sweet spots in alginite-dominated lacustrine sedimentary environments. • Oil-source correlation of the lower member in the Lucaogou Formation are conducted. • Crude oil density and viscosity control by thermal evolution are discussed from a new sight. • The higher salinity is, the lower density of crude oil is. [ABSTRACT FROM AUTHOR]

• Sedimentary conditions in the Lucaogou Formation source rocks are described. • The telalginite generated hydrocarbons earlier than the lamalginite. • New parameter index to identify effective source rocks is proposed. The Middle Permian Lucaogou Formation in the Jimusaer Sag is a hotspot for exploring and developing lacustrine tight oil in the Junggar Basin, NW China. In this study, we evaluated the tight oil potential from the perspective of source rock hydrocarbon generation and expulsion. Based on a detailed organic, petrological, and geochemical characterization of the target interval within the key well JHBE, kinetic experiments were performed on representative shale samples from the well JHBE and the threshold of hydrocarbon expulsion of the source rock was established. The findings of this study revealed that the Lucaogou Formation shales were deposited in a dysoxic to anoxic and clay-poor lacustrine environment with variable salinity and their organic matter (OM) was contributed from both lamalginite and telalginite with minor vitrinite and inertinite, resulting in good to excellent source rock potential. The lamalginite was deposited in water with low salinity, whereas the telalginite developed in water with relatively higher salinity. Although the greater contribution of lamalginite resulted in a higher OM content than that of telalginite, the former generated a lower amount of hydrocarbons than the latter, because telalginite is capable of generating hydrocarbons earlier than lamalginite, which is indicated by the higher HCI (Hydrocarbon index, S 1 × 100/TOC), EOM/TOC (extraction of organic matter/total organic carbon), C 29 ββ/(αα + ββ), and C 29 ααα20S/(20S + 20R) sterane values for telalginite than for lamalginite and is also evident from the difference in activation energy distributions between lamalginite and telalginite source rocks. As determined from the relationships of sterane maturity parameters C 29 ββ/(αα + ββ) and C 29 ααα20S/(20S + 20R) vs EOM/TOC ratio and HCI values, the lower C 29 ββ/(αα + ββ) and C 29 ααα20S/(20S + 20R) limits for active source rocks were approximately 0.28 and 0.44, respectively. [ABSTRACT FROM AUTHOR]

The geochemical compositions of crude oils and Permian source rocks from the Mahu depression of the Junggar Basin were analyzed in this study. Based on tricyclic terpanes and isoprenoid biomarkers, three oil groups (I, II and III) can be identified that correspond to different source rock formations and organic facies. After examination of the influence of source facies and thermal maturity, and selected biomarker ratios based on carbazole isomers such as 1-MC/4-MC, 1,8-DMC/2,7-DMC and [a]/([a] + [c])-BC ratios in different oil groups, allowed us to determine the direction of hydrocarbon migration in different reservoirs. In addition, abundant oil inclusions are present with fluorescence colors ranging from yellow to blue-white. These were analyzed by FTIR to distinguish between different sources for the oils. Fluid inclusion petrography and microthermometry were also used to prove two stages of oil migration and their different sources. Taking into consideration possible migration pathways and likely driving forces, we conclude that abnormally high pressure in the Permian sequence acted as the main driving force for oil migration. The major migration pathways were vertical faults in the fault belts and slope areas, and sand bodies in the deeper areas. Group I 1 oils from P 1 f carbonate source rocks in the fault belts mainly migrated vertically through the faults and accumulated in T 1 b reservoirs in the Late Triassic, and were driven by excess formation pressure and buoyancy. Group I 2 oils in the slope areas first migrated vertically within thrust faults from P 1 f mudstone source rock in the Late Triassic, after which they migrated laterally over short distances to accumulate in T 1 b sand bodies. Group II oils from adjacent P 2 w source rocks in the center of the depression migrated mainly in the Late Jurassic, due to abnormally high pressure, and accumulated in nearby T 1 b traps. Some reservoir rocks in the slope area contain two generations of fluid inclusions, implying oil mixing from early-stage P 1 f oils and late-stage P 2 w oils, resulting in the group III oils. Combining these data from biomarkers, pyrrolic nitrogen compounds and fluid inclusions allowed us to construct models of migration and accumulation for oils in the Mahu depression. [ABSTRACT FROM AUTHOR]