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In the present work, the thermophilic aerobic membrane reactor technology was studied for the treatment of high strength aqueous wastes mainly containing dyes, surfactants and solvents. The thermophilic biomass resilience and the process stability under critical conditions (such as rapid rise of the mixed liquor pH, oxygen supply interruption, etc.) were also evaluated. The experimental work was carried out with the use of a pilot plant at semi-industrial scale, which was managed throughout for 14 months; the operation temperature was 49 °C and the organic loading rate was increased from 3 to 12 kgCOD m−3 d−1. Critical conditions, especially the interruption of oxygen supply, affected the pilot plant performance but did not cause a complete system break down. After the temporary reduction of process performance, also proven by the decrease in the oxygen consumption, the normal working conditions were restored. Moreover, the longer non-aerated phase involved a significant reduction (40%) of volatile suspended solids concentration in the biological reactor and the increase of 30% in foaming power; nevertheless, once the oxygen supply was reactivated, optimal conditions were rapidly restored. Therefore, the study showed the high resilience of the thermophilic biomass, which was able to recover full functionality after critical events. [ABSTRACT FROM AUTHOR]

A thermophilic aerobic membrane reactor (TAMR) treating high-strength COD liquid wastes was submitted to an integrated investigation, with the aim of characterizing the biomass and its rheological behaviour. These processes are still scarcely adopted, also because the knowledge of their biology as well as of the physical-chemical properties of the sludge needs to be improved. In this paper, samples of mixed liquor were taken from a TAMR and submitted to fluorescent in situ hybridization for the identification and quantification of main bacterial groups. Measurements were also targeted at flocs features, filamentous bacteria, and microfauna, in order to characterize the sludge. The studied rheological properties were selected as they influence significantly the performances of membrane bioreactors (MBR) and, in particular, of the TAMR systems that operate under thermophilic conditions (i.e., around 50°C) with high MLSS concentrations (up to 200 gTS L−1). The proper description of the rheological behaviour of sludge represents a useful and fundamental aspect that allows characterizing the hydrodynamics of sludge suspension devoted to the optimization of the related processes. Therefore, in this study, the effects on the sludge rheology produced by the biomass concentration, pH, temperature, and aeration were analysed. [ABSTRACT FROM AUTHOR]

Foam formation in the excess sludge treatment facilities of biological wastewater treatment plants (WWTPs) may represent a critical issue as it could lead to several operative problems and reduce the overall plant performance. This trouble also affects a novel technology recently proposed for sludge minimization, the thermophilic membrane reactor (TMR), operating with alternate aeration/non-aeration cycles. This technology, which has proven to be extremely resilient and suitable for treating industrial wastewater of different nature, demonstrated a high potential also as a solution for integrating existing WWTPs, aiming at the 'zero sludge production.' In this work, an experimental study was conducted with a TMR pilot plant (fed daily with thickened sewage sludge) by adjusting the duration of aeration/non-aeration alternate cycles. Extracellular polymeric substance (EPS) concentration (and its soluble and bound fractions) has been monitored along with foaming power indices. The results highlight that foaming can be correlated to the presence of soluble protein fraction of EPS. Moreover, EPS production seems to be reduced by increasing the duration of the non-aeration cycles: optimal operating conditions resulted 2 h of aeration followed by 6 h of non-aeration. These conditions allow to obtain an EPS concentration of 500 mg L with respect to 2300 mg L measured at the beginning of experimental work. [ABSTRACT FROM AUTHOR]

Sewage sludge processing is a key issue in water resource recovery facilities due to the inefficacy of conventional treatments to produce high quality biosolids to be safely used in agriculture. Under this framework, the performances of several enhanced stabilization processes, namely ultrasound-pretreated Mesophilic Anaerobic Digestion (US+MAD), thermophilic anaerobic digestion (TAD), thermal-pretreated TAD (TH+TAD) and ultrasound-pretreated inverse Temperature Phased Anaerobic Digestion (US+iTPAD) have been investigated. Such enhanced processes resulted in higher biogas yields and higher destruction of pathogens with respect to conventional MAD process, thus suggesting their feasibility in full-scale implementation perspectives. A procedure for technical-economic comparison of new sludge processing lines against conventional ones (benchmarking) was developed, based on the definition of technical issues (e.g. reliability, complexity, etc.) which are rated for each situation. Moreover, capital and operating costs were estimated. The enhanced processes analyzed in this work showed some potentially critical items, mainly related to energy balance and reagent consumption. Water Environ. Res., 88, 468 (2016). [ABSTRACT FROM AUTHOR]

Nowadays, several technologies and management strategies are proposed for upgrading wastewater treatment plants (WWTPs) in order to improve sludge stabilization or minimize sludge production. In order to make sure that this leads to overall improvements, their techno-economic and environmental performance has to be carefully evaluated. In response to this, the techno-economic and environmental performance was assessed for a considered model reference WWTP upgraded with separate treatment and disposal for primary and secondary sludge to provide guidance to research, policy and investment efforts. This paper departs in an experimental campaign carried out within the EU project “ROUTES” and describes an assessment of an upgrade of a WWTP, involving wet oxidation of primary sludge and thermophilic anaerobic digestion (integrated with thermal hydrolysis pre-treatment) for secondary sludge. The reference plant and the upgrade implied different disposal routes for the resulting sludges: incineration for the stabilized sludge deriving from the reference WWTP; agricultural land application for the secondary stabilized sludge from the upgraded plant and landfilling for the solid residue deriving from the wet oxidation process (as non-hazardous waste). The mass balance carried out for both reference and upgraded WWTPs showed a reduction of total sludge production (up to 45%) for the upgraded WWTP. The additional energy demand of the upgraded solution (+22.4 Wh/(PE d), PE: population equivalent) was partially balanced by the electric energy produced by combined heat and power unit installed in the upgraded WWTP (−18.08 Wh/(PE d)). The integrated assessment showed that the upgraded solution, although resulting in an increase of WWTP technical complexity, may contribute to environmental and economic advantages. The paper provides guidance in terms of which aspects need a more thorough evaluation when this upgrade is considered in real cases. [ABSTRACT FROM AUTHOR]

The increase of sewage sludge production together with the high treatment and disposal costs in the last years has pushed to study different solutions aimed at sludge minimization. In this paper, the thermophilic membrane technology was evaluated as an alternative for municipal sewage sludge reduction. The experimentation (carried out by means of a pilot scale plant, 1 m 3 volume) was divided into two steps: the first one was aimed at confirming the results obtained in a previous research focused on industrial sludge treatment; the second step was devoted to define the best process conditions (in particular the optimization of the aeration phases) and to the chemical permeate characterization. The results of the experiments highlight that the hydraulic retention time (HRT) and aeration conditions play a crucial role on the overall process performance. The volatile suspended solids removal efficiency was greater than 80% under the following conditions: HRT even lower than 15 d; 2 h of aeration - 6 h of non aeration cycles; and organic loading rate of 2.0 kgCOD m −3 d −1 . The permeate showed a good biodegradability under mesophilic conditions thus being treatable by means of conventional biological processes. Moreover, ammonia (the permeate presenting high concentrations) could be recovered as a fertilizer (stripping and subsequent washing of the exhausted gas is an established technique). Finally, the ammonia-free permeate can be valorised as a carbon source in denitrification processes. [ABSTRACT FROM AUTHOR]

The management of sewage sludge is becoming a more and more important issue, both at national and international level, in particular due to the uncertain recovery/disposal future options. Therefore, it is clear that the development of new technologies that can mitigate the problem at the source by reducing sludge production is necessary, such as the European Directive 2008/98/EC prescribes. This work shows the results obtained with a thermophilic membrane reactor, for processing a biological sludge derived from a wastewater treatment plant (WWTP) that treats urban and industrial wastewater. Sewage sludge was treated in a thermophilic membrane reactor (TMR), at pilot-scale (1 m 3 volume), with alternate aeration cycles. The experimentation was divided into two phases: a “startup phase” during which, starting with a psychrophilic/mesophilic biomass, thermophilic conditions were progressively reached, while feeding a highly biodegradable substrate; the obtained thermophilic biomass was then used, in the “regime phase”, to digest biological sludge which was fed to the plant. Good removal yields were observed: 64% and 57% for volatile solids (VS) and total COD (COD tot ), respectively, with an average hydraulic retention time (HRT) equal to 20 d, an organic loading rate (OLR) of about 1.4–1.8 kg COD m −3 d −1 and aeration/non aeration cycles alternated every 4 h. [ABSTRACT FROM AUTHOR]