9 results on '"2,4-DB"'
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2. [Fe(Ox)3]3- complex as a photodegradation agent at neutral pH: Advances and limitations.
- Author
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Pozdnyakov, Ivan, Sherin, Peter, Bazhin, Nikolai, and Plyusnin, Victor
- Subjects
- *
PHOTODEGRADATION , *HYDROGEN-ion concentration , *OXALATES , *PERSISTENT pollutants , *AQUEOUS solutions , *LIGANDS (Chemistry) - Abstract
In the present work advances and limitations in the application of Fe(III)-oxalate complexes (namely, [Fe(Ox) 3 ] 3- ) to the photodegradation of a model persistent organic contaminant - 2,4-dichlorophenoxybutanoic acid (2,4-DB) in neutral aqueous solutions were systematically investigated for the first time. It has been shown that the efficiency of [Fe(Ox) 3 ] 3- system greatly depends on the initial concentrations of oxalate ion due to the fast consumption of the ligand during photodegradation process leading to the formation of photochemically less active Fe(III) species. Efficiency of Fe(Ox) 3 3− system normalized to UVA absorption at the excitation wavelength is practically independent on [Fe(III)]. Thus, it is highly probable that concentrations of Fe(III) as low as < 10 −5 M could be applied in water treatment procedures using reactors with very long optical path. The system also keeps high efficiency at low concentration of pollutant (<10 −5 M) though this results in higher relative consumption rate of Fe(III) and oxalate ions. [ABSTRACT FROM AUTHOR]
- Published
- 2018
- Full Text
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3. PRE- and POST-applied herbicide options for alfalfa interseeded with corn silage
- Author
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Mark Renz, José Luiz C. S. Dias, William R. Osterholz, and John H. Grabber
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Bromoxynil ,Bentazon ,Plant Science ,Biology ,Mesotrione ,chemistry.chemical_compound ,Agronomy ,chemistry ,Metribuzin ,Glyphosate ,2,4-DB ,Acetochlor ,Weed ,Agronomy and Crop Science - Abstract
Establishment of alfalfa by interseeding it with corn planted for silage can enhance crop productivity but weed management is a challenge to adoption of the practice. Although a simple and effective approach to weed management would be to apply a glyphosate-based herbicide, concerns about herbicide resistance and limitations in available alfalfa varieties exist. Field experiments were conducted to compare the efficacy and selectivity of PRE, POST, and PRE followed by POST herbicide programs to a glyphosate-only strategy when interseeding alfalfa with corn. Experiment 1 compared PRE applications of acetochlor, mesotrione, S-metalochlor, metribuzin, and flumetsulam. Results indicate that acetochlor and metribuzin, and S-metalochlor used at a rate of 1.1 kg ai ha−1 were the most effective and selective PRE herbicides 4 wk after treatment (WAT), but each resulted in greater overall weed cover than glyphosate by 8 WAT. Experiment 2 evaluated applications of bentazon, bromoxynil, 2,4-DB, and mesotrione at early and late POST times. Several herbicides used POST exhibited similar effectiveness and selectivity as glyphosate, including early applications of bromoxynil (0.14 kg ai ha−1) and 2,4-DB (0.84 or 1.68 kg ai ha−1), as well as late applications of bromoxynil (0.42 kg ai ha−1), 2,4-DB (0.84 kg ai ha−1), and mesotrione (0.05 or 0.11 kg ai ha−1). A third experiment compared applications of acetochlor PRE, bromoxynil POST, and a combination of acetochlor PRE with bromoxynil POST. All treatments were effective and safe for use in this interseeded system, although interseeded alfalfa provided 65% to 70% weed suppression in corn planted for silage without any herbicide. Herbicide treatments had no observable impacts on corn and alfalfa yields, so weed management was likely of limited economic importance. However, weed competitiveness can vary based on several different factors including weed species, density, and site-specific factors, and so further investigations under different environments and conditions are needed.
- Published
- 2020
- Full Text
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4. Biodegradation of 1-alkoxy-2,4-dichlorobenzenes by Yarrowia lipolytica KCTC 17618.
- Author
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Lim, Do-Hyung, Lim, Da-Som, and Keum, Young-Soo
- Subjects
- *
BENZENE biodegradation , *CANDIDA lipolytica , *DICHLOROBENZENE , *FUNGAL metabolism , *FUNGAL metabolites , *GAS chromatography/Mass spectrometry (GC-MS) - Abstract
Detailed analyses of the biodegradation of 1-alkoxy-2,4-dichlorobenzenes by Yarrowia lipolytica KCTC 17618 were conducted by gas chromatography-mass spectrometry. Eight different 1-alkoxy-2,4-dichlorobenzenes with a linear alkylgroup (butyl to tetradecyl) were subjected to liquid culture. Y. lipolytica could rapidly metabolize short-chain analogues (butyl to hexyl) and utilize them as the sole carbon source for growth, whereas the analogues with longer alkyl groups were unable to support the growth but gradually metabolized in the nutrient media. The metabolic rates decreased with an increase of alkyl chain length up to a decyl group. Comprehensive metabolite analysis indicated that 4-(2,4-dichlorophenoxy)-butyric acid was the final metabolite of substrates with even-numbered alkoxy groups. 4-(2,4-dichlorophenoxy)-butyric acid is a well-known plant growth regulator and herbicide. In case of odd-numbered alkoxybenzenes, 3-(2,4-dichlorophenoxy)-propionic acid was the most abundant metabolite and no trace of 4-(2,4-dichlorophenoxy)-butyric acid was observed. These findings suggested that alkyl chain metabolism by the yeast follows a typical β-oxidation mechanism. The metabolism was partially inhibited by piperonylbutoxide, a common cytochrome P450 inhibitor. Dose-dependent production of 4-(2,4-dichlorophenoxy)-butyric acid from 1-butoxy-2,4-dichlorobenzene was evaluated. The maximum yield was 487 mg l −1 at 1 g l −1 of substrate. In summary, Y. lipolytica could efficiently produce 4-(2,4-dichlorophenoxy)-butyric acid from 1-alkoxy-2,4-dichlorobenzenesthrough oxidative metabolism. [ABSTRACT FROM AUTHOR]
- Published
- 2016
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5. Degradation of herbicide 2,4-dichlorophenoxybutanoic acid in the photolysis of [FeOH]2+ and [Fe(Ox)3]3− complexes: A mechanistic study.
- Author
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Pozdnyakov, Ivan, Sherin, Peter, Grivin, Vjacheslav, and Plyusnin, Victor
- Subjects
- *
HERBICIDES , *PHOTOLYSIS (Chemistry) , *PHOTODEGRADATION , *SUBSTITUENTS (Chemistry) , *HYDROXYLATION , *FLASH photolysis - Abstract
In the present work the Fe(III)-assisted photodegradation of the herbicide 2,4-dichlorophenoxybutanoic acid (2,4-DB) has been studied by means of stationary (308 nm) and laser flash (355 nm) photolysis. The initial quantum yield of 2,4-DB photodegradation in [FeOH] 2+ and [Fe(Ox) 3 ] 3− systems was evaluated to be 0.11 and 0.17 upon 308 nm exposure, respectively. The prolonged photolysis of [FeOH] 2+ and [Fe(Ox) 3 ] 3− systems results in the complete degradation of 2,4-DB with almost complete mineralization of herbicide and its aromatic products in the case of [FeOH] 2+ photolysis and the accumulation of some persistent aromatic products in the case of [Fe(Ox) 3 ] 3− photolysis. For both systems the main primary products of 2,4-DB photolysis determined by liquid chromatography – mass spectrometry are products of the hydroxylation, the substitution of chlorine atom to OH group, the loss of aliphatic tail and the opening of benzene ring. The obtained results indicate ROS species (mainly OH radical) to be responsible for the herbicide photodegradation. [ABSTRACT FROM AUTHOR]
- Published
- 2016
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6. Effect of Sequential Applications of Protoporphyrinogen Oxidase-Inhibiting Herbicides on Palmer Amaranth (Amaranthus palmeri) Control and Peanut Response
- Author
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Jason A. Ferrell, Venancio J. Fernandez, Benjamin P. Sperry, Ramon G. Leon, Hunter C. Smith, and Clyde A. Smith
- Subjects
0106 biological sciences ,Acetolactate synthase ,biology ,Bentazon ,Amaranth ,04 agricultural and veterinary sciences ,Plant Science ,Acifluorfen ,biology.organism_classification ,01 natural sciences ,Amaranthus palmeri ,chemistry.chemical_compound ,Agronomy ,chemistry ,2,4-DB ,040103 agronomy & agriculture ,biology.protein ,0401 agriculture, forestry, and fisheries ,Protoporphyrinogen oxidase ,Agronomy and Crop Science ,010606 plant biology & botany ,Lactofen - Abstract
Two experiments were conducted in 2013 and 2014 in Florida to evaluate the effects of protoporphyrinogen oxidase (PPO)-inhibiting herbicides and single versus sequential applications on Palmer amaranth control and peanut injury. Protoporphyrinogen oxidase-inhibiting herbicides are among the last available herbicides for the POST control of acetolactate synthase (ALS)-resistant Palmer amaranth in peanut. Lactofen (219 g ai ha–1) applied 5 d after the initial application provided the highest level of Palmer amaranth control 7 and 14 d after initial application (DAIT). Delaying sequential applications of lactofen to 15 d resulted in the highest level of Palmer amaranth control 21 and 28 DAIT. Similar to Palmer amaranth control, foliar injury to peanut was often highest from lactofen applications, and by 28 DAIT lactofen treatments were the only treatments that caused foliar injury. Although no statistical difference was observed between yields of plots treated with acifluorfen (280 g ai ha–1), bentazon (560 g ai ha–1), 2,4-DB (280 g ae ha–1) alone or in combination with each other, plots treated with sequential applications of lactofen 5 or 15 DAIT produced the lowest yields. Sequential applications of lactofen applied 15 DAIT controlled Palmer amaranth more effectively than any other treatment but also caused the highest level of peanut injury. The use of sequential applications of lactofen was the most effective method for control of Palmer amaranth in this study, but did reduce peanut yield.
- Published
- 2017
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7. Tolerance of Three Clovers (Trifoliumspp.) to Common Herbicides
- Author
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James D. McCurdy, J. Scott McElroy, Michael L. Flessner, Ethan T. Parker, and Jared A. Hoyle
- Subjects
0106 biological sciences ,Imazaquin ,Bentazon ,Simazine ,04 agricultural and veterinary sciences ,Plant Science ,Biology ,Weed control ,01 natural sciences ,Clopyralid ,chemistry.chemical_compound ,chemistry ,Agronomy ,Metribuzin ,Glyphosate ,2,4-DB ,040103 agronomy & agriculture ,0401 agriculture, forestry, and fisheries ,Agronomy and Crop Science ,010606 plant biology & botany - Abstract
Clover inclusion may increase the sustainability of certain low-maintenance turfgrasses. However, selective weed control within mixed turfgrass–clover swards proves problematic because of clover susceptibility to herbicides. Research was conducted to identify common turf herbicides that are tolerated by threeTrifoliumspecies, including white clover, ball clover, and small hop clover, within low-maintenance turfgrass. Leaf and flower density, as well as plant height, were measured 4 wk after treatment as indicators of clover response to 14 herbicides. The threeTrifoliumspp. were moderately tolerant of bentazon (< 35% decrease in leaf density, height, or flowering). Simazine was well tolerated by white clover (< 5% decrease in all response variables), yet moderate injury to ball clover and small hop clover was observed (> 32% decrease in leaf density and > 27% decrease in flower density). Pronamide was well tolerated by white and ball clovers, with no effect on measured response variables; however, pronamide decreased small hop clover height and flower density (38 and 42%, respectively). Imazethapyr and imazamox were moderately well tolerated by white clover and small hop clover (< 39% decrease by all response variables), yet ball clover may be more susceptible to these herbicides than was anticipated based on previously reported tolerance. The herbicides 2,4-DB, halosulfuron, and metribuzin were well tolerated by white clover, with no effect on measured response variables; however, results suggest ball and small hop clovers were less tolerant. Clopyralid, 2,4-D, glyphosate, imazaquin, metsulfuron-methyl, and nicosulfuron resulted in varying degrees of injury across clover species and response variables, but, in general, these herbicides may not be viable options when attempting to maintain any of the three clover species tested. Further research is needed to quantify long-term effects of herbicide application on sward composition and clover succession.
- Published
- 2016
- Full Text
- View/download PDF
8. Effects of Herbicides on Sclerotinia Crown and Stem Rot of Alfalfa
- Author
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R. M. Sulc, M. M. Loux, L. H. Rhodes, and S. L. Reichard
- Subjects
chemistry.chemical_classification ,biology ,Bromoxynil ,Inoculation ,Plant Science ,biology.organism_classification ,chemistry.chemical_compound ,Horticulture ,chemistry ,Auxin ,Seedling ,2,4-DB ,Botany ,Sclerotinia trifoliorum ,Stem rot ,Agronomy and Crop Science ,Sclerotinia - Abstract
This study was conducted to determine whether herbicides and adjuvants registered for poste-mergence use in alfalfa have an effect on Sclerotinia crown and stem rot (SCSR). In a controlled environment, disease severity index (DSI) of alfalfa seedlings was reduced by pronamide and 2,4-DB compared with the untreated control, whereas bromoxynil and 13% sethoxydim + petroleum-based adjuvant (PBA) increased DSI. In the field, disease severity in all herbicide treatments was similar to that in untreated alfalfa. In a second controlled-environment study, pronamide and 2,4-DB reduced DSI compared with the no herbicide control when seedlings were inoculated 1 day after herbicide application, but this protective effect was not observed when seedlings were inoculated 8 days or longer after herbicide application. The results demonstrate that several herbicides are capable of suppressing or enhancing SCSR severity in a controlled environment if seedling inoculation occurs soon after herbicide application; however, the residual effect of these herbicides on SCSR appeared to be much shorter than the 4- to 6-week infection period occurring in the field.
- Published
- 2019
9. Yield and phytotoxicity responses of subterranean clover (Trifolium subterraneum L.) sprayed with different herbicides for broadleaf weed control
- Author
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Lewis, Teresa Rose
- Subjects
- Trifolium subterraneum L., New Zealand, 2,4-DB, Bentazone, Bromoxynil, Diflufenican, Flumetsulam, Imazethapyr, MCPB, Saflufenacil, subterranean clover, dryland pasture, broadleaf weeds, herbicides, cocksfoot, phytotoxicity, ANZSRC::070308 Crop and Pasture Protection (Pests, Diseases and Weeds), ANZSRC::070302 Agronomy
- Abstract
A key factor for integrating subterranean clover into pastoral systems is its success in the establishment year. With appropriate management, establishment ensures productivity and persistence in future years. This thesis investigated the relative herbicide tolerance of subterranean clover at the seedling stage for pasture establishment in New Zealand rain-fed environments. This involved quantification of the field response to herbicides, at different seedling development stages of subterranean clover cultivars. Four experiments, two arranged as split-plot, and two as split-strip-plot, were established in Canterbury, New Zealand in autumn 2016. Emergence of Experiments 1 and 2 occurred in late-March, while Experiments 3 and 4 were delayed by lack of rainfall. A cultivar*herbicide interaction was identified in all experiments, confirming that cultivars were different in their response to herbicides. The cultivar ‘Narrikup’ showed the greatest herbicide tolerance to imazethapyr across all experiments, with sown clover yields of 2600-3500 kg DM/ha. All yanninicum cultivars (‘Monti’, ‘Napier’, and ‘Trikkala’) were not suited to the environmental conditions of the season and failed to persist following herbicide applications. The subterranean clover subspecies brachycalycinum cultivar ‘Antas’ showed variable herbicide tolerance, with responses of developmental delay as well as yield depression. The white clover control was consistently the lowest yielding at 2000 kg/ha more than their unsprayed unweeded controls. For cocksfoot/clover mixtures only ‘Narrikup’ had no reduction in total dry matter yields compared to unsprayed unweeded controls when imazethapyr was applied. Cocksfoot productivity was slowed by imazethapyr up to 24 weeks after application, with yields 750 kg/DM lower than the unsprayed unweeded controls. Pastures recovered to be no different in November, and cocksfoot can be expected to continue to provide summer grazing after the annual clovers set seed. The early reduction in cocksfoot productivity allowed >20% increases in the clover component of imazethapyr treated swards. Experiments 3 and 4 found that the ALS-inhibiting herbicides imazethapyr and flumetsulam, and photosynthesis-inhibitor bentazone were the least damaging herbicides to subterranean clover. Experiment 3, where plants were treated at the 1-2 trifoliate leaf stage had higher subterranean clover yields when compared to Experiment 4, where herbicide was applied at the 4-6 trifoliate leaf stage. The early seedling herbicide application had less impact on yields than prolonged competition from weeds. Combined sown+resident clover yields showed that sowing cultivar mixes can improve subterranean clover herbicide tolerance and increase total yields. Both application times for Imazethapyr, flumetsulam, and bentazone had mean total clover yields the same as or greater than the unsprayed unweeded controls. 2,4-DB had a negative impact on the development of all subterranean clover plants. For the remaining herbicides bentazone + MCPB, bromoxynil + diflufenican, and MCPB, ‘Antas’ and resident ‘Woogenellup’ were susceptible to developmental delays as a result of application, while ‘Denmark’ and ‘Narrikup’ were less adversely affected. Imazethapyr + saflufenacil, and glyphosate treatments killed all vegetation and left ground bare in all experimental applications, confirming they are unsuitable for use in subterranean clover-containing pastures. This research confirmed a cultivar*herbicide interaction to a range of herbicides, and identified imazethapyr, flumetsulam and bentazone as suitable for use during establishment of subterranean clover based pastures. Longer term effects, such as those on subsequent regeneration and further investigations into effects on development, as well as the apparent brachycalycinum susceptibility are advised.
- Published
- 2017
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