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Hollow porous AuAg nanospheres (AuAg HPNSs) were obtained through a simple solvothermal synthesis, complemented by a dealloying strategy. The hollow interior, open pore voids, and integral interconnected skeleton shell in AuAg HPNSs are beneficial for providing sufficient electrolyte diffusion and contacts, abundant active sites, and efficient electron transport. This specific structure and the favorable alloy synergism contribute to the superior electrocatalytic activity toward dopamine (DA) and acetaminophen (AC). AuAg HPNSs show high sensitivity, good selectivity, excellent sensing durability, and outstanding repeatability for amperometric assays of AC and DA. In particular, the AuAg-based sensors achieve effective ultrasensitive simultaneous analyses of AC and DA, exhibiting the characteristics of the wide linear range and low detection limit. With their prominent electrocatalytic activity and simple preparation methods, AuAg HPNSs present broad application prospects for constructing a highly responsive electrochemical sensing system. [ABSTRACT FROM AUTHOR]

Summary: Shewanella strains are characterized by versatile metabolic capabilities, resulting in their wide distribution in the ocean at different depths. Considering that particle sedimentation is an important dynamic process in the ocean, we hypothesized that hadal Shewanella species evolved from the upper ocean. In this study, we isolated three novel Shewanella strains from deep‐sea sediments in the Southwest Indian Ocean. Genome sequencing indicated that strains YLB‐06 and YLB‐08 represent two novel species in the genus Shewanella. Through phylogenomic analysis, we showed that speciation and genomic changes in marine Shewanella strains are related to water depth. We further confirmed the aforementioned hypothesis and revealed a two‐stage process of the evolutionary transition of Shewanella from the upper ocean to the hadal zone by comparative genomics and gene gain/loss analysis. Finally, the transcriptomic analysis demonstrated that recently obtained genes are strictly repressed and may thus play a minor role in the response to environmental changes. [ABSTRACT FROM AUTHOR]

The interaction between biological surfactant sodium deoxycholate (NaDC) and nonionic surfactants polyoxyethylene (n) nonylphenol ether (NPn) for the formation of micelles in aqueous solution were investigated. Surface tension, interfacial dilational viscoelasticity, and transmission electron microscopy (TEM) were characterized to systematically study the interaction between NaDC and NPn in buffer solution. At last, the mechanism of the interaction between NPn and NaDC were analyzed. The surface tension results show that the interaction between NaDC and NPn was displayed synergism action. The composition of the mixed systems has been estimated on account of the regular solution theory, Clint's equation, Rubingh theory and Rosen theory. The surface dilational rheology provided abundant effective information on the feature of adsorbed layers. From the oscillating barrier measurements, the peak values of the dilational modulus moved to lower concentrations in NaDC/NPn binary system compared to single surfactant. The dilational elasticity of the binary system decreased distinctly on the basis of the rigid structure of NaDC. The interaction of these two substances was proved directly by TEM images, that the boundaries of the aggregates are clearer due to the protection of NPn molecules. The new complex systems have potential application in environmental protection. Schematic illustration of the aggregation in NPn/NaDC mixed systems and concentration increased from left to right. [ABSTRACT FROM AUTHOR]

Microbacterium sediminis YLB-01 T , a piezotolerant and psychrotolerant actinomycete, was isolated from deep-sea sediment of the South-West Indian Ocean and could be a good model for understanding the adaptation of extremophiles to the benthic piezosphere. Here, we report the analysis of the complete genome sequence of strain YLB-01 T . The genome sequence consists of a single circular chromosome comprising 2,792,195 bp and a linear plasmid comprising 127,669 bp with G + C content of 71.76 and 68.49 mol%, respectively. In this regard, strain YLB-01 T possesses the smallest genome size but the highest G + C content among the genus Microbacterium sequenced to date. As the first complete genome sequence of the genus Microbacterium isolated from deep-sea environment, the strain YLB-01 T genome is unique or enriched in genes involved in xenobiotics biodegradation and metabolism, compatible solutes, and transposases, some of which might be related to bacterial enhancement of ecological fitness in the deep sea., (Copyright © 2020 Elsevier B.V. All rights reserved.)