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1. A novel application of the Staudinger ligation to access neutral cyclic di-nucleotide analog precursors via a divergent method.

Author

Fletcher MH, Burns-Lynch CE, Knouse KW, Abraham LT, DeBrosse CW, and Wuest WM

Abstract

Our efforts to develop a scalable and divergent synthesis of cyclic di-nucleotide analog precursors have resulted in (1) an orthogonally protected di-amino carbohydrate as well as (2) the novel application of the Staudinger ligation to provide medium-sized macrocycles featuring carbamate or urea linkages.

Published
2017
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