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Particle tracking (PT) is a popular technique in microscopy, microfluidics and colloidal transport studies, where image analysis is used to reconstruct trajectories from bright spots in a video. The performance of many PT algorithms has been rigorously tested for directed and Brownian motion in open media. However, PT is frequently used to track particles in porous media where complex geometries and viscous flows generate particles with high velocity variability over time. Here, we present an evaluation of four PT algorithms for a simulated dispersion of particles in porous media across a range of particle speeds and densities. Of special note, we introduce a new velocity-based PT linking algorithm (V-TrackMat) that achieves high accuracy relative to the other PT algorithms. Our findings underscore that traditional statistics, which revolve around detection and linking proficiency, fall short in providing a holistic comparison of PT codes because they tend to underpenalize aggressive linking techniques. We further elucidate that all codes analyzed show a decrease in performance due to high speeds, particle densities, and trajectory noise. However, linking algorithms designed to harness velocity data show superior performance, especially in the case of high-speed advective motion. Lastly, we emphasize how PT error can influence transport analysis.

In this work, large-eddy simulations of hydrogen dispersion from turbulent subsonic hydrogen-gas emissions in a 5.8 × 0.9 × 0.8 m 3 open-ended channel are described. Such numerical modeling of hydrogen-related processes can provide new insights into the safety aspects of hydrogen, an increasingly more common energy carrier, particularly related to explosion hazards. Ten simulations, with jet mass flow rates ranging from 0.08 g/s to 1.27 g/s, have been simulated using the open-source OpenFOAM® 10 suite. The predicted concentrations in the channel are compared to corresponding experimental data, generally showing good agreement. Two distinct dispersion regimes are observed from the numerical data; a strongly stratified "filling box" regime is found for hydrogen mass flows ≲ 0. 15 g/s, whereas a more homogenized "fading box" regime emerges for higher mass flows. Based on the local Froude number in the channel, a novel model for the momentum length scale of the hydrogen jet is proposed, applicable to downward, strongly buoyant (i.e., non-Boussinesq) jets. It is demonstrated that the ratio of this length scale to the vertical length scale of the geometry can be used to predict the dispersion regime, which may benefit simplified predictive models for hydrogen concentrations and, consequently, ignition risks. • Experimental and numerical study of hydrogen dispersion in an open-ended channel. • Subsonic, turbulent jets with mass flows from 0.09 to 1.27 g/s. • Predicted concentrations compared to experimental measurements at 29 locations. • Two dispersion regimes, "filling box" and "fading up box", identified. • A new jet momentum-length model for strongly buoyant, downward jets is proposed. [ABSTRACT FROM AUTHOR]

In this study, the dispersion and explosion of liquid hydrogen (LH 2) in leakage accidents are investigated using the Flame Accelerator Simulator (FLACS) code. The study focus was a liquid hydrogen research facility in Gimhae, South Korea. Simulations were conducted under various conditions by varying the mass flow rates (0.61 and 0.3 kg/s), directions (lateral in areas with minimal structures, lateral towards a tube trailer truck, and downward), and durations (90 and 180 s) of leakage. The results indicated that higher leakage mass flow rates produce a larger flammable cloud volume (FCV), resulting in higher maximum overpressures than that caused by lower flow rates. Downward leakage generally resulted in a larger FCV and higher overpressure than lateral leakage. The explosion characteristics were also influenced by geometry of LH 2 facility, including the presence of structures in the leakage path. Contrastingly, leakage duration had a minimal effect on the maximum overpressure because an increased duration causes a greater dilution of hydrogen, only slightly expanding the FCV. According to the overpressure–impulse diagram, higher leakage flow rates cause severe health risks, approaching thresholds for lung rupture and 100% fatality. Contrary to the minor damages caused by lower leakage flow rates. High flow rates, particularly with downward leaks, can cause significant structural damage in brick buildings, potentially leading to partial demolition. • Higher leakage mass flow rates result in larger flammable cloud volumes and increased maximum overpressures. • Downward hydrogen leaks lead to larger flammable clouds and higher overpressures than lateral leaks. • Facility geometry and structures significantly affect explosion overpressure magnitude and distribution. • Leakage duration has a minimal effect on maximum overpressure due to hydrogen dilution during leakage. [ABSTRACT FROM AUTHOR]

Understanding hydrogen dispersion in a semi-confined space is crucial for the safe operation of hydrogen-related systems, such as hydrogen fuel cell vehicles. Analyzing hydrogen release and its subsequent dispersion can be effectively conducted using computational models, which necessitate experimental measurements for validation. For safety reasons, accidental scenarios are frequently replicated using helium as a hydrogen simulant in experiments, despite some concerns about the comparability of helium and hydrogen dispersions. Hence, this study conducts a comprehensive parametric numerical analysis of the similarities between hydrogen and helium dispersion when released in a semi-confined space. The model is based on the Macquarie Dispersion Chamber and the simulation results are first validated against the measurements. The study focuses on the impact of the leakage rate and ventilation velocity. Three release models were analysed: equal concentration (Method A), equal volumetric flow rate (Method B), and equal buoyancy (Method C). This study extends previous research on Method B, used for gas release in open spaces, to environments where flow-wall interactions become important. It also compares Methods A and C for a few scenarios, examining variations in concentration distribution, purge time, and activation time under different conditions. In the absence of ventilation, Method B effectively compares hydrogen and helium flow rates by accounting for volumetric flow rates, regardless of buoyancy effects. However, under increased ventilation velocities, Method A and Method C exhibit superior agreement across sensors, highlighting the necessity of choosing detection methods according to prevailing environmental conditions. [Display omitted] • A CFD model for gas release in semi-confined space equipped with ventilation is established. • Three release models are studied to investigate similarity between hydrogen and helium gas dispersion. • Purge time and activation time are analysed with the aim of safe hydrogen infrastructure development. • Influence on gas dispersion by various ventilation velocity and flow rate at leakage are analysed. [ABSTRACT FROM AUTHOR]

The diffraction efficiency of blaze gratings is optimized only at a specific frequency due to a fixed blaze angle, resulting in reduced and variable diffraction efficiencies over the working frequency band. Additionally, blazed gratings demonstrate polarization dependence due to their groove structures and the interaction of light with their surfaces. Consequently, designing gratings with constant diffraction efficiencies across a wide frequency bandwidth while maintaining polarization independence remains a challenge. Here, a design paradigm of dispersion engineerable meta‐grating inspired by orthogonal harmonic oscillations (OHO) is presented. Utilizing the OHO model, the phase dispersion of a metasurface can be precisely controlled, which applies to any unit cell featuring two orthogonal electromagnetic resonances. As a proof of concept, a polarization‐insensitive meta‐grating is showcased, where the blazed angle adapts with the incident frequency, ensuring broadband performance. In the experiment, the adaptively‐blazed grating measured an optimized and constant diffraction efficiency of ≈80% over the working wavelength range, i.e., 8.7–12.2 µm. The difference in diffraction efficiency between the two perpendicular linear polarization states remains within 4.6%. The proposed paradigm paves the way for meta‐device design based on precise dispersion engineering, which has potential applications in spectrometers, broadband beam forming and steering, hyperspectral imaging, etc. [ABSTRACT FROM AUTHOR]

The twin zero group velocity (ZGV) points are observed, which belong to the fundamental symmetric branch (S0) of Lamb waves propagating in a composite traction-free layered plate containing odd number of layers with alternating physical properties. It is shown that in a vicinity of these ZGV points an ambiguity of dispersion spectrum takes place, resulting in the appearance of several waves, which (i) belong to the same fundamental mode; (ii) satisfy the same boundary conditions; and, (iii) propagate at the same frequency, however (iv) with different phase velocities. The analysis is based on a combination of Cauchy formalism and the exponential fundamental matrix method. [ABSTRACT FROM AUTHOR]

The dispersion of nano‐SiO2 (NS) in cement plays a critical role in enhancing the properties of cementitious materials. In this study, the combination of ultrasonic dispersion and polycarboxylic acid water reducing agent (PCE) was used to significantly improve the dispersion of NS. The effects of ultrasonic dispersion time, NS content, and PCE content on dispersion quality were investigated, alongside their impact on mechanical properties, electrical resistivity, and frost resistance. The results demonstrated that this synergistic method optimized the dispersion of NS, leading to superior mechanical properties and frost resistance. With an ultrasonic dispersion time of 40 min, NS content of 1.0 wt.%, and PCE content of 0.75 wt.%, the cement paste achieved its optimal performance. Compared to non‐dispersed samples, compressive strength increased by 33.7%. After 75 freeze–thaw cycles, the mass loss was 2%, the relative dynamic elastic modulus was 99.15%, and the strength loss was 13.74%. [ABSTRACT FROM AUTHOR]

Fiber optic research continues to develop due to the need for fast information technology. The input signal in an optical fiber is in the form of a soliton wave that propagates in the fiber with a balanced index of refraction, dispersion, and diffraction. Fiber optics may lose some of the signal over time if they solely use a nonlinear refractive index. This study aims to examine into the dynamics and decoherence of multi-peak solitons caused by electromagnetic signal attenuation and potential trap in the propagation via optical fibers. The methods used start with the stationary solution of the nonlinear Schrödinger Cubic Quintic equation, the Newton-Raphson method, and the fourth-order Runge-Kutta. In stationary solutions, the p (state energy) and ρ (Lèvy index) values affect the number, pulse width, and height of soliton peaks. Increased p and ρ values lead to increased instability, causing the data transmitted into the optical fiber to collapse and become unreadable by the receiver. In the excited state (p > 0), the decoherence phenomenon occurs and causes wave instability and destruction. In term of energy intensity, a stable form of transmission in the ground state has a pattern of continuously weakening, decreasing, and smoothing, while in the excited state there is a spike in the intensity of the electromagnetic wave. Based on this study, multi-peak solitons can only be applied for propagation distances, which tend to be short due to their dynamics and decoherence. [ABSTRACT FROM AUTHOR]

Research into particulate polymer composites is of significant interest due to their potential for enhancing material properties, such as strength, thermal stability, and conductivity while maintaining low weight and cost. Among the various techniques for preparing particle-based composites, ultrasonic wave stimulation is one of the principal laboratory-scale methods for enhancing the dispersion of the discontinuous phase. Nevertheless, there is a scarcity of empirical evidence to substantiate the impact of stimulating materials with natural sound frequencies within the acoustic spectrum, ranging from 20 Hz to 20 kHz, during their formation process. The present work investigates the effect of acoustic stimuli with frequencies of 56, 111, and 180 Hz on the properties of an acrylic-based polymer and its discontinuous carbon-based composites. The results indicated that the stimulus frequency affects the cure time of the studied systems, with a notable reduction of 31% and 21% in the cure times of the neat polymer and carbon-nanofiber-based composites, respectively, after applying a frequency of 180 Hz. Additionally, the higher stimulation frequencies reduced porosity in the samples, increased the degree of dispersion of the discontinuous phase, and altered the composite materials' thermal, optical, and electrical behavior. [ABSTRACT FROM AUTHOR]

This paper investigates a quantitative comparison of the Love wave propagation due to traction-free and rigid boundary surfaces on the piezoelectric-dispersive layer over a non-dispersive initially stressed half-space. The model is considered (a) transversely isotropic piezoelectric material in the upper layer, (b) exponentially increasing dispersive (non-homogeneous) layer in the intermediate, and (c) initially stressed non-dispersive (homogeneous) medium in the lower half-space. Electrical potential fields in the piezoelectric layer are defined in terms of electrical potential function with open and short circuit piezoelectricity using the quasi-static Maxwell's equation. We have derived analytical dispersion relations for two cases of boundary conditions: (i) free surface with zero tractions and (ii) rigid boundary, in both the open and short circuit cases. The validities of the dispersion relations are shown by deriving some particular cases and compared with the classical dispersion relation of the Love wave. A novel numerical representation of changes in displacement amplitude with depth and comparative effect of various piezoelectric materials such as PZT-4, PZT-5A, PZT-7A, and BaTiO3 are shown using MATLAB software. The rigid boundary surface case is more effective than traction-free boundary surfaces in terms of electromechanical coupling factor. It is also identified that there are significant effects on the dispersion of the Love-type waves due to different boundary conditions on the upper surface of the model. These comparative studies highlight the present work and may be helpful in the fields of solid mechanics and material fabrication processes. [ABSTRACT FROM AUTHOR]

Basalt fibers were widely used as reinforcing matrix materials because of their thermal and chemical stability and environmental friendliness. The properties of composite materials were affected by the interaction between the basalt fibers and matrix materials. Surface modification of basalt fibers and the dispersion property have become key points of research in recent years. This study focuses on the impact of a dispersant on surface modification. Basalt fibers were dispersed by polyethylene glycol (PEG) before modification with 3-aminopropyltriethoxysilane (KH550), which significantly increased the surface roughness, thus increasing the surface area and facilitating mechanical bonding. The morphology, structure, and composition were characterized via scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), and X-ray photoelectron spectroscopy analysis (XPS), respectively. The distribution characteristics of fiber were evaluated by the response surface method. When the mass fraction of PEG was 0.5 wt.%, the modification time was 2.5 hours, and the modification temperature was 60°C, the fiber dispersion degree in KH550 solution reached 83%. The grafting degree test indicates that the weight of the grafting increased to 6.67 times that of the undispersed basalt fibers. This enhancement allowed for greater grafting of the KH550, thereby optimizing the effect of modified fibers. [ABSTRACT FROM AUTHOR]

Fullerene has been acknowledged as a significant nanocarbon nanofiller enhancing the imperative polymer characteristics. Since, thermoplastic polymers constitute a large group of polymeric materials, fullerene has been used as reinforcement in these matrices mostly via non-covalent means. This state-of-the-art review article summarizes thermoplastic polymer nanocomposites reinforced with fullerene nano-additives without involving any covalent interactions. Accordingly, thermoplastic polymer/fullerene nanocomposites of interest have non-covalent or physical interactions in the matrix-nanofiller such as van der Waals forces, electrostatic interactions, hydrogen bonding, and aromatic stacking interactions. Number of thermoplastic polymers including polyamide, polyurethanes, and block copolymers have been non-covalently or physically reinforced with the fullerene molecules. Ensuing high performance thermoplastic polymer/fullerene nanocomposites exhibited improved microstructure, electrical, mechanical, thermal, and other physical properties. Enhancements in the thermal, mechanical, and electrical properties of the thermoplastic/fullerene nanomaterials were found dependent upon the nanofiller contents, orientations, interfacial effects, and processing. Consequently, the polyamide/fullerene systems were found efficient to enhance the glass transition up to 260°C, in addition to optimum mechanical properties. Polyurethane/fullerene systems performed better for improved tensile strength and young's modulus features up to 90 MPa and 48 GPa, respectively. System based on poly (methyl methacrylate) and fullerene has resulted in high thermal degradation temperature in the range of 501-633°C with fine electrical conductivity of 1.3 Scm−1. Using combination of fullerene and graphene nanofiller (due to synergistic effects) has been found to improve the electrical conductivity considerably in the range of 1.8–2.5 Scm−1 for a polystyrene and block copolymer system. However, attaining fine fullerene nanoparticle dispersion of non-covalently reinforced matrices have been found important affecting the final nanocomposite properties. Consequently, processability and essential characteristics of non-covalently fullerene filled nanocomposites can be influenced due to nanoparticle aggregation. Hence, the physical property enhancement potential of physical linking between the non-covalently linked thermoplastics-fullerene has been portrayed in this article. Research on non-covalently interacted thermoplastic polymer/fullerene nanocomposites revealed technical potential ranging from energy/electronic devices to engineering and biomedical sectors. This review article can be a useful guide for the field researchers towards the development of advanced systems using non-covalently linked polymer/fullerene nanomaterials for future technical applications. [ABSTRACT FROM AUTHOR]

We investigated the Diels‐Alder reaction of 6,13‐bis(triisopropylsilylethynyl)pentacene (1) with small dienophiles such as (bridged) dihydronaphthalenes/cyclohexenes that yielded adducts at the central ring, the other dienophiles predominantly or exclusively attacked the unsubstituted off‐center ring. The difference in regioselectivity was investigated by DFT calculations. Apart from dispersion interactions, it is due to the steric demand of the dienophiles, which need to fit in between the silylethynyl substituents to react at the central ring. Epoxynaphthalene adducts of 1 as well as its anthracene and tetracene congeners were deoxygenated, easily furnishing triarenobarrelenes with TIPS‐ethynyl substituents at the bridgeheads, attractive building blocks for porous solids and higher acene‐based trimers. [ABSTRACT FROM AUTHOR]

AbstractThe experimental study assessed the impact of choline chloride cation-based ionic liquid (IL), on the dispersion stability and wear characteristics of copper (II) oxide (CuO) nanoparticles (NPs) in synthetic base oil (PAO 10). CuO NPs, averaging 50 nm in size, underwent surface modification using varying concentrations of the IL (0.25%, 0.5%, 0.75%, and 1% by weight). The formulations were subjected to sliding wear tests to evaluate their wear behavior. Analysis of the worn surfaces utilized scanning electron microscopy, energy-dispersive x-ray spectroscopy, and atomic force microscopy. The results indicated that the combination of 0.75% IL and 1% CuO NPs provided optimal dispersion and exhibited effective surface mending, enhancing wear protection by 21.1% than that of PAO 10. The formulation containing 1% IL and 1% CuO NPs demonstrated the highest load carrying capacity among all tested compositions. In terms of wear behavior, the nanolubricant formulations with 0.75% and 1% IL outperformed the lubricant formulation containing 1 wt% of the commercial antiwear additive Zinc dialkyldithiophosphates (ZDDP). [ABSTRACT FROM AUTHOR]

Mechanistic investigations at the density functional theory level of organic and organometallic reactions in solution are now broadly accessible and routinely implemented to complement experimental investigations. The selection of an appropriate functional among the plethora of developed ones is the first challenge on the way to reliable energy barrier calculations. To provide guidelines for the choice of an initial and reliable computational level, the performances of commonly used non‐empirical (PBE, PBE0, PBE0‐DH) and empirical density functionals (BLYP, B3LYP, B2PLYP) were evaluated relative to experimental activation enthalpies. Most reactivity databases to assess density functional performances are primarily based on high level calculations, here a set of experimental activation enthalpies of organic and organometallic reactions performed in solution were selected from the literature. As a general trend, the non‐empirical functionals outperform the empirical ones. The most accurate energy barriers are obtained with hybrid PBE0 and double‐hybrid PBE0‐DH density functionals, both providing similar performance. Regardless of the functional under consideration, the addition of the GD3‐BJ empirical dispersion correction does not enhance the accuracy of computed energy barriers. [ABSTRACT FROM AUTHOR]

AbstractAn investigation on the propagation of bending waves along the edge of a piezoelectric thin plate resting on an elastic foundation (cf. Pasternak foundation) and under the action of a point-load is carried out in this paper. The displacement field of the plate is based on the classical plate theory. The Kelvin-Voigt type viscoelastic model is used to examine the viscous effect on the characteristics of the bending wave. The Moore-Gibson-Thompson (MGT) thermoelastic equation is solved for an external time variant harmonic heat source at the upper surface of the plate. The piezoelectric potential is obtained for an electrode-covered upper surface and an electrically shorted lower surface. The displacements of the propagating bending wave along the edge are examined under a time-harmonic point-load acting near the vicinity of the free edge of the plate. The well-known Green function technique and Fourier transform method are implemented to generate an analytical solution for the non-homogeneous boundary value problem. The examination of the derived explicit form of the dispersion relationship and the displacements of the bending edge wave under external loading are discussed and presented both analytically and graphically, and the results are summarized. [ABSTRACT FROM AUTHOR]

Two‐photon polymerization 3D‐printing is a well‐known technique for fabricating passive micro/nanoscale structures, such as microlenses and inversely designed polarization splitters. The integration of light emitting nanoparticle (NP) dopants, such as quantum dots (QDs) and rare‐earth doped nanoparticles (RENPs), into a polymer resist would enable 3D printing of active polymer micro‐photonic devices, including sensors, lasers, and solid‐state displays. Many NPs contain oleic acid ligands to prevent degradation, but oleate‐capped NPs (oc‐NPs) tend to agglomerate in nonpolar media despite the hydrophobicity of the ligand. This results in an uneven nanoparticle distribution and increased optical extinction. In this work, a general approach is proposed for dispersing oc‐NPs in commercial 3D printable polymers. Controlled growth of small carbon chains around the oc‐NPs is achieved by functionalizing them with methyl‐methacrylate monomers. The proposed approach is validated on RENPs (≈65 nm) and CdSe/ZnS quantum dots (≈12 nm) using commercial polymer resists (IP‐Dip and IP‐Visio). Dispersions of functionalized NPs (f‐NPs) have improved the NP density by an order of magnitude and are shown to be stable for several weeks with minimal impact on printing quality. The approach is generalizable to other oc‐NPs, enabling synthesis of functional resins for high‐quality polymer‐based optical and electronic devices. [ABSTRACT FROM AUTHOR]

The quantity of silane chemically bonded to the organoclay's surface significantly influences its dispersion within the polymer matrix, as well as the interfacial interaction. This research presents a groundbreaking method for enhancing the surface properties of montmorillonite (Mt) through the use of γ‐(methacryloxy) propyl trimethoxy silane (KH570) coupled with acid treatment, leading to increased grafting efficiency. Confirmed by FT‐IR, TGA, and XRD, the process effectively bonds organo‐silanes to Mt and achieves a high grafting level of 1.59 mequiv/g. Utilizing a latex compounding method, Mt/rubber nanocomposites are synthesized with thoroughly modified clay for peak performance. Dispersion and interfacial properties are evaluated through XRD, TEM, AFM, and DMTA. The findings reveal that the well‐modified Mt is an exceptional filler, ensuring a high level of dispersion and robust interaction with the rubber matrix. This synergy translates to a marked improvement in the mechanical properties of the composite, with notable enhancements observed in both tensile strength and elongation at break of 9.7 MPa and 1141%, respectively. This innovative approach to the graft modification of clays presents a potent method, offering the potential for the industrial‐scale manufacture of high‐performance clay‐based composites. Highlights: A processing method for preparing high grafting clay with a silane coupling agent.Functionalized clay presents better nano‐dispersion in the polymeric matrix.Strong covalent interfacial interaction is constructed between clay and rubber.Tensile Strength and elongation at break of the composites are obliviously improved. [ABSTRACT FROM AUTHOR]

\nHIGHLIGHTSThe advancement of carbon nanotube (CNT) polymer composites has significantly revolutionized material science by offering exceptional mechanical, electrical, and thermal properties. However, the practical application of these composites is often hindered by the poor dispersion and compatibility of CNTs within polymer matrices. This paper explores advanced functionalization techniques to address these challenges, aiming to achieve superior dispersion and compatibility. Through a comprehensive review of chemical, physical, and hybrid functionalization methods, this study evaluates their effectiveness in enhancing CNT-polymer composite properties. Additionally, key characterization techniques, including spectroscopic and microscopy methods, are utilized to assess the quality of dispersion, interfacial bonding, and the presence of functional groups. Detailed case studies showcase the successful application of these advanced functionalization techniques, with significant improvements in mechanical properties such as tensile strength, modulus, and fracture toughness, resulting in composites with enhanced performance. This research advances the understanding of functionalization strategies and provides a robust framework for future studies and industrial applications, paving the way for the commercialization of high-performance CNT-polymer composites.Tailored functionalization optimizes electrical and mechanical performance.Hybrid functionalization enhances CNT dispersion in polymer matrices.Covalent and noncovalent methods combine for superior composite properties.Improved interfacial bonding boosts tensile strength and thermal stability.Enhanced CNTpolymer compatibility leads to advanced industrial applications.Tailored functionalization optimizes electrical and mechanical performance.Hybrid functionalization enhances CNT dispersion in polymer matrices.Covalent and noncovalent methods combine for superior composite properties.Improved interfacial bonding boosts tensile strength and thermal stability.Enhanced CNTpolymer compatibility leads to advanced industrial applications. [ABSTRACT FROM AUTHOR]

In this work, we propose a novel dual guided PCF design capable of supporting the transmission of 68 OAM modes. The innovative design features a specialized structure with multiple layers composed of pure silica and SF57 material arranged alternately. To enhance physical strength and minimize loss, the fiber is enclosed by a perfectly matched layer (PML). Air holes are strategically added and optimized in the third and fifth layers. Through numerical analysis, we observed that the proposed design yields excellent results across all evaluated parameters. The maximum confinement loss recorded is 10–12 dB/m. The effective refractive index values range from 1.444 to 1.8, with effective refractive index difference values in the order of 10–2. Furthermore, the modal purity and power fraction values exceed 99% for all modes. Dispersion values are maintained below 9.87 ps/THz/cm, and crosstalk values are less than − 12 dB. These results demonstrate the potential of our dual guided PCF design in meeting the increasing demands for high-speed and reliable communicating systems. [ABSTRACT FROM AUTHOR]

Reducing carbon dioxide emissions is one of the largest energy and environmental challenges currently faced globally. To achieve carbon neutrality, the development of new technologies and simultaneous improvement of conventional technologies are required. Catalysis, which determines the success or failure and efficiency of the process, is at the center of addressing these problems. Innovative advancements in catalysis have been accomplished through the extensive research on catalytic materials. Oxygen storage materials with oxygen storage capacity (OSC) have been widely applied in supports and active cocatalysts for energy and environmental catalytic applications. This review provides knowledge on the extended applications (reforming, water-gas shift reaction, and partial oxidation of methane (POM) for high-value-added chemicals, including hydrogen production, deoxygenation of fatty acids for second-generation biofuel production, selective catalytic reduction of NOx with NH3, hydrocarbon (HCs) oxidation for emission control, CO oxidation for vehicle exhaust control and purification of gaseous product fuel, and soot oxidation for the removal of motor-type pollutants) of these materials, which are mainly used as three-way catalysts (TWC) in automotive catalysis, to the carbon-neutral field. In particular, this study focuses on the physico-chemical properties that are closely synergistic with OSC, such as reducibility, dispersion, surface acid/base properties, and physical properties, such as surface structure or morphology. [ABSTRACT FROM AUTHOR]

The processing conditions were varied during the production of polycarbonate-based composites with the multiwalled carbon nanotubes (MWCNTs) Baytubes® C150 P (Bayer MaterialScience AG, Leverkusen, Germany), by melt mixing with an extruder on a laboratory scale. These included the screw design, rotation speed, throughput, feeding position and MWCNT content. Particular attention was paid to the shortening of the MWCNT length as a function of the conditions mentioned. It was found that there is a correlation between the applied specific mechanical energy (SME) during the melt mixing process and MWCNT dispersion, which was quantified by the agglomerate area ratio of the non-dispersed nanotubes based on optical microscopic analysis. The higher the SME value, the lower this ratio, which indicates better dispersion. Above an SME value of about 0.4 kWh/kg, no further improvement in dispersion was achieved. The MWCNT length, as measured by the quantitative analysis of TEM images of the MWCNTs dissolved from the composites, decreased with the SME value down to values of 44% of the original MWCNT length. At a constant loading of 3 wt.%, the tensile strength and tensile modulus were almost independent of the SME, while the elongation at break and notched impact strength showed an increasing trend. The variation in the feeding position showed that feeding the MWCNTs into a side feeder led to slightly better electrical and mechanical properties for both types of MWCNTs studied (Baytubes® C150 P and Nanocyl™ NC7000 (Nanocyl S.A., Sambreville, Belgium)). However, feeding into the hopper led to better CNT dispersion with Baytubes® C150 P, while this was the case with Nanocyl™ NC7000 when feeding into the side feeder. The screw profile had an influence on the dispersion, the MWCNT length and the electrical resistance, but only to a small extent. Distributive screws led to a greater shortening of the MWCNT length than dispersive screws. By varying the MWCNT content, it was shown that a greater MWCNT shortening occurred at higher loadings. Two-stage masterbatch dilution leads to stronger shortening than composite production with direct MWCNT incorporation. [ABSTRACT FROM AUTHOR]

A lanthanum–cerium-based abrasive composed of CeO2, LaOF, and LaF3 was commercially obtained. The effect of sodium hexametaphosphate (SHMP) on powder dispersion behavior was systematically investigated using the combined techniques of liquid contact angle, turbidity, zeta potential (ZP), scanning electron microscopy (SEM), powder X-ray diffraction (XRD) combined with Rietveld refinements, X-ray photoelectron spectroscopy (XPS), and polishing tests. The results indicated that the addition of 0.5 wt.% SHMP dispersant to the 5 wt.% lanthanum–cerium-based slurry produced the most stable suspension with a high turbidity of 2715 NTU and a low wetting angle of 45°. The as-obtained slurry displayed good surface polishing quality for K9 glass, with low surface roughness (Ra) of 0.642 and 0.515 nm (in the range of 979 × 979 μm2) at pH = 6 and 11, respectively, which corresponds to the fact that it has local maximum absolute values of ZP at these two pH values. SEM images demonstrated that after appropriate grafting of SHMP, the particle aggregation was reduced and the slurry's dispersion stability was improved. In addition, the dispersion mechanism was explained based on the principle of complexation reaction, which reveals that the dispersant SHMP can increase the interparticle steric hindrance and electrostatic repulsions. In an acidic environment, steric hindrance dominates, while electrostatic repulsion prevails under alkaline conditions. As expected, this polishing slurry may find potential applications in manufacturing optical devices and integrated circuits. [ABSTRACT FROM AUTHOR]

In industrial production, the identification and characterization of micron-sized second phases, such as carbonitrides in alloys, hold significant importance for optimizing alloy compositions and processes. However, conventional methods based on threshold segmentation suffer from drawbacks, including low accuracy, inefficiency, and subjectivity. Addressing these limitations, this study introduced a carbonitride instance segmentation model tailored for various nickel-based superalloys. The model enhanced the YOLOv8n network structure by integrating the SPDConv module and the P2 small target detection layer, thereby augmenting feature fusion capability and small target detection performance. Experimental findings demonstrated notable improvements: the mAP50 (Box) value increased from 0.676 to 0.828, and the mAP50 (Mask) value from 0.471 to 0.644 for the enhanced YOLOv8n model. The proposed model for carbonitride detection surpassed traditional threshold segmentation methods, meeting requirements for precise, rapid, and batch-automated detection in industrial settings. Furthermore, to assess the carbonitride distribution homogeneity, a method for quantifying dispersion uniformity was proposed and integrated into a data processing framework for seamless automation from prediction to analysis. [ABSTRACT FROM AUTHOR]

Polyhydroxybutyrate (PHB) is a potential biopolymer and can replace petroleum-based plastic. PHB accumulated by bacteria needs a supply of carbon source whereas cyanobacteria are capable of synthesizing PHB by carbon fixation using sunlight energy. Since PHB is an intracellular product the polymer recovery cost is about 50 % of production cost. Apart from these, cyanobacterial pigments also affect the purity and recovery yield. In the present study, Chlorogloea fritschii TISTR 8527 was chosen as a PHB cell factory which accumulated 28 % of biopolymer. The hypochlorite-chloroform dispersion method could remove the pigments along with PHB extraction with 95.51 ± 3.164 % of the recovery in a single step. In addition to this, PHB extraction was performed with various halogenated solvents and green non-halogenated solvents with hypochlorite pretreatment. Selected solvents were unable to recover more than 90 % of polymer yield due to unsuitable operating conditions. Besides this, the green solvent dimethyl carbonate (DMC) was employed for PHB recovery with prior pigment removal from biomass using chilled methanol. DMC was capable of 83.34 ± 0.76 % biopolymer recovery with a purity of 75 %. PHB recovered using DMC has improved thermal and material characteristics. [ABSTRACT FROM AUTHOR]

In order to understand the dispersion of hydrogen (H2) leaked in packed beds of nonporous/porous particles in a partially open space practically, the dispersion of H2 in the particle layers of glass beads and soil was analytically studied using a computational fluid dynamics code to be compared with the experiments and to elucidate the effects of the particle layer. The packed beds in the partially open space can be considered as a basic model for all processes of transfer, treatment, storage, and disposal of radioactive materials containing fuel debris in the decommissioning of nuclear facilities after a severe accident. The H2 flowing out from a single leak point in the particle layer of nonporous glass beads was affected by buoyancy around the leak point and diffused directly above the leak point in an elliptical shape faster than in the horizontal direction. After that, when it reached the air layer in the head space above the particle layer, the H2 spread horizontally, formed a large concentration gradient near the boundary between the particle layer and the air layer, and further diffused in the air layer until the H2 concentration became about 1/3 or less of the concentration near the surface of the particle layer. When the particle diameters were 512 μm and 1200 μm, this tendency was more pronounced when the porosity was the same and the particle diameter was smaller. The calculations largely reproduced the experimental concentration distributions. When the particle layer was porous decomposed granite soil, the diffusion behavior of H2 in the particle layer proceeded in the same manner as in the case of the glass beads. However, a large concentration gradient was formed near the boundary between the particle layer and the air layer, and then H2 diffused in the air layer until the H2 concentration became below the lower combustion limit. It was suggested through sensitivity analysis that the air permeability coefficient had a large effect on the time course of the H2 concentration distribution. Based on this information, we further simulated H2 behavior in the vessel containing the H2 leaked particle layer. By inserting multiple vent pipes without considering H2 generation distribution and particle properties in the particle layer, H2 accumulated from one pipe was discharged by buoyancy without depending on the H2 generation distribution and particle properties in the particle layer and air flowed in from the other pipe. It was suggested that such a natural ventilation process would reduce the H2 concentration in the container. [ABSTRACT FROM AUTHOR]

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A Rotary-Pulsation Apparatus (RPA), also known in the literature as a Rotational Hydrodynamic Cavitation Reactor (RHCR), is a device which typically consists of a rotating mechanism that generates pulsations or vibrations within a fluid. This can be achieved through various means such as mechanical agitation, pneumatic pulses, or hydraulic forces. It is widely used in food, chemical, pharmaceutical, and microbiological industries to improve the mixing of different fluids, dispersion, pasteurization, and sterilization. In the present paper, a CFD study was conducted to develop and optimize the geometry of the RPA's rotor and stator to induce cavitation in the fluid flow. The effect of cavitation has the potential to improve dispersion and emulsion properties and to significantly reduce operation pressure, in comparison to conventional mixing systems. [ABSTRACT FROM AUTHOR]

Deforestation poses a significant environmental challenge that demands global efforts to address, aiming to preserve forest ecosystems and promote sustainable development worldwide. This study investigates the global phenomenon of deforestation convergence from 1990 to 2020 across 149 countries, employing state transition probabilities assessed using Markov chains, dispersion indicators, and average deforestation rates. The analysis indicates a consistent decrease in dispersion indicators and average deforestation rates observed across the studied countries over three decades, coupled with high probabilities of maintaining current forest ecosystem states. These findings suggest the presence of sigma and beta convergence phenomena in the shift towards sustainable development, akin to patterns observed in economic growth. Furthermore, our research identifies the emergence of a Kuznets curve based on deforestation growth rates and dispersion indicators relative to GDP per capita since 2010. This also suggests a potential global convergence in sustainable forest-related activities. Hence, it is clear that coordinating environmental development policies among countries is crucial for achieving global ecological stability. This underscores the necessity for proactive measures to ensure worldwide forest conservation and sustainable management. [ABSTRACT FROM AUTHOR]

A PCF (photonic crystal fiber) with high birefringence and single-mode polarization retention over a wide wavelength range is designed and studied. The birefringence and polarization retention characteristics of the PCF base mode were studied using FVFEM (full vector finite element method) and APML (anisotropic perfect matching layer) as boundary conditions. The simulation results show that by rotating the elliptical air hole parallel to the horizontal axis by 45°, and then rotating the elliptical air hole parallel to the longitudinal axis by 45°, the birefringence of the PCF obtained is as high as 4.7 × 10−2, and it has good single model ability, which can be used for various optical devices. [ABSTRACT FROM AUTHOR]

The issue of semantic dispersion has captured the attention of researchers in the field, and they attribute its reasons to translators’ negligence in highlighting the connotations correctly. This is a result of their sole reliance on literal or meaningful translation that consequently led to ambiguity surrounding the meanings and semantic style of Quranic verses. This study aimed to analyze the process of translating words in selected Quranic verses into the Malay language by different translators of the holy Qur’an by identifying the main problems involved in the translation process. Comparisons were made between the translations above by selecting several controversial verses that lead to semantic dispersion. The current study employed the descriptive analytical comparative approach, where the researchers described the approaches in translating the holy Qur’an from the Arabic language into the Malay language. Three translations were compared, namely the Al-Humaira translation (printed version) and the other two translations, which are digital, namely Surah.my and The Noor, because the Malay community commonly uses them. Al-Humaira is the primary source in this study, where examples of selected verses were analyzed and compared with the other two translations. Several findings were reported in this study, with the most important being that there are glaring differences with significant gaps between the translation processes of the translations above, where the translation of Al-Humaira was better and more accurate than the other two translations. Another finding in this study is that the difficulties facing translators are related to the connotations of meanings resulting from dimensions of language such as culture and connection to context, difficulties that cast a shadow over all translation processes. Hence, it is almost impossible to convey the meanings of the holy Qur’an with complete accuracy despite the excellent skills of translators in the field. [ABSTRACT FROM AUTHOR]

Heptamethine based cyanines, namely 1,3,‐trimethyl‐2‐(2‐2[2‐phenylsulfanyl‐3‐[2‐(1,3,3‐trimethyl‐1,3,3‐trithyl‐1,3‐dihydro‐indol‐2‐ylidene)‐ethylidene]cyclohex‐1‐enyl]vinyl)‐3H‐indolium chloride (S1) and 2‐[2‐(2‐chloro‐[2‐[1,1‐dimethyl‐7‐sulfo‐3‐(4‐sulfobutyl)‐1,3‐dihydro‐benzo[e]indol‐2‐ylidene]‐ethylidene]cyclopent‐1‐enyl]vinyl]‐1,1‐dimethyl‐7‐sulfo‐3‐(4‐sulfobutyl)‐1Hbenzo[e]indolium hydroxide, inner salt, triethylammonium salt (S2), efficiently result in physical drying of an aqueous dispersion comprising a polyurethane binder. S2 possesses a water solubility of 40 g/L. A high‐intensity near‐infrared‐LED emitting at 820 nm with an intensity of 1 W/cm2 served as light source. The cyanine converted the light absorbed into heat by internal conversion needing less drying time compared to conventional drying. Water content after film formation showed less then 1%. In the second step, ultraviolet (UV) exposure with a LED emitting at 395 nm resulted in formation of semi‐interpenetrating polymer networks by crosslinking of the multifunctional (meth)acrylate operating as reactive diluent. Ethyl phenyl(2,4,6‐trimethylbenzoyl)phosphinate‐L served as effective UV‐photoinitiator. Furthermore, the UV‐exposure together with Norrish Type I and Type II photoinitator systems results in a very efficient bleaching of the green physical dried film. This contribution shows for the first time a new photonic hybrid technique describing successful replacement of an oven‐based process by a photonic based step that generates heat needed for drying. [ABSTRACT FROM AUTHOR]

Municipal solid waste (MSW) storage sites are potential and overlooked contributors to microplastic (MP) pollution. Herein, the distribution and dispersion characteristics of MPs at MSW storage sites were investigated through modeling, sampling analysis, and prediction methodologies. The results indicated a notable adsorption phenomenon of MPs on smooth surfaces within such sites, achieving high saturation levels and making MPs prone to re-release by airflow disturbance. Quantitative analysis revealed that the MP concentrations on these surfaces varied from 4.48 × 105 to 1.90 × 106 n/m2 and that MPs predominantly accumulated in the corner areas. Notably, MP accumulation on wall surfaces can be reduced by 76.4% using washing procedures. The majority of MPs were under 50 µm in size and were primarily in fragment form. Operational activities such as ventilation and waste handling were identified to amplify the airborne spread of MPs. The atmospheric concentrations of MPs peaked seasonally, with concentrations of 28.25 n/m3 in summer and 3.90 n/m3 in winter, and the spatial dispersion ranged from 14.98 to 124.08 km2 per station. This study highlights that MSW storage sites are substantial yet overlooked sources of MP pollution, where wall surfaces play a critical role in MP adsorption and dispersal. The implementation of robust management and cleaning protocols is essential to mitigate the environmental footprint of MPs emanating from these locations. This study also provides a typical case for the precise prevention and control of MPs in the environment. [ABSTRACT FROM AUTHOR]

Highlights This study assesses the effectiveness of a specially developed surface‐modified carbon black, both on its own and in combination with nano‐silica, as a hybrid filler for ethylene–propylene–diene monomer (EPDM) rubber compounds. The modification process, which included treatment with a silane coupling agent, resulted in enhanced curing characteristics. The ∆Torque values for compounds incorporating the modified carbon black exceeded those of other formulations by 25.85%. Scanning electron microscopy (SEM) analysis demonstrated improved filler dispersion and better compatibility between rubber and filler due to the surface modification. The silane‐modified carbon black showed considerable enhancements in mechanical properties, particularly in tear resistance, with increases in tensile and tear strength of 22.46% and 34.86%, respectively, following surface treatment. Dynamic mechanical analysis (DMA) indicated the influence of both surface modification and filler type, revealing that the combination of modified carbon black and nano‐silica achieved a reduction in rolling resistance of 20.41% and enhanced ice and wet grip performance by 7.95%. Additionally, modified carbon black displayed varying effects on the glass transition temperature. Thermal gravimetric analysis (TGA) confirmed that the thermal stability of the compounds was consistent, while solvent resistance improved with surface modification, as shown by swelling ratios. Thermodynamic analysis indicated that the surface modification of carbon black positively influences the elasticity and chain mobility of the rubber compounds studied. In conclusion, the careful selection and optimization of filler materials and their modifications are essential for customizing the properties of rubber compounds to satisfy specific performance criteria and applications. Promising EPDM compounds were prepared with Silane‐Modified CB and Nano‐Silica. Silane‐modified CB effectively improved the curing properties of the EPDM compound. The ΔTorque and cross‐link density of modified CB/EPDM show the highest value. Modified CB/Nano‐Silica/EPDM exhibited significant improvement in tear strength. Modified CB/Nano‐silica/EPDM have lower rolling resistance and higher wet grip. [ABSTRACT FROM AUTHOR]

This study investigates the feasibility of utilizing carbon dioxide (CO2) as a cushion gas in depleted reservoirs for enhanced gas storage efficiency and carbon sequestration against the backdrop of rising natural gas stable supply demand and climate change concerns. Simulations of gas storage reservoir scenarios require accurate dispersion parameters at flow alternation conditions to quantify the size of the miscible displacement front. Several experimental studies using core-flooding equipment aimed at measuring related parameters have been reported over the last decade but did not take flow alternation into consideration. We simulated directionally variable displacements to mimic the cyclic injection and extraction processes in gas storage, focusing on the dispersion characteristics of CO2 and methane (CH4) during flow alternation. Key findings were observed using Nuclear Magnetic Resonance (NMR) imaging, which provided real-time data on the spatial distribution and temporal changes of CH4 signals in rock cores. The results revealed that dispersion, influenced predominantly by dispersion coefficients rather than molecular diffusion, was significantly higher during alternating flow compared to concurrent displacement. Additionally, CO2 exhibited a greater dispersion effect when displacing CH4 than the reverse. This enhanced mixing efficiency during flow alternation supports the potential of CO2 as a cost-effective and efficient cushion gas, offering both improved storage performance and the added benefit of CO2 sequestration. These findings contribute valuable insights for the numerical simulation and operational adaptation of CO2 in gas storage reservoirs, emphasizing the importance of understanding fluid interactions under varying flow conditions to optimize storage efficiency and environmental benefits. [ABSTRACT FROM AUTHOR]

We report on an experimental study in which Lagrangian tracking is applied to millions of microscopic particles floating on the free surface of turbulent water. We leverage a large jet-stirred zero-mean-flow apparatus, where the Reynolds number is sufficiently high for an inertial range to emerge while the surface deformation remains minimal. Two-point statistics reveal specific features of the flow, deviating from the classic description derived for incompressible turbulence. The magnitude of the relative velocity is strongly intermittent, especially at small separations, leading to anomalous scaling of the second-order structure functions in the dissipative range. This is driven by the divergent component of the flow, leading to fast approaching/separation rates of nearby particles. The Lagrangian relative velocity shows strong persistence of the initial state, such that the ballistic pair separation extends to the inertial range of time delays. Based on these observations, we propose a classification of particle pairs based on their initial separation rate. When this is much smaller than the relative velocity prescribed by inertial scaling (which is the case for the majority of the observed particle pairs), the relative velocity transitions to a diffusive growth and the Richardson–Obukhov super-diffusive dispersion is recovered. [ABSTRACT FROM AUTHOR]

The presence of the black twig borer Xylosandrus compactus (Eichhoff) (Coleoptera: Curculionidae: Scolytinae) is recorded in the region of Soconusco, Chiapas, Mexico associated with Robusta coffee (Coffea canephora Pierre ex Frohener). [ABSTRACT FROM AUTHOR]

This paper proposes a mechanical dispersion method of hydrated lime in a vibrating activator equipped with special blades that operate in a resonant mode. It has been found that during the vibro-activation process, hydrated lime consistently passes through proportionately increasing stages of dynamic viscosity, slowing its growth and ceasing dispersion. A new vibration method for determining the viscosity of the hydrated lime-water system has been developed. The effect of vibration treatment on changes in the dispersion of calcium hydroxide was studied. It has been found that vibration-treated lime, compared to conventional hydrated lime, has new properties: the ability to form durable coatings due to accelerated carbonization. [ABSTRACT FROM AUTHOR]

Assessing air quality in urban areas is vital for protecting public health, and low-cost sensor networks help quantify the population's exposure to harmful pollutants effectively. This paper introduces an innovative method to calibrate air-quality sensor networks by combining CFD modeling with dependable AQ measurements. The developed CFD model is used to simulate traffic-related PM10 dispersion in a 1.6 × 2 km2 urban area. Hourly simulations are conducted, and the resulting concentrations are cross-validated against high-quality measurements. By offering detailed 3D information at a micro-scale, the CFD model enables the creation of concentration maps at sensor locations. Through regression analysis, relationships between low-cost sensor (LCS) readings and modeled outcomes are established and used for network calibration. The study demonstrates the methodology's capability to provide aid to low-cost devices during a representative 24 h period. The precision of a CFD model can also guide optimal sensor placement based on prevailing meteorological and emission scenarios and refine existing networks for more accurate urban air quality representation. The usage of cost-effective air quality networks, high-quality monitoring stations, and high-resolution air quality modeling combines the strengths of both top-down and bottom-up approaches for air quality assessment. Therefore, the work demonstrated plays a significant role in providing reliable pollutant monitoring and supporting the assessment of environmental policies, aiming to address health issues related to urban air pollution. [ABSTRACT FROM AUTHOR]

Widely used methods to assess population genetic structure and differentiation rely on independence of marker loci. Following the assumption, the common metrics, for example FST, evaluate genetic structure by averaging across loci. Common metrics do not use information in the associations among loci at the individual level and are often criticized for failing to measure true differentiation even when loci segregate independently. We introduce a new concept to measure β‐variation (Effective Number of Different Populations, ENDP). It requires the following steps: (a) calculation of a proper dissimilarity between genetic profiles of all individuals; (b) calculation of suitable pairwise distances between the samples based on the dissimilarities between individuals; (c) calculation of diversity (in terms of Hill numbers) and dispersion of samples based on the pairwise distances between samples; (d) ENDP is then estimated by combining the diversity and dispersion. ENDP estimates β‐variation independently of estimates of within‐sample α‐variation, although β‐ and α‐estimates could statistically correlate to some extent. This new concept differs from the existing standard where β‐diversity is estimated based on the "partition of variation" scheme (beta=gamma−alpha$$ \mathrm{beta}=\mathrm{gamma}-\mathrm{alpha} $$ or beta=gamma/alpha$$ \mathrm{beta}=\mathrm{gamma}/\mathrm{alpha} $$), so that estimates of β‐diversity directly depend on the corresponding values of α‐diversity. ENDP estimates are obtained by evaluating information in the available genetic profiles of individuals including association of loci. Therefore, ENDP can be used even in an absence of panmixia. We illustrate the use of this concept by analyzing the population genetic structure of a sexual species (a trematode parasite) occupying connected populations across a broad geographic area. The analysis is complicated by geographically coexisting cryptic species and the potential mixed‐mating system of this hermaphroditic parasite. Analyses with subsampled data demonstrated that ENDP estimates are robust. Number of loci used for genotyping has much stronger effect on variation of point ENDP estimates than sample size. [ABSTRACT FROM AUTHOR]

In frequency regions where ultra‐wide band log‐periodic antennas exhibit negative group delay (NGD), the effect of higher‐order modes upon amplitude‐modulated signals is examined using convolution theory. It is shown that in these frequency regions, the group delay and the effect of the higher order modes upon amplitude‐modulated signals vary throughout the antenna's radiation pattern. It is also shown that the signal time advances predicted by the NGD are due to signal distortion when undesired higher‐order modes are present on the antenna. [ABSTRACT FROM AUTHOR]

The design of band gap metamaterials, i.e., metamaterials with the capability to inhibit wave propagation of a specific frequency range, has numerous potential engineering applications, such as acoustic filters and vibration isolation control. In order to describe the behavior of such materials, a novel integral micromorphic elastic continuum is introduced, and its ability to describe band gaps is studied in the one-dimensional setting. The nonlocal formulation is based on a modification of two terms in the expression for potential energy density. The corresponding dispersion equation is derived and converted to a dimensionless format, so that the effect of individual parameters can be described in the most efficient way. The results indicate that both suggested nonlocal modifications play an important role. The original local micromorphic model reproduces a band gap only in the special, somewhat artificial case, when the stiffness coefficient associated with the gradient of the micromorphic variable vanishes. On the other hand, the nonlocal formulation can provide band gaps even for nonzero values of this coefficient, provided that the penalty coefficient that enforces coupling between the micromorphic variable and nonlocal strain is sufficiently high and the micromorphic stiffness is sufficiently low. [ABSTRACT FROM AUTHOR]

Current trends in agricultural intensification lead to degraded grasslands, requiring their restoration through native species reintroduction. Various techniques are available for harvesting seeds from donor sites. However, little is known about their performance in South American C3/C4 mixed grasslands, where studies are scarce. Their particular species composition and phenology, with different flowering periods, require specific harvest strategies. We evaluated mechanical seed harvest in a northern Uruguay grassland, part of Río de la Plata grasslands. Performance of two mechanical harvest methods (seed‐stripper and dry hay) was compared in two harvest seasons (late‐spring and mid‐summer). The evaluation considered the quantity and identity of harvested seeds, and their germination in a greenhouse. Hand collections were made to assess standing seed yield. For each seed mixture, efficiency of mechanical harvests (number of seeds and seedlings compared to hand collection), proportion of germinated seeds, species transfer relative to donor site, and composition were calculated. Results revealed trade‐offs between harvests: seed‐stripper in late‐spring presented low seed collection efficiency (2% for seeds, 5% for seedlings) and species richness (43% transfer), but high seed germination (64%), showing selectivity toward winter species; seed‐stripper in mid‐summer and dry hay in both seasons showed high seed collection efficiency (42–154% for seeds, 26–50% for seedlings) and species richness (65–80% transfer), resembling donor site, albeit lower seed germination (9–20%). Seed‐stripper performance varied between seasons, while dry hay remained consistently effective. These results are pioneering for grassland restoration in Uruguay, encouraging future studies to focus on establishment in the field. [ABSTRACT FROM AUTHOR]

In material science, converting waste into nanomaterials by green technologies highlights the interest in producing sustainable carbon nanomaterial (SCN). This study first-ever utilized tyre-char as a Nano-Structure Pyrolytic Carbon (NSPC) to develop electrically conductive composites. Unlike other carbon nanomaterials, the efficiency of NSPC particle as an SCN in developing electrically conductive composites was investigated in terms of dispersion, mechanical, water absorption, electrical resistivity, and microstructure. The results of sedimentation and zeta potential (−19 mV) showed the excellent dispersion of NSPC particle in water with the combined effect of superplasticizer and ultrasonication. The compressive (40.37%) and flexural strength (10.76%) than that of plain cement mortar composite (CMC) is achieved with 2 wt.% and 1.5 wt.% of NSPC particle, respectively. The water absorption rate and volume of permeable voids were reduced, exhibiting less agglomerations. The percolation zone of AC and DC resistivity of NSPC composite ranges between 1 and 2 wt.%, and the established percolation threshold is at 2 wt.%. XRD analysis showed C-S-H formation consistently increased with curing age, and HR-SEM with EDAX analysis exhibits the dense microstructure and well-distributed NSPC particle at the nanoscale. These experimental outcomes significantly enhanced the reliability and provided a framework for tailoring NSPC particle as SCN for developing electrically conductive composite. [ABSTRACT FROM AUTHOR]

The incorporation of nanoparticles can significantly enhance the properties of polymers. However, the industrial production of nanocomposites presents a technological challenge in achieving the proper dispersion of nanoparticles within the polymer matrix. In this work, a novel device is presented that can be seamlessly integrated with standard twin-screw extruders, enabling the application of ultrasonic vibration to molten polymeric material. The primary objective of this study is to experimentally validate the effectiveness of this technology in improving the dispersion of nanoparticles. To accomplish this, a comparative analysis was carried out between nanocomposites obtained through conventional compounding extrusion and those processed with the assistance of ultrasonic vibrations. The nanocomposites under investigation consist of a polypropylene (PP) matrix reinforced with nano clays (Cloisite 20A) at a target loading ratio of 5% by weight. To comprehensively evaluate the impact of the ultrasound-assisted compounding, various key properties were assessed, such as the melt flow index (MFI) to characterize the flow behavior, mechanical properties to evaluate the structural performance, oxygen barrier properties to assess potential gas permeability, and microstructure analysis using Scanning Electron Microscopy (SEM) for detailed morphology characterization. The results suggested an improvement in nanoparticle dispersion when using the ultrasound device, particularly when the intensity was adjusted to 60%. [ABSTRACT FROM AUTHOR]

Polycarboxylate superplasticizers (PCEs) have been extensively used in the areas of construction and building; however, the application limitation of PCEs has emerged owing to their sensitivity to clay. In this work, three anticlay PCEs were synthesized by introducing acrylamide (AM), methacryloxyethyltrimethyl ammonium chloride (DMC), or 3-[2-(methacryloyloxy) ethyl] dimethylammonio-propane-1-sulfonate (DMAPS) into the polycarboxylate copolymer of ethylene glycol monovinyl polyethylene glycol ether (EPEG) and acrylic acid (AA), denoted as A-PCE, D-PCE, and S-PCE, respectively. The structures of these superplasticizers were characterized by gel permeation chromatography (GPC) and Fourier-transform infrared spectroscopy (FTIR). Compared with the common polycarboxylate superplasticizers (O-PCEs), the resultant anticlay PCEs showed better dispersion as far as the fluidity of cement paste and mortar were concerned. With the content of 0.5% per weight sodium bentonite in place of cement, these anticlay PCEs exhibited better clay resistance than O-PCE. In addition, the compressive strengths of mortar and concrete by the addition of A-PCE, D-PCE, or S-PCE were slightly higher than those of O-PCE. Total organic carbon (TOC) revealed that the sensitivity of A-PCE, D-PCE, and S-PCE to clay was lower than that of O-PCE. X-ray diffraction (XRD) proved that the layer spacing of clay increased after treatment with superplasticizer. In combination of adsorption determination with XRD analysis, a possible mechanism was proposed. Unlike the PEG side chains inserting into the clay layers for O-PCE, the cations in functional groups entered the clay layers through cation exchange for anticlay PCEs preferentially. [ABSTRACT FROM AUTHOR]

This paper presents the results of a selective flocculation/magnetic separation study performed with a sample of iron ore slime from the desliming stage of the industrial flotation circuit of a mine in the southern region in the Quadrilátero Ferrífero-Brazil that was discarded in a tailings dam. Zeta potential measurements of pure minerals previously identified in the sample (goethite = 52.4%, hematite = 26.2%, quartz = 12.3%, kaolinite = 8.2%, and others = 0. 9%) were evaluated to assess the influence of the reagents used (sodium hexametaphosphate – SHMP (dispersant)) and flocculants (corn starch, nonionic polyacrylamide – P2500 and cationic polyacrylamide – P806)) on their surface properties and consequently on the stability of suspensions of the slime and of the pure minerals individually, aiming to establish conditions for selective separation between Fe-bearing minerals (goethite and hematite) and gangue minerals (quartz and kaolinite) in the subsequent magnetic separation step. At pH 10 and a 25 mg/L dosage of SHMP, a higher Fe recovery was verified with starch (2000 g/t) in relation to nonionic and cationic polyacrylamides, and similar Fe contents in all dosages tested of the flocculants. [ABSTRACT FROM AUTHOR]

Blue, green, and khaki spinels were produced by self-propagating high-temperature synthesis (SHS) using Co 3 O 4 –ZnO–Mg(NO 3) 2 ·6H 2 O–Al(OH) 3 –Al, Ni 2 O 3 –ZnO–Cr 2 O 3 –Al(OH) 3 –Al, and Co 2 O 3 –Fe 2 O 3 –Al(OH) 3 –Al mixtures. The composition of the synthesis products was characterized by X-ray diffraction and IR spectroscopy. The oxides Co 3 O 4 , Co 2 O 3 , ZnO, Ni 2 O 3 , Cr 2 O 3 , Fe 2 O 3 , and aluminum hydroxide Al(OH) 3 were used for the synthesis. Fuel was provided by aluminum powder (ASD-4). The spinel-type ceramic pigments were synthesized using layer-by-layer combustion, which involves two parallel exothermic reactions: aluminum oxidation and aluminothermic reactions. The fast self-propagating reactions and high synthesis temperatures rapidly destroy the structure of Al(OH) 3 hydroxide in the starting mixture, producing gaseous reaction products that prevent the sintering of the spinels. The surface morphology of pigment powders and their composition was studied using a Quanta 3D 200i, FEI Co. scanning electron microscope and a Philips SEM 515 scanning electron microscope equipped with a local energy dispersive X-ray analysis (EDAX). The particle size of the synthesized spinels was approximately 1–5 μm. Colored spinels powders obtained by the SHS process can be used as ceramic pigments. [ABSTRACT FROM AUTHOR]

Integrating nanomaterials like carbon nanotubes (CNTs) and iron oxide (Fe3O4) into epoxy composites has attracted significant interest due to their potential to enhance mechanical properties. This study evaluates the impact of dispersion quality on the mechanical performance of CNT/Fe3O4/epoxy composites, comparing stirring and sonication methods at three different loadings: 0.1, 0.3, and 0.5 wt.%. Tensile testing revealed that sonicated composites consistently outperformed stirred composites, with a significant increase in the elastic modulus and ultimate tensile strength (UTS). However, fracture strain decreased in both composite types compared to pure epoxy, with sonicated composites experiencing a more significant reduction than stirred composites. These results underscore the importance of high-quality dispersion for optimizing mechanical properties. [ABSTRACT FROM AUTHOR]