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Your search keyword '"Jiang, Zhong-Xia"' showing total 3 results
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3. Lanthanoid single-ion magnets with the LnN10 coordination geometry.

Author

Jiang, Zhong-Xia, Liu, Jun-Liang, Chen, Yan-Cong, Liu, Jiang, Jia, Jian-Hua, and Tong, Ming-Liang

Subjects
*RARE earth metals, *GEOMETRY, *LIGANDS (Chemistry), *POLYHEDRA, *SINGLE molecule magnets
Abstract

We have reported two unprecedented single-ion magnets (SIMs) with the homoatomic LnN10 coordination geometry, where the central Ln (Ln = DyIII or ErIII) ion is interlocked by two pentadentate ligands (N5) affording a low symmetry polyhedron. Studies of dynamic magnetic behaviours show an effective energy of 79(4) K for [Dy(N5)2]3+ and 59(4) K for [Er(N5)2]3+, respectively. [ABSTRACT FROM AUTHOR]

Published
2016
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