5,504 results on '"Superhydrophobic"'
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2. Robust superhydrophobic copper oxide layer with high-low staggered structure on polymers for strong anti-icing and all-day de-icing
- Author
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Xu, Haoran, Luo, Pengan, Wang, Jia-Xin, Yu, Feifan, and Zhou, Tao
- Published
- 2024
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3. Robust design of reinforced superhydrophobic FEP-SiO2@PTFE hollow fiber membrane for waste lubricating oils treatment
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Zhao, Wei, Zhu, Hui, jin, Xin, Chen, Kaikai, Liu, Hailiang, and Xiao, Changfa
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- 2024
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4. Preparation of superhydrophobic biomedical pulp from rice straw coated with a stearic acid-cellulose composite
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Daulay, Irene Rizky Safina, Ariyanta, Harits Atika, Karimah, Azizatul, Fitria, Santoso, Eko Budi, Cahyana, Antonius Herry, Bukhari, Mohd Nadeem Shah Syed, Bakshi, Mohammad Irfan, Dungani, Rudi, Hanifa, Tsabita Zahra, Karliati, Tati, Farobie, Obie, Iswanto, Apri Heri, and Fatriasari, Widya
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- 2024
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5. Superhydrophobic carbon fiber composite coatings based on TC4 titanium alloy for improving corrosion resistance.
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Pei, Wenle, Xie, Zhuangzhuang, Pei, Xiaoliang, and Wang, Jianmei
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SEAWATER corrosion , *FIBROUS composites , *COMPOSITE coating , *CARBON composites , *CORROSION in alloys , *TITANIUM alloys - Abstract
Seawater corrosion poses significant challenges to marine industrial equipment, leading to a reduced lifespan and potential safety hazards. To enhance the corrosion resistance and reliability of titanium alloys in marine environments, a superhydrophobic TiO₂ nanotube-carbon fiber composite coating (SCF-TAD20) was developed through anodic oxidation, spraying, and chemical modification. SCF-TAD20 achieves a contact angle of 153°, which facilitates excellent corrosion protection due to its unique micro-nano structure, gas barrier properties, and chemical resistance. Electrochemical tests demonstrate that SCF-TAD20 increases the corrosion potential from −0.482 V to 0.0612 V and reduces the corrosion current density from 377.8 × 10−8 A/cm2 to 0.615 × 10−8 A/cm2, a four-order decrease. Its charge transfer resistance (∼8.81E6 Ω·cm2) is significantly higher than that of the substrate (∼3.03E5 Ω·cm2). The coating also performs well in seawater with varying pH levels, showing the lowest corrosion current density and a significant increase in resistive arc radius. This research presents a novel approach to enhancing TC4 titanium alloys for marine applications. [ABSTRACT FROM AUTHOR]
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- 2024
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6. Superhydrophobic Coatings with Synergistically Enhanced Anti/Deicing Performance by Optically/Electrically Assisted Heating.
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Huang, Zhihong, Zhan, Yanlong, Li, Wen, Li, Xiang, and Amirfazli, Alidad
- Abstract
Surface icing issues have a significant impact on industries such as aviation, transportation, and construction. Superhydrophobic surfaces can delay ice formation due to their liquid‐repellent properties, but their effectiveness is not pronounced in extremely cold environments. Electric heating coatings can effectively prevent ice formation, but they have limitations in environments with insufficient electrical energy supply. The anti‐icing effect of photothermal superhydrophobic coatings is restricted under conditions of insufficient sunlight. To enhance the ice‐preventing performance of superhydrophobic coatings in extremely cold environments, this article employs a template spraying method to prepare a carbon black and graphene composite coating that provides superhydrophobic passive anti‐icing and photo/electrothermal active deicing capabilities. The micro‐nanostructured superhydrophobic surface exhibits exceptional ice‐preventing performance. The excellent electrothermal and photothermal performance, along with high energy conversion efficiency, significantly enhance the coating's deicing efficiency. Under the synergistic effect of solar and electrical energy, the ice layer is completely melted within just 135 s. Furthermore, the material possesses excellent durability (resistance to mechanical wear, acid and alkali corrosion, and UV aging), as well as thermal stability. This research provides new avenues and insights for the development of advanced anti‐icing and deicing materials for applications in aviation, transportation, construction, and other fields. [ABSTRACT FROM AUTHOR]
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- 2024
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7. Carbon-Nanotube-Based Superhydrophobic Magnetic Nanomaterial as Absorbent for Rapid and Efficient Oil/Water Separation.
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Kudaibergenova, Rabiga M., Roman, Fernanda F., Silva, Adriano S., and Sugurbekova, Gulnar K.
- Abstract
In this work, the simple fabrication of a new superhydrophobic magnetic sponge based on CNTs, NiFe2O4 nanoparticles, and PDMS was investigated. CNTs were synthesized by chemical vapor deposition (CVD) on a nickel ferrite catalyst supported on aluminum oxide (NiFe2O4/Al2O3). The synthesis of nickel ferrite (NiFe) was accomplished using the sol–gel method, yielding magnetic nanoparticles (43 Am2kg−1, coercivity of 93 Oe, 21–29 nm). A new superhydrophobic magnetic PU/CNT/NiFe2O4/PDMS sponge was fabricated using a polyurethane (PU) sponge, CNTs, NiFe2O4 nanoparticles, and polydimethylsiloxane (PDMS) through the immersion coating method. The new PU/CNT/NiFe2O4/PDMS sponge exhibits excellent superhydrophobic/oleophilic/mechanical properties and water repellency (water absorption rate of 0.4%) while having good absorption of oil, olive oil, and organic liquids of different densities (absorption capacity of 21.38 to 44.83 g/g), excellent separation efficiency (up to 99.81%), the ability to be reused for removing oil and organic solvents for more than 10 cycles, and easy control and separation from water using a magnet. The new PU/CNT/NiFe2O4/PDMS sponge is a promising candidate as a reusable sorbent for collecting oil and organic pollutants and can also be used as a hydrophobic filter due to its excellent mechanical properties. [ABSTRACT FROM AUTHOR]
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- 2024
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8. Enhancing glass surface hydrophobicity: the role of Perfluorooctyltriethoxysilane in advanced surface modification.
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Khojasteh, Hossein, Mazhari, Mohammad-Peyman, Heydaryan, Kamran, Aspoukeh, Peyman, Ahmadiazar, Shahab, Hamad, Samir Mustafa, and Shaikhah, Dilshad
- Abstract
This study presents a novel approach to fabricate self-cleaning, superhydrophobic coatings on glass surfaces and photovoltaic cells. Using a cost-effective spray-coating technique, superhydrophobic glass surfaces were developed incorporating modified SiO
2 nanoparticles (NPs), synthesized via a simple sol–gel method. Silylating agents, Poly(dimethylsiloxane) (PDMS) and Perfluorooctyltriethoxysilane (PFOS), were used for the modification, resulting in enhanced surface roughness and hydrophobicity. The study extensively characterizes the analytical techniques such as Fourier transform infrared spectroscopy (FT-IR), atomic force microscopy (AFM), transmission electron microscopy (TEM), scanning electron microscopy (SEM), and contact angle measurements. Modified NPs with PFOS showed a significant improvement in hydrophobic properties, with water contact angles of 144.73° and sliding angles of 5°. The stability of these surfaces under various pH conditions was also evaluated. This research contributes valuable insights into the development of self-cleaning coatings for glass and photovoltaic cells, demonstrating the potential of superhydrophobic surfaces in practical applications. Highlights: Cost-effective superhydrophobic coatings: A scalable and cost-effective spray-coating method was developed using modified SiO₂ nanoparticles, PFOS, and PDMS to create superhydrophobic surfaces on glass. Significant water repellency: The coatings achieved an impressive water contact angle of 144.73° and a sliding angle of 5°, demonstrating excellent hydrophobic properties close to the superhydrophobic benchmark. Enhanced surface roughness: The dual-phase modification process, involving SiO₂ nanoparticles and PFOS, significantly increased surface roughness, a key factor for maximizing hydrophobicity. Chemical durability: The superhydrophobic coatings exhibited excellent durability, maintaining their properties under various pH conditions, including acidic, neutral, and basic environments. Simple and scalable process: The method used for developing these coatings is both simple and scalable, offering a practical approach for producing durable superhydrophobic surfaces suitable for various industrial applications. [ABSTRACT FROM AUTHOR]- Published
- 2024
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9. Research Progress of Superhydrophobic Coatings Constructed by Arrayed and Non‐Arrayed Carbon Nanotubes for Anti‐Corrosion, Anti‐Icing and Photothermal De‐Icing.
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Hao, Xiaoru, Xu, Longxiang, Cheng, Zhihao, Ji, Haowen, Dang, Chaobin, and Zheng, Haikun
- Abstract
The preparation methods of superhydrophobic nanocomposite surfaces based on carbon nanotubes are reviewed in view of the different arrangement accuracy and various performance differences of the preparation methods of superhydrophobic surfaces of arrayed and non‐arrayed carbon nanotubes. The application progress of superhydrophobic surfaces of non‐arrayed carbon nanotubes in the fields of anti‐corrosion, anti‐icing and photothermal de‐icing is introduced. On the basis of summarizing the basic preparation methods and properties of carbon nanotubes, the advantages of carbon nanotubes as superhydrophobic surface materials are clarified. By analyzing and comparing the preparation methods of superhydrophobic surface of arrayed carbon nanotubes and non‐arrayed carbon nanotubes, it is concluded that the superhydrophobic surface of arrayed carbon nanotubes has some shortcomings compared with the superhydrophobic surface of non‐arrayed carbon nanotubes. The superhydrophobic surface of non‐arrayed carbon nanotubes offers advantages such as excellent long‐term durability and unique functionality, which will become the focus of research on the preparation of superhydrophobic surfaces based on carbon nanotubes. This will provide guidance for future research on the large‐scale preparation of such surfaces. [ABSTRACT FROM AUTHOR]
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- 2024
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10. Heat Treatment of PTFE/PDMS/Nano‐silica Deposited Layer for Preparation of Superhydrophobic Coating with Anti‐corrosion, Anti‐scaling, and Anti‐fouling Properties.
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Yin, Zichao, Sun, Zhenhua, Li, Junyi, Zhou, Haigang, Qi, Jingjing, and Wang, Weidong
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CONTACT angle , *IRON & steel plates , *CORROSION resistance , *HEAT treatment , *SURFACE coatings , *POLYTEF - Abstract
PTFE‐based superhydrophobic coatings have received increasing research and the fabricated coatings exhibited excellent anti‐corrosion, anti‐scaling, anti‐fouling, and anti‐icing properties. In order to further enhance the hydrophobicity of PTFE coating, a PTFE‐based coating consisted of nano‐silica and polydimethylsiloxane (PDMS) was fabricated by deposition coating and annealing treatment. The water contact angle and sliding angle of the coating achieved 160.65° and 3.02°, respectively, demonstrating it possessed superhydrophobic property. Due to its excellent surface feature, the coating exhibited resistance to milk, coffee, and mud water, and could be easily cleaned by water flow. Besides, the water droplet on the coating had a longer freezing time and the ice droplet could be easily removed from the coating. Ascribed to the abundant nonpolar groups and the air cushion formed under water, the prepared coating had outstanding anti‐scaling and anti‐corrosion properties. The electrochemical impedance of the steel plate with the coating (above 9000 Ω·cm2) increased by two orders of magnitude compared with the non‐coating one (78.2 Ω·cm2), and the anti‐scaling rates of the coating towards BaSO4 and SrSO4 were all above 80%. It is promising that the coating will be a competitive candidate in many application fields. [ABSTRACT FROM AUTHOR]
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- 2024
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11. Designing biodegradable and antibacterial cellulose-based superhydrophobic packaging materials via large-scale self-assembly.
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Li, Qiang, Jiang, Xiaofan, Huang, Mingjun, Lv, Jiachen, Ling, Zhe, Wang, Songlin, Chen, Fushan, and Ji, Zhe
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TITANIUM dioxide nanoparticles ,PACKAGING materials ,SUSTAINABILITY ,MECHANICAL abrasion ,BACTERIAL adhesion - Abstract
Unbiodegradable petroleum-based packaging materials have posed a significant threat to the environment and human health, forcing the exploration of alternatives. Inspired by the charge-secreting layer of Sandcastle worm and the asymmetric wettability of lotus leaf, we successfully developed a dual biomimetic cellulose-based packaging material (CW@(CT)
10 ). This material was achieved through an electrically charge-controlled layer-by-layer self-assembly of chitosan and titanium dioxide nanoparticles (TiO₂ NPs), followed by functionalization with carnauba wax (CW). The material achieved commendable mechanical properties and abrasion resistance, rendering it highly stable and durable. Benefitting from the rough surface with nanostructures and low surface energy, the CW@(CT)10 showed a high water contact angle of 152.14°. The superhydrophobic surface reduced the bacterial adhesion, which integrated with the electropositivity of chitosan, endowing the materials with a 100% antibacterial ability to Staphylococcus aureus and Escherichia coli. Fruit antimicrobial tests and degradation studies in the natural environment demonstrated that CW@(CT)10 kept fruit bacteria-free for 5 days and were completely biodegraded within 100 days. Notably, this work introduced a facile strategy for scalable production of a sustainable, inexpensive, durable, and environmentally friendly material, showcasing immense potential applications in food packaging. [ABSTRACT FROM AUTHOR]- Published
- 2024
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12. Study on Intelligent Bionic Superhydrophobic Material and its Oil‐Water Separation Mechanism.
- Author
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Wang, Zuoliang, Qu, Guangfei, Ren, Yuanchuan, Chen, Xiuping, Wang, Jun, and Lu, Ping
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PETROLEUM in submerged lands , *OIL spills , *WATER pollution , *CONTACT angle , *BROMOMETHANE , *OIL spill cleanup - Abstract
Marine oil spills and improper disposal of daily oil usage have posed significant threat to ecological environments and human health due to rapid industrial development. In this study, an environmentally friendly, simple process and high‐performance Fe3O4@SiO2@Polymethyl methacrylate (PMMA)‐based smart bionic superhydrophobic oil‐absorbing material was developed for effectively collecting and removing oil pollutants from water. By studying the effects of Fe3O4 particle size, polydimethylsiloxane (PDMS) concentration, and heating time on the superhydrophobicity of the materials, the directional regulation of superhydrophobicity and oil‐water separation performance of Fe3O4@SiO2@PMMA@PDMS materials was realized. The results showed that the material exhibited optimal performance when the Fe3O4 particle size combination was 20/500 nm/1 μm, the mass ratio of PDMS to Fe3O4@SiO2@PMMA was 7 : 1, and it was heated at 350°C for 1 minute. The coating achieved an apparent contact angle (APCA) of 158.7° and a rolling angle as low as 4.9°. This coating not only remained superhydrophobic after a 21 m abrasion test and 288 h immersion in acid, alkali, salt, and high‐temperature solutions, but also efficiently separated oil‐water mixtures and water‐in‐oil emulsions, and the separation efficiency for oil‐water mixtures of trichloromethane, dichloromethane and bromomethane was over 99.78 %, and that for water‐in‐oil emulsions was over 98.34 %. Furthermore, the superhydrophobic magnetic polyurethane (SFPU) sponge prepared using Fe3O4@SiO2@PMMA not only exhibited excellent oil‐absorbing capacity (11–28 g/g), but also realized precise oil absorption at multiple sites by magnetic conduction. In the actual oily wastewater test, the oil‐water separation efficiency of the sponge reached 90.58 % and the oil absorption capacity reached 17.03 g/g. This efficient oil‐water separation performance as well as oil adsorption capacity comes from the fact that the nonpolar molecules (e. g., −CH3) generated by the hydrolysis of PDMS can produce van der Waals adsorption with oil substances, while the excellent micro‐nanostructure of the coating surface greatly increases the contact area between oil droplets and the coating, which can make them adsorb or pass through quickly. This multifunctional coating and sponge had immense application potential in fields like offshore oil spill treatment, organic pollution control in water bodies. [ABSTRACT FROM AUTHOR]
- Published
- 2024
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13. Pioneering technologies over time to rehabilitate crude oil–contaminated ecosystems: a review.
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Baruah, Netra Prova, Goswami, Manisha, Sarma, Nimisha, Chowdhury, Devasish, and Devi, Arundhuti
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POLYCYCLIC aromatic hydrocarbons ,PETROLEUM ,HEAVY oil ,POISONS ,FOSSIL fuels - Abstract
The unremitting pollution of our environment induced by crude oil spillage and drilling site accidents has jeopardized every living species in the biological ecosystem. Removing heavy crude oil constituents with the help of traditional and mainstream oil sorbents because of their ingrained raised viscosities is a strenuous venture. Lighter distillates of crude oil, like condensate, do not aggregate with tremulous shine on the aquatic surface nor settle at the bottom sediment of the water bodies like the heavier components do with time. Fabricating optimally designed materials capable of capturing, degrading, or removing toxic chemical constituents of this fossil fuel is critical in this modern era. This review comprehensively discusses the evolution of scientific technologies developed to separate these constituents from land and aquatic bodies. We provide an overview of the latest physical and chemical strategies and prevalent biological remediation schemes for removing these pollutants from soils and water for environmental protection. The article highlights the urgency of preventing oil spill accidents, whose anticipation is challenging to harness. A spectrum of advanced functional methodologies is also discussed to adequately treat discharged hydrocarbon contaminants, establish public safety, and pave the path to enhancing the circular economy metrics linked with oil industries. [ABSTRACT FROM AUTHOR]
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- 2024
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14. Droplet impact dynamics on the surface of super-hydrophobic BNNTs stainless steel mesh.
- Author
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Zhang, Lie, Feng, Yongbao, Li, Liang, Li, Shuzhi, Yuan, Bo, Han, Xiaoxia, and He, Zhenxin
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CONTACT angle , *SUPERHYDROPHOBIC surfaces , *BORON nitride , *SURFACES (Technology) , *MOLECULAR dynamics - Abstract
The 'gas‒liquid‒solid' mechanism annealing method was used to create a superhydrophobic boron nitride nanotube (BNNT) stainless steel mesh in a tube furnace at 1250 °C in an NH3 environment. Fe powder was used as a catalyst, and B:B2O3 = 4:1 was used as the raw material. The water droplets on the surface of the superhydrophobic material had a contact angle of approximately 150° and a slide angle of approximately 3°. By using molecular dynamics (MD) simulation technology, a three-dimensional braided physical model of nanodroplets and superhydrophobic BNNT mesh surfaces with the same contact angle and rolling angle was prepared via the function weaving method. The Weber number (We) was used as the entrance point to establish the relationship between macroscale experimental studies and nanoscale MD simulation analysis on the basis of these efforts. A study was conducted on the dynamic behaviour of droplets impacting a superhydrophobic BNNT filter surface. We suggest that the wettability, substrate structure, and impact velocity are connected to the impact dynamic behaviour of droplets on the basis of the data obtained at various scales. The findings demonstrate that when the droplet impact velocity increases, several droplet phenomena—such as impact–rebound, impact–spread–rebound, and impact–spread–breaking–polymerisation–spatter—appear on the substrate surface sequentially. The mechanism of impact behaviour at various scales is explained in light of these events. Furthermore, a better theoretical model is proposed to assess the droplet wetting transition at the nanoscale. This model accurately predicts the boundary Weber number that starts the wetting transition. Moreover, the connections among the impact velocity, spreading diameter, and contact time (or We) are examined. The tendencies found via MD simulations match the outcomes of the experiments. Our discoveries and outcomes broaden our understanding of how droplet impact affects the dynamic behaviour of superhydrophobic surfaces. A scientific foundation for examining the dynamic behaviour of droplets is provided by combining simulations and experiments. [ABSTRACT FROM AUTHOR]
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- 2024
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15. Synthesis and Characterization of ZnO Nanoparticles and Their Application on Cotton Fabrics to Obtain Superhydrophobic Surfaces.
- Author
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Ebrahim, Mai and Saffour, Ziad
- Subjects
SUPERHYDROPHOBIC surfaces ,SCANNING electron microscopy ,CONTACT angle ,ZINC chloride ,COTTON textiles - Abstract
Copyright of Baghdad Science Journal is the property of Republic of Iraq Ministry of Higher Education & Scientific Research (MOHESR) and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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- 2024
- Full Text
- View/download PDF
16. Durable superhydrophobic cotton fabrics with electromagnetic wave absorption based on MoS2/RGO composites.
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Cai, Yangfang, Xu, Lihui, Pan, Hong, Zhao, Hong, Yao, Chengjian, Yang, Qun, Shen, Yong, Wang, Liming, Dou, Meiran, Teng, Yi, Zhang, Yingxiu, Hu, Lei, and Wang, Yihong
- Subjects
COTTON textiles ,CONTACT angle ,SURFACE energy ,SURFACE morphology ,CHEMICAL stability ,ELECTROMAGNETIC wave absorption - Abstract
Durable superhydrophobic fabrics with electromagnetic wave absorption were highly valuable in practical applications. In this work, durable superhydrophobic cotton fabrics with electromagnetic wave absorption were successfully prepared by modifying the cotton fabrics with polydopamine (PDA) and then depositing MoS
2 /RGO (MR) composites and polydimethylsiloxane (PDMS). The surface morphology, crystal structure, and thermal degradation properties of the obtained products were evaluated. The PDA modification enhanced the affinity and adsorption saturation between the fabrics and the MR composites. Here, the MR composites provided the fabrics with wave-absorbing components and rough micro/nanostructure, and the PDMS offered lower surface energy for the treated fabrics. Ultimately, the water contact angle (WCA) of the obtained cotton fabrics could reach 157.2 ± 0.4 ° and the minimum reflection loss (RLmin ) was −45.3 dB at 11.1 GHz, which showed excellent superhydrophobicity and microwave absorption properties. In addition, the obtained cotton fabrics displayed excellent robustness against rubbing, bending, and laundrying and satisfactory chemical stability. This research showed promising prospects for the development of wearable materials with durable electromagnetic wave absorption. [ABSTRACT FROM AUTHOR]- Published
- 2024
- Full Text
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17. Light‐ and Heat‐Responsive Superhydrophobic Surfaces with Shape Memory Capacity Prepared by 4D Printing.
- Author
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Li, Xiang, Zhan, Yanlong, Li, Wen, Huang, Zhihong, and Amirfazli, Alidad
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SHAPE memory effect ,POLYLACTIC acid ,PHOTOTHERMAL effect ,MANUFACTURING processes ,CARBON-black ,SHAPE memory polymers ,SUPERHYDROPHOBIC surfaces - Abstract
The precise manipulation of microdroplets on solid surfaces is crucial for the practical application and future development of microfluidic control technology. Traditionally, methods to achieve precise control over microdroplets often involve complex fabrication processes. Herein, the control of surface wettability is achieved based on the light‐ and heat‐responsive shape memory effect of the microstructure. An innovative superhydrophobic shape‐memory material with a simplified and efficient manufacturing process is proposed to precisely control microdroplets through surface wettability switching. Firstly, microplates with shape‐memory effects are manufactured using 4D printing technology and polylactic acid as the base material. Then, a mixture of carbon black and epoxy resin is sprayed onto the surface for superhydrophobic modification, resulting in a contact angle of up to 165°. The addition of carbon black endows the surface with excellent photothermal conversion effects. Anisotropy and photothermal response studies are incorporated. Through periodic heating, pressing, and deformation, the microplate array exhibits controllable wettability switching. Based on the shape‐memory effect of polylactic acid, the superhydrophobic surface has adjustable adhesion and is successfully applied to microfluidic platforms and microdroplet size screening. This innovative material and process offer significant potential for advancing the field of microfluidic control technology. [ABSTRACT FROM AUTHOR]
- Published
- 2024
- Full Text
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18. Electrothermal/Superhydrophobic Anti-Deicing Coating with a Sandwich Structure Based on Micro-Nanomaterials.
- Author
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Li, Ke, Wang, Qiang, Zhou, Xu, He, Yulong, Shi, Yanan, Qin, Mengjie, Wu, Binrui, Chen, Ningli, Liu, Ruidi, and Yi, Xian
- Abstract
The freezing phenomenon poses significant challenges in many fields, causing serious casualties and economic losses. Compared with traditional measures, active/passive coupled anti-deicing technology exhibits greater adaptability and effectiveness in diverse scenarios. Herein, an electrothermal/superhydrophobic coating featuring a sandwich structure was proposed for anti-deicing applications. Benefiting from the hydrophobic modified micro-nanostructure, this superhydrophobic coating boasted remarkable abilities to delay icing and repel water adhesion, rendering it ideal for combating freezing rain. Under a certain electrothermal power density, the coating could be heated quickly and evenly. Furthermore, it has proven to be highly capable of enduring prolonged continuous heating and rigorous high–low-temperature cycling tests, delivering exceptional performance. To evaluate its dynamic anti-icing performance, icing wind tunnel tests were conducted, which demonstrated that the coating can prevent freezing with the coupled electrothermal/superhydrophobic properties, even under harsh icing environments. This work would inspire the design of electrothermal/superhydrophobic anti-deicing coating with a sandwich structure and promote the practical engineering applications. [ABSTRACT FROM AUTHOR]
- Published
- 2024
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19. 超双疏表面的制备及应用进展.
- Author
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周学湫, 汪希奎, 覃冰黎, 罗鸿,韦函, and 梅益
- Abstract
Copyright of Acta Materiae Compositae Sinica is the property of Acta Materiea Compositae Sinica Editorial Department and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
- Published
- 2024
- Full Text
- View/download PDF
20. Antifouling Properties of Electrospun Polymeric Coatings Induced by Controlled Surface Morphology.
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Favrin, Fabio L., Zavagna, Lorenzo, Sestini, Matteo, Esin, Semih, Azimi, Bahareh, Labardi, Massimiliano, Milazzo, Mario, Gallone, Giuseppe, Batoni, Giovanna, and Danti, Serena
- Subjects
BACTERIAL adhesion ,FIBER orientation ,BACTERIAL contamination ,SURFACE coatings ,MEDICAL equipment - Abstract
Nosocomial infections affect implanted medical devices and greatly challenge their functional outcomes, becoming sometimes life threatening for the patients. Therefore, aggressive antibiotic therapies are administered, which often require the use of last‐resort drugs, if the infection is caused by multi‐drug‐resistant bacteria. Reducing the risk of bacterial contamination of medical devices in the hospitals has thus become an emerging issue. Promising routes to control these infections are based on materials provided with intrinsic bactericidal properties (i.e., chemical action) and on the design of surface coatings able to limit bacteria adhesion and fouling phenomena (i.e., physical action), thus preventing bacterial biofilm formation. Here, we report the development and validation of coatings made of layer‐by‐layer deposition of electrospun poly(vinylidene fluoride‐co‐trifluoro ethylene) P(VDF‐TrFE) fibers with controlled orientations, which ultimately gave rise to antifouling surfaces. The obtained 10‐layer surface morphology with 90° orientation fibers was able to efficiently prevent the adhesion of bacteria, by establishing a superhydrophobic‐like behavior compatible with the Cassie‐Baxter regimen. Moreover, the results highlighted that surface wettability and bacteria adhesion could be controlled using fibers with diameter comparable to bacteria size (i.e., achievable via electrospinning process), by tuning the intra‐fiber spacing, with relevant implications in the future design of biomedical surface coatings. [ABSTRACT FROM AUTHOR]
- Published
- 2024
- Full Text
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21. Biomimetic Superhydrophobic Triboelectric Surface Prepared by Interfacial Self‐Assembly for Water Harvesting.
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Zhang, Puyang, Zhang, Song, Li, Xiuzhen, Liu, Tao, Zhao, Tong, Wang, Jinlong, Luo, Bin, Cai, Chenchen, Liu, Yanhua, Shao, Yuzheng, Du, Guoli, Wang, Shuangfei, and Nie, Shuangxi
- Subjects
- *
WATER harvesting , *TRIBOELECTRICITY , *SUPERHYDROPHOBIC surfaces , *WATER shortages , *MASS transfer - Abstract
Extracting water from air offers a promising route to address the global challenge of water scarcity. However, bionic engineering surfaces for water harvesting often struggle with efficiently coordinating droplet nucleation and desorption. The recently emerging triboelectric effect at the liquid–solid interface offers a novel approach for developing bionic fog harvesting surfaces. In this study, inspired by Namib Desert beetles and lotus leaves, a biomimetic superhydrophobic surface with nanoscale hydrophilic domains is prepared via interfacial self‐assembly, exhibiting heterogeneous wettability for effective water harvesting. The essence of interfacial self‐assembly lies in the synergy of non‐covalent interaction forces, driving the self‐assembly of nanoparticles into surface micro‐nano hierarchical structures, thereby regulating wettability and increasing potential nucleation sites. Additionally, the triboelectric effect can directly utilize the triboelectric charges to facilitate droplet migration. The triboelectric effect can be generated by flexible mechanical input induced by walking, which enhances interfacial mass transfer, thereby rapidly improving droplet removal and achieving a 39.02% increase in water harvesting efficiency. This study has opened up a new breakthrough for the design of portable and efficient water harvesting systems. [ABSTRACT FROM AUTHOR]
- Published
- 2024
- Full Text
- View/download PDF
22. Laser-based functionalization for superhydrophobic silicon carbide with mechanical durability, anti-icing and anti-fouling properties.
- Author
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Fu, Jiajun, Liu, Chao, Wang, Huixin, Song, Xinrong, Shi, Zhe, Guo, Xiaozhe, Li, Ziang, and Wang, Qinghua
- Subjects
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X-ray photoelectron spectroscopy , *SURFACE chemistry , *SURFACE energy , *ICE prevention & control , *SILICON surfaces , *SUPERHYDROPHOBIC surfaces - Abstract
The further applications of silicon carbide (SiC) are limited due to the ease of being contaminated and tendency for icing at low temperature caused by its intrinsically hydrophilicity. In recent years, superhydrophobic surface has been widely employed due to the potential value in anti-fouling and passive anti-icing. In this work, a novel laser ablation-silicone oil heat treatment (LASH) composite process is proposed to fabricate superhydrophobic SiC surface. Many microscale "fence" structures and nanoscale "broccoli" fragmental structures are successfully obtained, which can be adjusted by using different laser processing parameters. Besides, the X-ray photoelectron spectroscopy analysis demonstrates that the effective deposition of low surface energy chemical functional groups is the key to realize the superhydrophobic properties of SiC surface. The coupling effect between the micro/nano structures and low surface energy is confirmed to be important for the stability of Cassie-Baxter state at low temperature. In addition, the freezing process of water droplets on the LASH surface at low temperature and the mechanism of the rapid transition from Wenzel state to Cassie-Baxter state are analyzed. The experimental results indicate that the LASH surface possesses a longer static icing time and keeps good hydrophobicity at −5 °C. The icing temperature of the LASH surface decreases to −17.6 °C while the temperature of the untreated surface is −3.7 °C. Moreover, the LASH surface possesses a lower ice adhesion strength which means it is easier for the ice droplets to break away from the surface. After 20 cycles of icing-deicing experiments, the WCA of the LASH surface is still higher than 150° and its ice adhesion strength slightly increases to 240 kPa. Finally, the mechanical robustness of the LASH surface is studied through the abrasive belt and tape stripping tests, and the anti-fouling property is also evaluated. The change of ice adhesion strength on the LASH surface under cyclic icing experiment is analyzed. The experimental results show that the LASH surface has great mechanical durability and anti-fouling property, which is expected to further expand the application prospects of SiC in different fields. [Display omitted] • LASH composite process is developed to fabricate superhydrophobic silicon carbide surface. • Micro/nano structures and surface chemistry play important roles for superhydrophobicity. • Wettability of the surface can be controlled by adjusting the laser processing parameters. • LASH surface can achieve free transition from Wenzel state to Cassie-Baxter state. • LASH surface possesses excellent mechanical durability and anti-icing properties. [ABSTRACT FROM AUTHOR]
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- 2024
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- View/download PDF
23. A Shape-Restorable hierarchical polymer membrane composite system for enhanced antibacterial and antiadhesive efficiency.
- Author
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Tang, Yanan, Qin, Zhen, Yan, Xianqiang, Song, Yudong, Zhang, Lan, Li, Bingqian, Sun, Hang, and Wang, Guangbin
- Subjects
- *
POLYLACTIC acid , *COMPOSITE membranes (Chemistry) , *POLYMERIC membranes , *POLYMER blends , *SHAPE memory polymers , *ESCHERICHIA coli , *ARTIFICIAL implants , *BACTERIAL diseases - Abstract
[Display omitted] Intelligent shape memory polymer can be potentially used in manufacturing implantable devices that enables a benign variation of implant dimensions with the external stimuli, thus effectively lowering insertion forces and evading associated risks. However, in surgical implantation, biomaterials-associated infection has imposed a huge burden to healthcare system that urgently requires an efficacious replacement of antibiotic usages. Preventing the initial attachment and harvesting a biocidal function upon native surfaces may be deemed as a preferable strategy to tackle the issues of bacterial infection. Herein, a functionalized polylactic acid (PLA) composite membrane assembled with graphene (GE, a widely used photothermal agent) was fabricated through a blending process and then polydimethylsiloxane utilized as binders to pack hydrophobic SiO 2 tightly onto polymer surface (denoted as PLA-GE/SiO 2). Such an active platform exhibited a moderate shape-memory performance upon near-infrared (NIR) light stimulation, which was feasible for programmed deformation and shape recovery. Particularly stirring was that PLA-GE/SiO 2 exerted a pronounced bacteria-killing effect under NIR illumination, 99.9 % of E. coli and 99.8 % of S. aureus were effectively eradicated in a lean period of 5 min. Furthermore, the obtained composite membrane manifested excellent antiadhesive properties, resulting in a bacteria-repelling efficacy of up to 99 % for both E. coli and S. aureus species. These findings demonstrated the potential value of PLA-GE/SiO 2 as a shape-restorable platform in "kill&repel" integration strategy, further expanding its applications for clinical anti-infective treatment. [ABSTRACT FROM AUTHOR]
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- 2024
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24. Bioinspired Stretchable Strain Sensor with High Linearity and Superhydrophobicity for Underwater Applications.
- Author
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Wu, Huansheng, Wang, Cong, Liu, Linpeng, Liu, Zhilin, He, Jiahua, Zhang, Changchao, and Duan, Ji‐an
- Subjects
- *
MARINE resources conservation , *STRAIN sensors , *ELECTRONIC equipment , *CONTACT angle , *DETECTORS - Abstract
Flexible strain sensors are of great significance in health monitoring, wearable electronic devices, intelligent robot sensing, and other fields. Most of the reported works focus on the enhancement of sensitivity or working range, while linearity is ignored and exhibits strong nonlinearity. Conflict among performances remains a serious challenge for the development of flexible strain sensors. Herein, inspired by the architecture of butterfly's wings, a strain sensor with double conductive layers and wrinkles/holes structures is proposed. The fabricated sensor shows a high linearity of >0.98 over a full working strain range of 120%, and a linearity of up to 0.999 within a strain range of 0%–30%. Apart from that, the sensor also presents a sensitivity of 8.28, high stability over 40 000 cycles when subjected to a full‐scale strain, as well as a water contact angle of >167.4°. Meanwhile, strains as low as 0.075% can be identified, while a maximum frequency of 40 Hz can be responded to for the sensor. It is demonstrated that the sensor is capable of enabling flexible grippers to sense and monitor the motions of underwater vehicles, indicating its greater potential for diverse applications, such as human–machine interaction, marine environmental protection, and biological research. [ABSTRACT FROM AUTHOR]
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- 2024
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25. Easily Applicable Superhydrophobic Composite Coating with Improved Corrosion Resistance and Delayed Icing Properties.
- Author
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Zhang, Binbin, Zhao, Lixia, and Hou, Baorong
- Subjects
- *
ALUMINUM alloys , *CORROSION potential , *COMPOSITE coating , *CONTACT angle , *CORROSION resistance - Abstract
Mitigating the adverse effects of corrosion failure and low-temperature icing on aluminum (Al) alloy materials poses significant research challenges. The facile fabrication of bioinspired superhydrophobic materials offers a promising solution to the issues of corrosion and icing. In this study, we utilized laboratory-collected candle soot (CS), hydrophobic fumed SiO2, and epoxy resin (EP) to create a HF-SiO2@CS@EP superhydrophobic coating on Al alloy surfaces using a spray-coating technique. Various characterization techniques, including contact angle meter, high-speed camera, FE-SEM, EDS, FTIR, and XPS, were employed to investigate surface wettability, morphologies, and chemical compositions. Moreover, a 3.5 wt.% NaCl solution was used as a corrosive medium to evaluate the corrosion resistance of the uncoated and coated samples. The results show that the capacitive arc radius, charge transfer resistance, and low-frequency modulus of the coated Al alloy significantly increased, while the corrosion potential (Ecorr) shifted positively and the corrosion current (Icorr) decreased by two orders of magnitude, indicating improved corrosion resistance. Additionally, an investigation of ice formation on the coated Al alloy at −10 °C revealed that the freezing time was 4.75 times longer and the ice adhesion strength was one-fifth of the uncoated Al alloy substrate, demonstrating superior delayed icing and reduced ice adhesion strength performance. [ABSTRACT FROM AUTHOR]
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- 2024
- Full Text
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26. Enhancing Resistance to Corrosion and Fouling Using Epoxy Coatings with Superhydrophobic Cells.
- Author
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Xia, Yage, Gu, Wancheng, Zhang, Qiang, Yang, Zhongtian, Lv, Xinyu, Ji, Yanzheng, Deng, Weilin, Liu, Weiwei, Dong, Lei, Feng, Pan, Ran, Qianpin, Yu, Xinquan, and Zhang, Youfa
- Subjects
- *
SALT spray testing , *CORROSION prevention , *CORROSION resistance , *CORROSION potential , *HYDROXYL group , *EPOXY coatings - Abstract
As maritime transport becomes increasingly important, metal corrosion results in significant economic losses. Superhydrophobic materials have significant potential for corrosion prevention. However, poor compatibility between superhydrophobic materials and resin reduces the long‐term corrosion resistance. Interfacial strengthening cells (IS‐Cells) are designed to maintain superhydrophobicity and retain active hydroxyl groups participating in resin‐curing. IS‐Cells also contribute to achieving the maze effect. A novel anti‐corrosion IS coating is fabricated by compatible IS‐Cells and epoxy. IS coatings feature smooth surfaces and vertical compactness, protecting against liquid and gaseous corrosive medium. Strong diffusion resistance and extended diffusion distance ensure long‐term corrosion resistance of IS coatings. Approximately 85 µm of IS coatings remain corrosion‐free after 112 days of immersion in the NaCl solution. The low‐frequency impedance, self‐corrosion potential, and self‐corrosion current density are 1.68 × 109 Ω cm2, −0.0708 V, and 5.38 × 10−11 A cm−2, respectively. IS coatings can also withstand 2400 h of neutral salt spray testing without corrosion in the artificial scratches. Due to the electrostatic repulsion between the hydrophobic C–F chains onto IS‐Cells and protein molecules, IS coatings maintain anti‐fouling properties after dry‐wet immersion tests in the natural marine environment for 90 days. IS coatings show great potential for marine anti‐corrosion applications. [ABSTRACT FROM AUTHOR]
- Published
- 2024
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27. Nonflammable superhydrophobic passive cooling Cellulose-CaCO3 film.
- Author
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Xu, Chang-Lian, Yuan, Chongfeng, Yang, Zelong, Xu, Xiaoxun, Wang, Guiyin, Yang, Zhanbiao, Cheng, Zhang, Zhang, Shirong, Li, Ting, Lv, Guochun, Cai, Junzhuo, and Qi, Xin
- Subjects
- *
WASTE paper , *COOLING of water , *WASTE recycling , *WATER harvesting , *COOLING , *OIL spill cleanup , *SWEET corn - Abstract
[Display omitted] Energy consumption from air cooling systems in summer, water scarcity in hot regions, and the functional reusability of waste paper are emerging environmental problems. Finding solutions to these problems simultaneously remains a significant challenge. Herein, a superhydrophobic passive cooling Cellulose-CaCO 3 film with hierarchical nano-sheets was fabricated to realize daytime radiative cooling with a temperature drop of 15–20 °C in summer and water harvesting with harvesting efficiency of 387 mg cm−2h−1 bd utilization of recycled waste paper. The superhydrophobic Cellulose-CaCO 3 film demonstrates its self-cleaning properties against inorganic and organic pollutants. Furthermore, the superhydrophobicity of the film was maintained after base/acid corrosions, dynamic water flushing, and thermal treatment at 100 °C for 7 h, exhibiting good durability of the superhydrophobicity. Moreover, the superhydrophobic Cellulose-CaCO 3 film is nonflammable after exposure to fire combustion for 1 min. In addition to waste paper, waste maize straws, and pasteboards were also collected to produce superhydrophobic passive cooling films. Results indicate that the above three cellulose-based raw materials can be well used to prepare durable superhydrophobic passive cooling materials. Environmental toxicology assessments confirm the safety of the material. This study not only provides a protocol for preparing superhydrophobic materials; but also demonstrates their potential for passive cooling and water harvesting. [ABSTRACT FROM AUTHOR]
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- 2024
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28. 耐磨防覆冰聚四氟乙烯表面设计与加工.
- Author
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何志豪, 张柄桢, 潘维浩, 孙晶, and 宋金龙
- Subjects
SUPERHYDROPHOBIC surfaces ,LASER engraving ,CONTACT angle ,WEAR resistance ,CLEANING equipment - Abstract
Copyright of Acta Materiae Compositae Sinica is the property of Acta Materiea Compositae Sinica Editorial Department and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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- 2024
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29. Enhanced mechanical stability and corrosion resistance of superhydrophobic coating reinforced with inorganic binder.
- Author
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Zhao, Li-xia, Li, Hong-yan, Zhou, Kun, Liu, Hai-xing, Wang, Jian, and Zhang, Bin-bin
- Abstract
Copyright of Journal of Central South University is the property of Springer Nature and its content may not be copied or emailed to multiple sites or posted to a listserv without the copyright holder's express written permission. However, users may print, download, or email articles for individual use. This abstract may be abridged. No warranty is given about the accuracy of the copy. Users should refer to the original published version of the material for the full abstract. (Copyright applies to all Abstracts.)
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- 2024
- Full Text
- View/download PDF
30. Development of self‐cleaning and antibacterial properties on cotton fabric using silver nanoparticles and PFOTS.
- Author
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Khan, Mahnoor, Saeed, Muhammad Adnan, Ullah, Sultan, Repon, Md. Reazuddin, Pranta, Arnob Dhar, Yunusov, Nurzod, and Hossain, Md Monir
- Subjects
COTTON textiles ,COTTON manufacture ,CHEMICAL testing ,SILVER nanoparticles ,CONTACT angle - Abstract
The demand for superhydrophobic fabric with self‐cleaning and antibacterial features as potential practical applications has been rising steadily with the passage of time. In this research work, the wet chemical method is used to manufacture cotton with a superhydrophobic coating. Thus, Nanoparticles of silver were produced by using an in situ method. Afterward, the fabric is treated with a solution of perfluorooctyltriethoxysilane to make it superhydrophobic. The cotton fabric performs remarkably with exceptional hydrophobicity as it had a contact angle of 157 ± 1° and less than 10° in sliding angle. Water droplet's dynamic behavior is also studied so that the superhydrophobic fabric development can be proven. The fabric shows excellent chemical durability by performing chemical tests. The antimicrobial and self‐cleaning properties are greatly enhanced by the superhydrophobic coating on cotton. Particle density on the superhydrophobic cotton before and after self‐cleaning was found 5.1 and 0.4 mg/cm2. In addition, the treated cotton fabric also exhibited superior antibacterial properties against Escherichia coli bacteria. Therefore, the developed multifunctional cotton fabric can be used in real‐life applications. Highlights: Cotton fabric enables to repelling of dirt, oil, and water‐based stains more effectively.Silver nanoparticles possess potent antibacterial properties.Incorporation of PFOTS controls the release of silver into the environment.Versatile applications from healthcare and hospitality to outdoor and athletic apparel. [ABSTRACT FROM AUTHOR]
- Published
- 2024
- Full Text
- View/download PDF
31. Superhydrophobic Corrosion-Resistant Coating of AZ91D Magnesium Alloy: Preparation and Performance.
- Author
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Qi, Shucheng, Liu, Xiang, Cheng, Lei, and Zhu, Jiyuan
- Subjects
COMPOSITE coating ,SURFACE preparation ,CONTACT angle ,SUBSTRATES (Materials science) ,SCANNING electron microscopy ,SURFACE coatings ,MAGNESIUM alloys - Abstract
This research presents the development of a surface treatment for AZ91D magnesium alloy that exhibits both superhydrophobic and anticorrosive properties. Initially, a zinc-based phosphate film was deposited on the magnesium alloy surface. Subsequently, a composite coating with superhydrophobic properties was produced by surface modification using a fluorosilane-ethanol solution. The composite coating's microstructure, chemical composition, wettability, self-cleaning, and anti-corrosion properties were evaluated using scanning electron microscopy, a contact angle measurement instrument, and an electrochemical workstation. The results demonstrated that the main components of the composite coating were P, O, Zn, F, and C. The static contact angle reached 158°, providing superior self-cleaning and acid and alkali corrosion resistance. Additionally, the charge transfer resistance and coating resistance of the composite coating were significantly higher than those of the magnesium alloy substrate, effectively preventing corrosion and preserving the surface from fouling. [ABSTRACT FROM AUTHOR]
- Published
- 2024
- Full Text
- View/download PDF
32. Droplet impact dynamics on the surface of super-hydrophobic BNNTs stainless steel mesh
- Author
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Lie Zhang, Yongbao Feng, Liang Li, Shuzhi Li, Bo Yuan, Xiaoxia Han, and Zhenxin He
- Subjects
Superhydrophobic ,Wetting theory ,MD simulation ,Boron nitride nanotubes ,Contact time ,Dynamic behaviour ,Medicine ,Science - Abstract
Abstract The ‘gas‒liquid‒solid’ mechanism annealing method was used to create a superhydrophobic boron nitride nanotube (BNNT) stainless steel mesh in a tube furnace at 1250 °C in an NH3 environment. Fe powder was used as a catalyst, and B:B2O3 = 4:1 was used as the raw material. The water droplets on the surface of the superhydrophobic material had a contact angle of approximately 150° and a slide angle of approximately 3°. By using molecular dynamics (MD) simulation technology, a three-dimensional braided physical model of nanodroplets and superhydrophobic BNNT mesh surfaces with the same contact angle and rolling angle was prepared via the function weaving method. The Weber number (We) was used as the entrance point to establish the relationship between macroscale experimental studies and nanoscale MD simulation analysis on the basis of these efforts. A study was conducted on the dynamic behaviour of droplets impacting a superhydrophobic BNNT filter surface. We suggest that the wettability, substrate structure, and impact velocity are connected to the impact dynamic behaviour of droplets on the basis of the data obtained at various scales. The findings demonstrate that when the droplet impact velocity increases, several droplet phenomena—such as impact–rebound, impact–spread–rebound, and impact–spread–breaking–polymerisation–spatter—appear on the substrate surface sequentially. The mechanism of impact behaviour at various scales is explained in light of these events. Furthermore, a better theoretical model is proposed to assess the droplet wetting transition at the nanoscale. This model accurately predicts the boundary Weber number that starts the wetting transition. Moreover, the connections among the impact velocity, spreading diameter, and contact time (or We) are examined. The tendencies found via MD simulations match the outcomes of the experiments. Our discoveries and outcomes broaden our understanding of how droplet impact affects the dynamic behaviour of superhydrophobic surfaces. A scientific foundation for examining the dynamic behaviour of droplets is provided by combining simulations and experiments.
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- 2024
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33. Robust, Flexible, and Superhydrophobic Fabrics for High-Efficiency and Ultrawide-Band Microwave Absorption
- Author
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Zhong Zhang, Yaxin Meng, Xinrui Fang, Qing Wang, Xungai Wang, Haitao Niu, and Hua Zhou
- Subjects
Microwave absorption ,Superhydrophobic ,Fabrics ,Coating ,Self-healing ,Engineering (General). Civil engineering (General) ,TA1-2040 - Abstract
Microwave absorption (MA) materials are essential for protecting against harmful electromagnetic radiation. In this study, highly efficient and ultrawide-band microwave-absorbing fabrics with superhydrophobic surface features were developed using a facile dip-coating method involving in situ graphene oxide (GO) reduction, deposition of TiO2 nanoparticles, and subsequent coating of a mixture of polydimethylsiloxane (PDMS) and octadecylamine (ODA) on polyester fabrics. Owing to the presence of hierarchically structured surfaces and low-surface-energy materials, the resultant reduced GO (rGO)/TiO2-ODA/PDMS-coated fabrics demonstrate superhydrophobicity with a water contact angle of 159° and sliding angle of 5°. Under the synergistic effects of conduction loss, interface polarization loss, and surface roughness topography, the optimized fabrics show excellent microwave absorbing performances with a minimum reflection loss (RLmin) of −47.4 dB and a maximum effective absorption bandwidth (EABmax) of 7.7 GHz at a small rGO loading of 6.9 wt%. In addition, the rGO/TiO2-ODA/PDMS coating was robust, and the coated fabrics could withstand repeated washing, soiling, long-term ultraviolet irradiation, and chemical attacks without losing their superhydrophobicity and MA properties. Moreover, the coating imparts self-healing properties to the fabrics. This study provides a promising and effective route for the development of robust and flexible materials with microwave-absorbing properties.
- Published
- 2024
- Full Text
- View/download PDF
34. Development of self‐cleaning and antibacterial properties on cotton fabric using silver nanoparticles and PFOTS
- Author
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Mahnoor Khan, Muhammad Adnan Saeed, Sultan Ullah, Md. Reazuddin Repon, Arnob Dhar Pranta, Nurzod Yunusov, and Md Monir Hossain
- Subjects
in situ method ,medical applications ,multifunctional properties ,nanoparticles ,superhydrophobic ,Polymers and polymer manufacture ,TP1080-1185 - Abstract
Abstract The demand for superhydrophobic fabric with self‐cleaning and antibacterial features as potential practical applications has been rising steadily with the passage of time. In this research work, the wet chemical method is used to manufacture cotton with a superhydrophobic coating. Thus, Nanoparticles of silver were produced by using an in situ method. Afterward, the fabric is treated with a solution of perfluorooctyltriethoxysilane to make it superhydrophobic. The cotton fabric performs remarkably with exceptional hydrophobicity as it had a contact angle of 157 ± 1° and less than 10° in sliding angle. Water droplet's dynamic behavior is also studied so that the superhydrophobic fabric development can be proven. The fabric shows excellent chemical durability by performing chemical tests. The antimicrobial and self‐cleaning properties are greatly enhanced by the superhydrophobic coating on cotton. Particle density on the superhydrophobic cotton before and after self‐cleaning was found 5.1 and 0.4 mg/cm2. In addition, the treated cotton fabric also exhibited superior antibacterial properties against Escherichia coli bacteria. Therefore, the developed multifunctional cotton fabric can be used in real‐life applications. Highlights Cotton fabric enables to repelling of dirt, oil, and water‐based stains more effectively. Silver nanoparticles possess potent antibacterial properties. Incorporation of PFOTS controls the release of silver into the environment. Versatile applications from healthcare and hospitality to outdoor and athletic apparel.
- Published
- 2024
- Full Text
- View/download PDF
35. Corrosion resistance of a superhydrophobic polypropylene coating on magnesium alloy AZ31
- Author
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Zhang, Shengjian, Li, Min, Li, Baoyi, Zhao, Hansen, and Wang, Feng
- Published
- 2024
- Full Text
- View/download PDF
36. Research advances in bio-inspired superhydrophobic surface: Bridging nature to practical applications.
- Author
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Zhang, Dong, Ji, Jinchao, Yan, Chengtao, Zhang, Jingrui, An, Zhoujian, and Shen, Yongqian
- Subjects
SUPERHYDROPHOBIC surfaces ,DRAG reduction ,ENGINEERS ,SURFACE properties ,NATURAL selection ,BIOMIMETIC materials - Abstract
[Display omitted] Evolved through millennia of natural selection, biological systems have perfected the integration of structure and function. With modern advances in characterization techniques and materials engineering, there has been a surge of interest in biomimetic superhydrophobic surfaces, combining unique structural properties and surface properties to engineer materials with exceptional performance. Through meticulous examination and mimetic replication of distinctive structures found in various natural organisms, engineers have achieved the development of superhydrophobic materials that reflect their specific functionalities, thereby presenting novel solutions to challenges across a spectrum of energy and industrial application domains. The succinct overview of wetting theory pertinent to superhydrophobic surface is briefly introduced in this paper. Besides, selected typical natural organisms are summarized, an in-depth analysis of their multiscale structures and components is offered, especially elucidating the key mechanisms underpinning their distinctive characteristics. Additionally, recent advancements in bio-inspired superhydrophobic surfaces are explored at length, with a focus on self-cleaning, drag reduction, oil–water separation, anti-reflection, and water collection. Lastly, insights into current challenges and future prospects for biomimetic superhydrophobic surfaces are provided. [ABSTRACT FROM AUTHOR]
- Published
- 2024
- Full Text
- View/download PDF
37. SiC-armoured triple-layered superhydrophobic coating with super-robustness and anti-corrosion durability.
- Author
-
Liang, Guangzhou, Zhou, Yuan, Hai, Chunxi, and Zhang, Binbin
- Subjects
CONTACT angle ,CORROSION potential ,CARBON steel ,RESIN adhesives ,CHARGE transfer - Abstract
[Display omitted] • A triple-layered superhydrophobic coating with mechanical stability was designed. • SiC was employed to endow the coating with an ultra-strong armoured structure. • The R ct of the coating was 8 orders of magnitude higher than bare Q235 substrate. • The coating exhibited anti-corrosion durability in marine atmospheric environment. Continuously enhancing the mechanical stability and durability of superhydrophobic corrosion-resistant materials is a great challenge for researchers. In this paper, we developed a SiC armoured triple-layered superhydrophobic coating with super-robustness on Q235 carbon steel substrates. The triple-layered coating was achieved by sequentially applying an epoxy (EP) resin adhesive layer, a SiC-armored skeleton structure, and a superhydrophobic F-Al 2 O 3 @EP layer. The resulting coating demonstrated outstanding non-wetting superhydrophobicity, featuring a static water contact angle (WCA) of 157.7 ± 0.5° and a sliding angle (SA) of 3.7 ± 0.6°. Moreover, the designed triple-layered superhydrophobic coating exhibits ultra-low interfacial adhesion force and demonstrates self-cleaning ability. Its mechanical stability was significantly heightened, enduring more than 2700 sandpaper abrasion cycles, 2200 tape-peeling cycles, and 3000 g sand impact resistance. Additionally, the coating displayed superior corrosion resistance with eight orders of magnitude enhanced charge transfer resistance (R ct), 590 mV positive shift corrosion potential (E corr), and six orders of magnitude lower corrosion current density (I corr) in a 3.5 wt% NaCl solution. Impressively, the SiC armoured triple-layered superhydrophobic coating demonstrated prolonged marine anti-corrosion performance, enduring immersion in a 3.5 wt% NaCl solution for over 1200 h and exposure to the outdoor marine atmospheric environment for more than 3360 h. We believe the development of superhydrophobic materials with high stability and durability contributes to their widespread adoption and multifunctional applications. [ABSTRACT FROM AUTHOR]
- Published
- 2024
- Full Text
- View/download PDF
38. Synthesis of Superhydrophobic Metal Coating Based on Nanostructured ZnO Thin Films in One Step: Effect of Solvents
- Author
-
Z. Belamri and L. Chetibi
- Subjects
superhydrophobic ,nanostructures ,one step ,contact angle ,zno thin film ,Mining engineering. Metallurgy ,TN1-997 ,Materials of engineering and construction. Mechanics of materials ,TA401-492 - Abstract
In this work, ZnO thin film is prepared by spraying a solution of zinc acetate precursor prepared with different solvents, namely, methanol, ethanol and distilled water at optimized conditions for aluminum substrate temperature and solution concentration. The impact of different solvents on the structural and hydrophobic properties of ZnO thin films was investigated by X-ray diffraction, Raman spectroscopy, Field Emission Scanning Electron Microscope and a Profilometer-Roughness Tester. The morphology of the elaborated ZnO thin films is spherical shaped nanostructured decorated by textures such as bumps (coexistence of ZnO micro-nanostructures). The results confirm that the different solvents used to prepare the ZnO thin films have a significant impact on the characteristics of these layers and the wettability study reveals that the surface of ZnO thin film prepared with distilled water is superhydrophobic.
- Published
- 2024
- Full Text
- View/download PDF
39. Graphene semiconductor superhydrophobic coating with stretchability
- Author
-
HUAI Jiru, WANG Peng, and YANG Mengyu
- Subjects
superhydrophobic ,electrothermal property ,anti-icing ,delayed icing ,Motor vehicles. Aeronautics. Astronautics ,TL1-4050 - Abstract
Superhydrophobic coating is the ideal anti-icing materials, and the superhydrophobic materials can delay the formation of ice crystals or reduce the strength of ice adhesion, but the existing coating has the problems such as poor mechanical property and fast natural aging of performance parameters. The modified graphene is partially embedded into the elastomer to produce a new coating. The icing-deicing performance of the coating is tested and compared, and the surface structure and chemical composition of the coating are analyzed. The results show that the new coating has a certain ability of electric deicing. In the re-mechanical properties test, the coating showed excellent properties in strain, wear resistance and aging resistance. The graphene introduced into the coating is the key to make the coating have a certain active deicing ability. The unique active and passive dual deicing properties of the coating are different from the traditional passive coating unique properties, which not only lays the foundation for the research and development of dual-attribute anti-icing coating but also opens up a new development direction of anti-icing coating.
- Published
- 2024
- Full Text
- View/download PDF
40. Superhydrophobic Absorbent Based on Multiwall Carbon Nanotubes and Superlight Clay for Solar-Assisted Crude Oil Cleanup.
- Author
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Cheng, Sijie, He, Enyu, Sutar, Rajaram S., Shi, Bairu, Xing, Ruimin, and Liu, Shanhu
- Abstract
Frequent oil spills pose a serious threat to the ecological environment and to human health. Therefore, it is a global topic to develop adsorbents with photothermal and superhydrophobic properties for the effective absorption of a high-viscosity crude oil. Herein, for the first time, the multiwall carbon nanotubes (MWCNTs)-superlight clay (SLC) was prepared using a freeze-drying method. Then, it was modified with octadecyl trichlorosilane (OTS) to obtain a superhydrophobic adsorbent (OTS/MWCNTs-SLC). The surface temperature of OTS/MWCNTs-SLC reaches 70 °C quickly under 1 kW m
–2 solar irradiation, which is essential to lower the viscosity of crude oil. Consequently, the adsorbent material demonstrated a crude oil absorption capacity of 19 ± 0.4 g/g and a light/heavy oil absorption capacity of 10–26 g/g. Additionally, the superhydrophobic photothermal OTS/MWCNTs-SLC exhibited mechanical and chemical stability and enabled continuous crude oil recovery. The prepared OTC/MWCNT-SLC broadens the application of SLC and provides a strategy for crude oil cleanup. [ABSTRACT FROM AUTHOR]- Published
- 2024
- Full Text
- View/download PDF
41. Stable and Durable Superhydrophobic Cotton Fabrics Prepared via a Simple 1,4‐Conjugate Addition Reaction for Ultrahigh Efficient Oil–Water Separation.
- Author
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Wu, Wanze, Miao, Shiwei, and Gong, Xiao
- Subjects
- *
OIL spill cleanup , *COTTON textiles , *ADDITION reactions , *CHEMICAL stability , *AMINO group - Abstract
Superhydrophobic materials used for oil–water separation have received wide attention. However, the simple and low‐cost strategy for making durable superhydrophobic materials remains a major challenge. Here, this work reports that stable and durable superhydrophobic cotton fabrics can be prepared using a simple two‐step impregnation process. Silica nanoparticles are surface modified by hydrolysis condensation of 3‐aminopropyltrimethoxysilane (APTMS). 1,4‐conjugate addition reaction between the acrylic group of cross‐linking agent pentaerythritol triacrylate (PETA) and the amino group of octadecylamine (ODA) forms a covalent cross‐linked rough network structure. The long hydrophobic chain of ODA makes the cotton fabric exhibit excellent superhydrophobic properties, and the water contact angle (WCA) of the fabric surface reaches 158°. The modified cotton fabric has good physical and chemical stability, self‐cleaning, and anti‐fouling. At the same time, the modified fabric shows excellent oil/water separation efficiency (98.16% after 20 cycles) and ultrahigh separation flux (15413.63 L m−2 h−1) due to its superhydrophobicity, superoleophilicity, and inherent porous structure. The method provides a broad prospect in the future diversification applications of oil/water separation and oil spill cleaning. [ABSTRACT FROM AUTHOR]
- Published
- 2024
- Full Text
- View/download PDF
42. Alkylated MXene–Carbon Nanotube/Microfiber Composite Material with Flexible, Superhydrophobic, and Sensing Properties.
- Author
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Wang, Siyu, Xia, Dawei, Xu, Xinyu, Song, Haoyang, and Qing, Yongquan
- Subjects
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STRAIN sensors , *COMPOSITE materials , *SUBSTRATES (Materials science) , *SOCIAL interaction , *OLIGOMERS , *EPOXY coatings - Abstract
Superhydrophobic strain sensors are highly promising for human motion and health monitoring in wet environments. However, the introduction of superhydrophobicity inevitably alters the mechanical and conductive properties of these sensors, affecting sensing performance and limiting behavior monitoring. Here, we developed an alkylated MXene–carbon nanotube/microfiber composite material (AMNCM) that is simultaneously flexible, superhydrophobic, and senses properties. Comprising a commercially available fabric substrate that is coated with a functional network of alkylated MXene/multi-walled carbon nanotubes and epoxy–silicone oligomers, the AMNCM offers high mechanical and chemical robustness, maintaining high conductivity and strain sensing properties. Furthermore, the AMNCM strain sensor achieves a gauge factor of up to 51.68 within a strain range of 80–100%, and exhibits rapid response times (125 ms) and long-term stability under cyclic stretching, while also displaying superior direct/indirect anti-fouling capabilities. These properties position the AMNCM as a promising candidate for next-generation wearable devices designed for advanced environmental interactions and human activity monitoring. [ABSTRACT FROM AUTHOR]
- Published
- 2024
- Full Text
- View/download PDF
43. Designing Plastrons for Underwater Bubble Capture: From Model Microstructures to Stochastic Nanostructures.
- Author
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Wong, William S. Y., Naga, Abhinav, Armstrong, Tobias, Karunakaran, Bhuvaneshwari, Poulikakos, Dimos, and Ras, Robin H. A.
- Subjects
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MANUFACTURING processes , *BUBBLE dynamics , *WASTEWATER treatment , *STOCHASTIC models , *REPELLENTS - Abstract
Bubbles and foams are often removed via chemical defoamers and/or mechanical agitation. Designing surfaces that promote chemical‐free and energy‐passive bubble capture is desirable for numerous industrial processes, including mineral flotation, wastewater treatment, and electrolysis. When immersed, super‐liquid‐repellent surfaces form plastrons, which are textured solid topographies with interconnected gas domains. Plastrons exhibit the remarkable ability of capturing bubbles through coalescence. However, the two‐step mechanics of plastron‐induced bubble coalescence, namely, rupture (initiation and location) and subsequent absorption (propagation and drainage) are not well understood. Here, the influence of 1) topographical feature size and 2) gas fraction on bubble capture dynamics is investigated. Smaller feature sizes accelerate rupture while larger gas fractions markedly improve absorption. Rupture is initiated solely on solid domains and is more probable near the edges of solid features. Yet, rupture time becomes longer as solid fraction increases. This counterintuitive behavior represents unexpected complexities. Upon rupture, the bubble's moving liquid‐solid contact line influences its absorption rate and equilibrium state. These findings show the importance of rationally minimizing surface feature sizes and contact line interactions for rapid bubble rupture and absorption. This work provides key design principles for plastron‐induced bubble coalescence, inspiring future development of industrially‐relevant surfaces for underwater bubble capture. [ABSTRACT FROM AUTHOR]
- Published
- 2024
- Full Text
- View/download PDF
44. Superhydrophobicity, Photocatalytic Self-Cleaning and Biocidal Activity Combined in a Siloxane-ZnO Composite for the Protection of Limestone.
- Author
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Manoudis, Panagiotis N., Zuburtikudis, Ioannis, Konstantopoulos, Georgios, Khalifeh, Hadil Abu, Kottaridi, Christine, and Karapanagiotis, Ioannis
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STONE , *COMPOSITE coating , *CONTACT angle , *ESCHERICHIA coli , *CHEMICAL stability - Abstract
The erosion phenomena of the natural stone in cultural heritage are induced by various sources. Consequently, the development of multifunctional protective materials that combine two or more useful properties is an effective strategy in addressing the synergistic effects of various erosion mechanisms. A multifunctional coating, consisting of a silane-based precursor and zinc oxide (ZnO) nanoparticles (NPs), is produced and tested for the protection of limestone. The hybrid coating combines the following three properties: superhydrophobicity, including water-repellency, photocatalytic self-cleaning and biocidal activity. The relative concentration of the NPs (0.8% w/w), used for the suggested composite coating, is carefully selected according to wetting studies, colourimetric measurements and durability (tape peeling) tests. The non-wetting state is evidenced on the surface of the composite coating by the large contact angle of water drops (≈153°) and the small contact angle hysteresis (≈5°), which gives rise to a physical self-cleaning scenario (lotus effect). The photocatalytic chemical self-cleaning is shown with the removal of methylene blue, induced by UV-A radiation. Moreover, it is shown that the suggested coating hinders the incubation of E. coli and S. aureus, as the inhibitions are 94.8 and 99.9%, respectively. Finally, preliminary studies reveal the chemical stability of the suggested coating. [ABSTRACT FROM AUTHOR]
- Published
- 2024
- Full Text
- View/download PDF
45. Preparation of Aluminum-Based Superhydrophobic Surfaces for Fog Collection by Bioinspired Sarracenia Microstructures.
- Author
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Guo, Yunjie, Li, Jie, Ma, Lisheng, Shi, Wentian, Wang, Yuke, Fu, Shuo, and Lu, Yanning
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SUPERHYDROPHOBIC surfaces , *CHOICE of transportation , *FRESH water , *CONDENSATION , *LASERS - Abstract
Freshwater shortage is a growing problem. Inspired by the Sarracenia trichome fog-trapping and ultrafast water-transport structure, a series of hierarchical textured surfaces with high-low ribs with different wettabilities was prepared based on laser processing combined with dip modification. Through fog-collection performance tests, it was found that the samples with superhydrophobicity and low adhesion had the best fog-collection effect. In addition, it was observed that the fog-collection process of different microstructured samples was significantly different, and it was analysed that the fog-collection process was composed of two aspects: directional condensation and directional transport of droplets, which were affected by the low ribs number and rib height ratio. A design parameter was given to create the Sarracenia trichome-like structure to achieve a fast water transport mode. This study provides a good reference for the development and preparation of fog-collection surfaces. [ABSTRACT FROM AUTHOR]
- Published
- 2024
- Full Text
- View/download PDF
46. Preparation and properties of superhydrophobic fluorinated polyurethane with room temperature self-healing performance.
- Author
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Wang, Luyao, Ye, Li, Zhang, Xiaoyu, Li, Ning, and Li, Jiwei
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CONTACT angle , *HYDROGEN bonding , *THERMAL stability , *POLYURETHANE elastomers , *MEDICAL equipment , *ISOPHORONE - Abstract
This study synthesized a series of linear polyurethane elastomers (FTPU) with hydrophobicity and self-healing properties by adjusting the content of Polytetrahydrofuran (PTMEG) and fluorinated polyol (F-OH) as soft chain segments, isophorone diisocyanate (IPDI) and disulfide as hard chain segments. FT-IR, XPS, OM, 3D optical surface profilometer, contact angle tester, SEM, TG, and solvent resistance test were used to characterize its structure and study its self-healing, hydrophobicity, heat resistance, solvent resistance, etc. The results showed that with the increase of F-OH addition, the repair time was shortened and the repair effect was enhanced under the synergistic effect of disulfide bonds and fluorine hydrogen bonds. When the content of F-OH is 50 wt%, the self-healing efficiency is the highest, reaching 94.7%. FTPU can complete self-healing at room temperature (23 ± 2 °C) for 10 h, and self-healing can be completed within 6 min at 100 °C. Second, the introduction of F-OH significantly increased the F content on the surface of FTPU, and the water contact angle of FTPU gradually increased from 70° to 105.5°. More importantly, when FTPU was applied to fabrics, superhydrophobic fabrics with a contact angle of up to 154° were obtained. In addition, FTPU also exhibits excellent thermal stability and solvent resistance, with the T5% of FTPU-3 reaching 331 °C. FTPU has excellent comprehensive performance and can be widely used in various fields such as medical devices, electronic skin, flexible devices, etc. [ABSTRACT FROM AUTHOR]
- Published
- 2024
- Full Text
- View/download PDF
47. Estimation of the Structure of Hydrophobic Surfaces Using the Cassie–Baxter Equation.
- Author
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Myronyuk, Oleksiy, Vanagas, Egidijus, Rodin, Aleksej M., and Wesolowski, Miroslaw
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SURFACE texture , *ATOMIC force microscopy , *HYDROPHOBIC surfaces , *CONTACT angle , *SURFACE structure - Abstract
The effect of extreme water repellency, called the lotus effect, is caused by the formation of a Cassie–Baxter state in which only a small portion of the wetting liquid droplet is in contact with the surface. The rest of the bottom of the droplet is in contact with air pockets. Instrumental methods are often used to determine the textural features that cause this effect—scanning electron and atomic force microscopies, profilometry, etc. However, this result provides only an accurate texture model, not the actual information about the part of the surface that is wetted by the liquid. Here, we show a practical method for estimating the surface fraction of texture that has contact with liquid in a Cassie–Baxter wetting state. The method is performed using a set of ethanol–water mixtures to determine the contact angle of the textured and chemically equivalent flat surfaces of AlSI 304 steel, 7500 aluminum, and siloxane elastomer. We showed that the system of Cassie–Baxter equations can be solved graphically by the wetting diagrams introduced in this paper, returning a value for the texture surface fraction in contact with a liquid. We anticipate that the demonstrated method will be useful for a direct evaluation of the ability of textures to repel liquids, particularly superhydrophobic and superoleophobic materials, slippery liquid-infused porous surfaces, etc. [ABSTRACT FROM AUTHOR]
- Published
- 2024
- Full Text
- View/download PDF
48. Crack-Based Composite Flexible Sensor with Superhydrophobicity to Detect Strain and Vibration.
- Author
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Zhang, Yazhou, Wu, Huansheng, Liu, Linpeng, Yang, Yang, Zhang, Changchao, and Duan, Ji'an
- Subjects
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CONDUCTIVE ink , *ENGINEERING equipment , *VIBRATION (Mechanics) , *CONTACT angle , *WRITING processes , *FEMTOSECOND lasers - Abstract
Vibration sensors are widely applied in the detection of faults and analysis of operational states in engineering machinery and equipment. However, commercial vibration sensors with a feature of high hardness hinder their usage in some practical applications where the measured objects have irregular surfaces that are difficult to install. Moreover, as the operating environments of machinery become increasingly complex, there is a growing demand for sensors capable of working in wet and humid conditions. Here, we present a flexible, superhydrophobic vibration sensor with parallel microcracks. The sensor is fabricated using a femtosecond laser direct writing ablation strategy to create the parallel cracks on a PDMS film, followed by spray-coating with a conductive ink composed of MWCNTs, CB, and PDMS. The results demonstrate that the developed flexible sensor exhibits a high-frequency response of up to 2000 Hz, a high acceleration response of up to 100 m/s2, a water contact angle as high as 159.61°, and a linearity of 0.9812 between the voltage signal and acceleration. The results indicate that the sensor can be employed for underwater vibration, sound recognition, and vibration monitoring in fields such as shield cutters, holding significant potential for mechanical equipment vibration monitoring and speech-based human–machine interaction. [ABSTRACT FROM AUTHOR]
- Published
- 2024
- Full Text
- View/download PDF
49. Study on superhydrophobicity and excellent corrosion resistance of a novel Ni‐SiC nanocomposite coating.
- Author
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Liu, Jianguo, Bai, Yujie, Xing, Xiao, and Cui, Gan
- Subjects
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CARBON steel , *COMPOSITE coating , *STEELWORK , *SURFACE resistance , *CORROSION resistance , *OIL spill cleanup , *SUPERHYDROPHOBIC surfaces - Abstract
Carbon steel is widely used, but it is prone to corrosion, which can lead to safety accidents. In this study, a novel Ni‐SiC coating was synthesized on the surface of carbon steel using a one‐step electrodeposition method, and the influence of electrodeposition parameters on the wettability of the coating was investigated. This coating possesses abundant micro‐nanostructures on its surface, which, after being placed in a vacuum drying environment for 2 weeks, endows it with superhydrophobic characteristics. Due to its superhydrophobic properties and the rich micro‐nanostructures, the corrosion current density of this coating is 1/18.95 that of bare steel. After immersion in a corrosive medium for some time, the polarization resistance value of the coated sample was observed to be 13.05 times greater than that of bare steel, demonstrating its remarkable ability to enhance the corrosion resistance of the surface. The results of this study can provide a reference for the anticorrosion work on carbon steel. [ABSTRACT FROM AUTHOR]
- Published
- 2024
- Full Text
- View/download PDF
50. Fabrication of superhydrophobic (CuO-SiO2) nanocomposite coating for oil/water separation.
- Author
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Majeed, Ali N., Sabry, Raad S., and Abid, Muslim A.
- Subjects
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FIELD emission electron microscopy , *CONTACT angle , *INDUSTRIAL wastes , *SILICONE rubber , *DIESEL fuels - Abstract
The presence of oil-contaminated water due to oil spill disasters or improper industrial waste dumping is now a worldwide danger to both human health and the sustainability of the environment.The use of superhydrophobic materials has attracted considerable attention in the field of oil-water separation, owing to the increasing demand for effective and economical oil-water separation techniques.A new, easy, and inexpensive flame treatment method was used to make a nanocomposite (CuO-SiO2) in order to improve its hierarchical structure (micro-nano).The anodisation process produced copper oxide (CuO) nanostructures (NSs) on a copper mesh. Subsequently, the nanostructures were modified by dip coating with a solution of room-temperature vulcanised silicone rubber (RTV-SR).The coated mesh demonstrated remarkable characteristics of superhydrophobicity and superoleophilicity, with a water contact angle (WCA) of (160 ± 1°) and an oil contact angle (OCA) of (0°), as determined during the measurement of the surface's wetability. The coated mesh surface was characterised using X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM), and energy dispersive spectroscopy (EDS).The successful separation of kerosene-water and diesel oil-water mixtures is accomplished by using a coated mesh in a simple filtration procedure. Furthermore, it has the capability to separate oils with a high efficiency of (99.8%) for kerosene and (87%) for diesel oil. It also has flux values of (7352.9 L.m-2.h-1) for kerosene and (6112.9 L/m2.h) for diesel. [ABSTRACT FROM AUTHOR]
- Published
- 2024
- Full Text
- View/download PDF
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