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As a result of their pleasant odor qualities and low odor thresholds, iso- and anteiso-fatty aldehydes represent promising candidates for applications in flavoring preparations. A novel cyanobacter...

Lipid extracts of the fungus Flammulina velutipes were found to contain various scarce fatty acids including dodec-11-enoic acid and di- and tri-unsaturated C16 isomers. A biotechnological approach using a heterologously expressed carboxylic acid reductase was developed to transform the fatty acids into the respective aldehydes, yielding inter alia dodec-11-enal. Supplementation studies gave insights into the fungal biosynthesis of this rarely occurring acid and suggested a terminal desaturation of lauric acid being responsible for its formation. A systematic structure-odor relationship assessment of terminally unsaturated aldehydes (C7-C13) revealed odor thresholds in the range of 0.24-22 μg/L in aqueous solution and 0.039-29 ng/L in air. In both cases, non-8-enal was identified as the most potent compound. All aldehydes exhibited green odor qualities. Short-chained substances were additionally associated with grassy, melon-, and cucumber-like notes, while longer-chained homologs smelled soapy and coriander leaf-like with partly herbaceous nuances. Dodec-11-enal turned out to be of highly pleasant scent without off-notes.

As a result of their pleasant odor qualities and low odor thresholds, iso- and anteiso-fatty aldehydes represent promising candidates for applications in flavoring preparations. A novel cyanobacterial α-dioxygenase from

Originating from the seedpods of orchids, Vanilla belongs to the most widely appreciated flavours worldwide. Besides the seedpods (beans) also Vanilla extracts and isolated vanillin as the major characteristic aroma compound are commercially used. Different consumer demands and national regulations require appropriate quality control of products arising from the Vanilla plants. Depending on the kind of product and its position in the supply or value chain, different methods for quality control and authentication have to be applied. When examining plant material for instance DNA barcoding can be used, whereas for Vanilla extracts and vanillin analytical quality control is frequently employed. As one of the first chemically synthesized flavouring substances with its first production in the late 19th century vanillin is nowadays manufactured via multiple different chemical and natural routes. To discriminate commercial vanillin qualities by their precursors with respect to the chemical and natural origin stable isotope ratio mass spectrometry (sIRMS) and 1H nuclear resonance spectroscopy (NMR) are the most recognized techniques. This article describes new features to discriminate vanillin from different origins using the δ13C and δ2H ratios of the methoxy group after derivatization with hydriodic acid and subsequent measurement of the released gaseous methyl iodide (CH3I) with sIRMS. The combination of available analytical data by means of multiparametric statistical tools allows for the clear segregation of critical provenience clusters for vanillin, such as (natural) eugenol-derived qualities from (synthetic) lignin- or curcumin-based products. The approach supports quality and authenticity control for Vanilla-based products, aiding in meeting customer expectations in this demanding market segment.

The market penetration surveys have provided important insights into the state-of play concerning vehicle-safety systems in Germany. The surveys have confirmed that some building blocks are widely penetrated or almost ubiquitous in the vehicle fleet (e.g. airbags, ESC), whereas advanced systems (e.g. emergency braking) are at the beginning of penetrating the fleet. The combination of system equipment and socio-demographic/geographic indicators has revealed that the presence of systems on the road (fleet km) is higher than the equipment suggests, because there is already a rational incentive that large equipment is most beneficial for vehicles with high annual mileage. Taken together in a temporal perspective, the surveys point at the growing intelligence of and in the vehicles. One can also recognise the penetration pattern following the innovation cascade where new systems are introduced as options in upper class segments, usually bundled in packages. Over time, innovation seeps through to the volume segments [18]. Vehicle-safety systems are experience goods. Acknowledging that some of the vehicle -safety systems can be interpreted as automation Level 1 s or 2 systems, users can collect valuable experience on how to drive assisted by such systems.

Automated driving will provide many kinds of benefits - some direct and some indirect. The benefits originate at the individual level, from changes in the behaviour of drivers and travellers with regard to driving and mobility, ending up with benefits at the social level via changes in the whole transport system and society, where many of the current planning and operations paradigms are likely to be transformed by automated driving. There may also be disbenefits, particularly at a social level, for example in intensity of travel which could result in additional congestion and increased use of natural resources. There may also be unintended consequences. For example, we do not know the impacts on public transport: driverless vehicles could provide a means to a lower cost service provision, but the availability of automated cars could lead to more car travel at the expense of collective transport.