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A char cone, whose shape is similar to Bunsen flame and varies with oxidation conditions, was found in steady smoldering of biomass rods. In this short communication, characteristics of this char cone in natural downward smoldering of char rods with different diameters (2 – 7 mm) and ash contents (30–46%) were investigated via measuring propagation velocity and analyzing shape of char cone. Results showed that smoldering propagates steadily in all prepared char rods and the propagation velocity decreases with increasing diameter and ash content of char rods. Height of char cone is proportional to the mass flowrate of carbon, similar to the relationship between flame length and volume flowrate of gas fuel in laminar jet diffusion flame. It implies that oxygen diffusion through ash plays a dominant role in natural smoldering of char rod. This work provides some experimental basis for further investigation on mechanism of steady smoldering. [ABSTRACT FROM AUTHOR]

In order to assess the possibility of silica production via smoldering of moist rice husk, experiments of washed (moist) rice husk (7 kg with moisture content of 51%) in a newly designed smoldering apparatus was performed. The temperature inside the fuel bed during smoldering was recorded, and characteristics of ash were analyzed. Results showed that the highest temperature in the middle of the naturally piled fuel bed was about 560.0 °C, lower than those in most of combustors. Some volatiles from the lower part of the fuel bed adhere to its upper ash during piled smoldering. Silica content and specific surface area of ash from smoldering of washed (moist) rice husk were 86.4% and 84.9 m2/g, respectively. Compared to our experiments, they are close to smoldering of unwashed rice husk (89.0%, 67.7 m2/g); different from muffle furnace burning (600 °C, 2 h) of washed (93.4%, 164.9 m2/g) and un-washed (90.2%, 45.7 m2/g) rice husk. The specific surface area is higher than those from most industrial methods (from 11.4 to 39.3 m2/g). After some improvements, the smoldering process has great potential in mass product of high quality silica directly from moist rice husk. [ABSTRACT FROM AUTHOR]