1. Synthesis and characterization of new multinary selenides Sn4In5Sb9Se25 and Sn6.13Pb1.87In5.00Sb10.12Bi2.88Se35.
- Author
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Chen, Guan-Ruei, Wang, Ming-Fang, and Lee, Chi-Shen
- Subjects
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SELENIDES , *ELECTRICAL conductivity measurement , *ELECTRONIC band structure , *SEEBECK coefficient , *P-type semiconductors , *DENSITY functional theory - Abstract
Multinary selenides, Sn 4 In 5 Sb 9 Se 25 (1) and Sn 6.13 Pb 1.87 In 5.00 Sb 10.12 Bi 2.88 Se 35 (2) were synthesized by solid-state sintering reactions. These compounds were initially observed resulting from the exploratory synthesis of multinary selenides in In–Sn–Sb–Se systems. Sn 4 In 5 Sb 9 Se 25 crystallizes in a monoclinic lattice with a = 31.820(2) Å, b = 4.0241(3) Å, c = 19.703(2) Å, β = 114.246(5)°, and V = 2300.4(3) Å3; space group C2/m (No. 12); Z = 2. Sn 6.13 Pb 1.87 In 5.00 Sb 10.12 Bi 2.88 Se 35 crystallizes in a monoclinic lattice with a = 31.6883(5) Å, b = 4.0709(1) Å, c = 26.5406(4) Å, β = 105.710(1)°, and V = 3295.8(2) Å3; C2/m (No. 12); Z = 2. The structures of both compounds are constructed with two building units of NaCl100-type [ M 2 x − 4 2 + M 4 3 + Se 2 x + 2 ] ∞ 1 and NaCl111-type [ M 2 y − 2 3 + Se 3 y − 3 ] ∞ 2. The structural anisotropy leads to a columnar or layered shape and strongly preferred orientation along [010] direction upon two compounds. These materials exhibit black color comprising a semiconducting property. Band gaps observed in electrical conductivity measurements are 0.66 eV and 0.62 eV for compound 1 and 2 , respectively. UV–vis–NIR spectroscopy and the electronic band structure calculations at the density functional theory (DFT) level indicate the results of the semiconducting behaviors. Measurements of Seebeck coefficient indicates p-type semiconductors for both compounds. New multinary chalcogenides: Sn 4 In 5 Sb 9 Se 25 and Sn 6.13 Pb 1.87 In 5.00 Sb 10.12 Bi 2.88 Se 35 , with complex crystal structures have been successfully synthesized via a combination of single-crystal X-ray diffraction and tuning chemical composition. Their physical properties are reported herein. Both materials consist of similar units and imply a new homologous series. [Display omitted] • New multinary chalcogenides: Sn 4 In 5 Sb 9 Se 25 and Sn 6.13 Pb 1.87 In 5.00 Sb 10.12 Bi 2.88 Se 35 have been successfully synthesized. • Both materials contain similar building units with different sizes. • Electronic band structure calculations are studied and indicate semiconducting behaviors for both compounds. [ABSTRACT FROM AUTHOR]
- Published
- 2022
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