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• Optimization model for the integrated assessment of the green ammonia value chain. • Case study for ammonia trade between Australia and Germany in 2030. • Sensitivity analysis on ammonia prices for technical and economic parameters. • Cost comparison of conventional and green ammonia production. This paper contributes to understanding the transformation of global energy trade to green energy carriers, focusing on green ammonia as the foreseeable first green hydrogen carrier. We provide a comprehensive overview of today's ammonia trade and assess scaling options for the trade of green ammonia. To that aim, we develop an optimization model for the integrated assessment of the green ammonia value chain that covers all steps from green ammonia production in an exporting country, up to delivery to a harbor in an importing country. The model endogenously chooses among different technology options and determines cost minimal operation. In a case study, we apply the model to the large-scale import of ammonia from Australia to Germany in a scenario for 2030. The results show that green ammonia can reach cost parity with gray ammonia even for moderate gas prices (but not necessarily with blue ammonia) if CO 2 prices are high enough. We also provide a sensitivity analysis with respect to the interest rate and other key technical and economic parameters and show that cracking ammonia to provide pure hydrogen comes at a 45 % cost markup per MWh at the destination. [ABSTRACT FROM AUTHOR]

This study considers the emissions implications of co-combusting imported ammonia in coal-fired power stations. The study adopts a supply chain approach, estimating the emissions reduction potential of 20% ammonia co-combustion in coal-fired power stations in the country of use, and the emissions associated with ammonia production in the country of origin. The paper considers the emissions implications of using different ammonia production technologies: Haber-Bosch (HB) ammonia production with hydrogen generated from steam methane reforming using natural gas (SMR), with and without carbon capture and storage (CCS); Haber-Bosch ammonia production with hydrogen generated from renewable sources; and fully renewable electricity generated ammonia. The empirical setting of the study is an ammonia supply chain encompassing Japan and Australia. The results show co-combustion of ammonia produced with SMR-HB provides no net benefit for the combined country emissions, as ammonia production related greenhouse emissions in Australia are equivalent to the emission reductions in Japan. In contrast, co-firing ammonia produced from fully renewable sources reduces emissions in the two countries in 2030 by 43 MT per annum. SMR-HB processes with varying levels of CCS reduce annual emissions by 16–34 MT. Based on the results, different policy options are suggested for managing the emissions associated with a Japan-Australia ammonia supply chain. • Japan actively pursuing ammonia/coal co-combustion to reduce power sector greenhouse gas emissions. • An Australia-Japan ammonia supply is examined at a country boundary emissions basis. • Choice of ammonia manufacturing approach has significant impact on emissions. • 40 MT pa saving in Japan offset by 39 ± 11 MT pa increase in Australia from Best Available Technology. • Only a fully renewable ammonia manufacturing process reduces emissions in both Australia and Japan. [ABSTRACT FROM AUTHOR]