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Urbanization and the release of carbon emission are two significant features of contemporary economic and social progress in China. However, there are few studies that consider how urbanization policy goals affect carbon emission. This paper aims to study the nonlinear effects of urbanization policy goals on carbon emission in 13 cities of the Beijing-Tianjin-Hebei region. In this paper, a multi-dimensional spatial disturbance grey model is proposed. Based on matrix perturbation theory, this paper explores the spatial perturbation bounds of the novel model and verifies that the spatial property of the model is consistent with the viewpoint of the First Law of Geography. Then, the novel model is used to predict the urban carbon emission under different urbanization policy goal scenarios. The results showed that the novel model has spatial regional correlation in spatial region prediction. With the development of urbanization level, carbon emissions show a downward trend in more than 50% of cities from 2022 to 2025. In addition, the improvement of urbanization policy goals will promote the carbon peak time of most cities. The carbon emission intensity will exhibit an inverted U-shaped trend distribution in space. The research results are conducive to providing scientific guidance for the formulation of new-type urbanization policies and helping to achieve the dual carbon goals. • A multi-dimensional spatial disturbance grey model is proposed. • The novel grey model is consistent with the viewpoint of the First Law of Geography. • The spatial distribution of carbon intensity showed an inverted U-shaped pattern. [ABSTRACT FROM AUTHOR]

Green finance is a financial innovation that directs capital allocation towards green industries. How will this affect regional carbon emissions? Based on the data on green finance and carbon emissions of 30 provinces in China from 2008 to 2019, this paper employs a multivariate linear regression model and a spatial econometric model to empirically study the impact of green finance on carbon emissions. The results find that (1) green finance significantly reduces provincial carbon emissions, specifically through promoting a cleaner energy structure and an advanced industrial structure, as well as improving the quality of green innovation. (2) Heterogeneity exists between regions. In eastern regions and areas characterized by high levels of marketization and minimal fiscal pressure, the role of green finance in promoting provincial carbon emission reduction is more pronounced. (3) Spatial econometric analysis found that green finance has a significant spatial spillover effect on carbon reduction in adjacent regions. Specifically, the flow of green resources and green ideas between provinces facilitates the formation of regional radiation, while green competition generates a siphon effect on neighboring regions. These findings provide some meaningful policy implications to achieve China's dual-carbon goal by promoting green finance. • Green finance has significantly reduced China's provincial carbon emissions. • The upgrading of energy structure and industrial structure is a positive channel to reduce carbon emissions. • Green innovation strengthens the carbon reduction effect of green finance, but reveals the potential "greenwashing". • Green finance has a significant spatial spillover effect on carbon reduction in adjacent regions. • Policymakers should develop flexible, dynamic and coordinated green finance development policies. [ABSTRACT FROM AUTHOR]

[Display omitted] • The bitumen in wall rocks and the Danzhai paleo-oil reservoir both originate from the Lower Cambrian source rock. • The paleo-oil reservoir and the ore sulfur both derive from seawater sulfate in the strata. The metallogenic metals are mainly sourced from the underlying strata and basement. • Bitumen Re-Os and sphalerite Rb-Sr isotopes yield isochron ages of 424±160 Ma and 398±4.7 Ma, respectively. • Hydrocarbons supply a large amount of reduced sulfur for mineralization through TSR reaction. The Niujiaotang MVT Pb-Zn ore field is located at the southwestern end of the West Hunan-East Guizhou (WHEG) metallogenic belt, which overlaps spatially with the Majiang paleo-oil reservoir. The Pb-Zn mineralization is closely associated with oil-gas accumulation processes. However, the genetic link between the paleo-oil reservoir and the Pb-Zn deposits remains unclear. In this paper, we present new findings of bitumen (paleo-oil reservoir) and its features in the deposits, and apply various isotopic geochemical methods and 2D seismic data to elucidate the source rock and coupling relationship of the paleo-oil reservoir and the Pb-Zn deposits. This study reveals that the ore has a simple mineral composition, mainly comprising sphalerite, pyrite, and dolomite. Solid bitumen occurs widely in the ore and the host dolostone, and coexists with minerals from the mineralization stage. Laser Raman spectroscopy shows that the bitumen in the wall rocks of the Chengong deposit and the Danzhai paleo-oil reservoir are both overmature, and their carbon isotope compositions (δ13C PDB = –29.17 ‰ – –31.20 ‰, average –30.10 ‰, n = 6) and initial 187Os/188Os ratio (1.08±0.19) suggest that they have the Lower Cambrian source rock similar to the Majiang paleo-oil reservoir. The δ34S value of pyrite in the bitumen from the wall rocks in the Chengong deposit ranges from +28.15 ‰ to +44.12 ‰ (average +33.28 ‰, n = 18), which is consistent with the sulfur isotope composition of the ore sulfide reported previously, indicating that they both derived from sulfate in the Middle-Upper Cambrian strata. Bitumen Re-Os and sphalerite Rb-Sr isotopic dating indicate that oil reservoir accumulation in the ore-hosting strata preceded Pb-Zn mineralization, occurring at 424±160 Ma (MSWD = 1.3) and 398±4.7 Ma (MSWD = 0.66), respectively. The initial 87Sr/86Sr ratio of sphalerite is 0.709983±0.000027, which, after comparison and in combination with previous studies, suggests that the metallogenic metals mainly originated from the underlying strata and basement. 2D seismic data show that the Zaolou fault (F 2) that controls the mineralization is a deep fault that extends to the basin basement, and acts as a migration pathway for hydrocarbon fluids and ore-forming materials. We propose that liquid hydrocarbons played a significant role in Pb-Zn mineralization, acting as reductants to reduce sulfate through the thermochemical sulfate reduction (TSR) reaction and provide abundant reduced sulfur (H2S/HS−) for Pb-Zn mineralization. Finally, we present a comprehensive model of hydrocarbon accumulation and mineralization in the Niujiaotang ore field. [ABSTRACT FROM AUTHOR]

Under the background that China will achieve the goal of carbon neutrality by 2060, analyzing the impact of carbon neutral target constraints on the welfare of urban and rural residents is an important part of the design of a carbon emission reduction policy mechanism, in this paper, the dynamic recursive CGE(Computable general equilibrium) model is used to simulate the changes in welfare level, income consumption, and CO2 emissions of residents and their urban-rural heterogeneity under the policy of imposing a carbon tax on the fossil energy industry from 2022 to 2060. The results show that: compared with the BAU scenario, by 2060, first the income and consumption of residents will decrease slightly. Second, the target constraint of carbon neutrality makes the equivalent variation and compensate variation of urban and rural residents' welfare decrease slightly, and the equivalent variation and compensate variation of urban residents decrease more than those of rural residents. The following conclusions are drawn: first, the carbon-neutral target constraint makes the welfare of urban and rural residents decline slightly, but it will not have a strong impact on residents' income and consumption. Second, this constraint has a greater impact on the income, consumption and savings of urban residents than those of rural residents. [Display omitted] • A five-layer nested dynamic recursive CGE model is established to analyze residents' welfare. • Carbon taxes are incorporated into production decisions as a policy cost for energy companies. • The heterogeneity of the impact of carbon tax policy constraints on the welfare of urban and rural residents was analyzed. • The government needs to improve the intensive and diversified energy supply in rural areas to reduce the urban-rural gap. [ABSTRACT FROM AUTHOR]

[Display omitted] • The Paleoproterozoic Jingshan Group marble displays a pronounced positive δ13C V-PDB. • The positive excursion appears to have been a response to the Lomagundi-Jatuli event. • The carbon isotope anomaly appears most pronounced in shallow marine deposits. • BIF and graphite deposits formed coeval with increasing atmospheric oxygen levels. The North China Craton, one of the oldest continental blocks in the world, comprises Paleoproterozoic metamorphic sedimentary formations that record the effects of multiple major events in early Earth history, including the Great Oxidation Event (GOE) and its consequent Lomagundi-Jatuli carbon isotope event (LJE). The lack of focused research on the geological record of LJE-equivalent rocks of the Jiaodong Peninsula, Shandong Province, eastern China, has hindered our understanding of the Precambrian atmospheric oxygen evolution recorded by rocks of the North China Craton. This paper considers carbon and oxygen isotope and trace element geochemical data recovered from marble deposits of the Paleoproterozoic Jingshan Group (2.20–1.90 Ga) of the Jiaolai Basin. The investigated strata display a pronounced positive δ13C V-PDB excursion greater than 4.2 ‰. δ13C V-PDB and δ18O V-SMOW values range from −3.7 ‰ to 5.4 ‰ and 4.5 ‰ to 18.7 ‰, respectively. Positive co-variance of carbon and oxygen isotope values of the analyzed Jingshan Group samples is interpreted to reflect the effects of metamorphism and water–rock reactions. Marble deposits of the Jingshan Group experienced recrystallization, metamorphism, and silicification resulting in strong decarbonation. High amphibolite facies metamorphism may have reduced δ13C V-PDB by 3 ‰ to 5 ‰. Thus, estimated original sedimentary δ13C V-PDB values of as great as +8.4 ‰ suggest the existence of a strong positive anomaly that may reflect the global Lomagundi-Jatuli event. Rare earth and other trace element geochemical results of the present study suggest that banded iron formation (BIF) deposits associated with the Jingshan Group marble formed in a redox stratified ocean in the Jiaolai Basin dominated by ferruginous conditions. Moreover, our results suggest that positive carbon isotope anomaly associated with the LJE is largely constrained to sediment deposited in shallow and coastal marine environments. [ABSTRACT FROM AUTHOR]

• Regional ecological benefits of developing forest carbon sequestration projects in carbon markets are empirically investigated. • The pilot policy of China's one regional offset mechanism (Guangdong PHCER) is used as a quasi-natural experiment. • The carbon market can effectively increase city greening by encouraging the development of forest carbon sequestration projects. • This effect does not crowd out arable resources.Thank you very much. This paper investigates the regional spillover effects of the project-based voluntary market under the carbon emissions trading scheme (ETS). By exploiting one local offset mechanism (China's PHCER) as a quasi-experiment, we detect the unintended causal effect of the carbon market on greening the city. Using the difference-in-differences (DiD) estimator, we find that the voluntary carbon market resulted in a 14.45% (14.34%) increase in city-year-level NDVI summary value (per capita). The primary mechanism is the expansion of forest carbon sequestration projects. Cities with lower carbon emissions and fewer carbon market participants experience a greater causal effect. More importantly, we find no evidence to support the crowding out of arable land by forest carbon sequestration projects. Finally, several policy implications for a more functional carbon market are discussed. [Display omitted] [ABSTRACT FROM AUTHOR]

Under the influence of glacial-interglacial climate change and regional tectonic activities in the Quaternary, the sedimentary environments of the Bohai Sea changed greatly, providing significant information on transgression-regression events, East Asian monsoon changes and regional tectonic activities. This study analyzed the sedimentological characteristics of the BH1302 core (water depth of 12.3 m, length of 70.2 m) in the southern Bohai Sea based on grain size, foraminiferal assemblages, carbon and oxygen isotopes in foraminiferal shells and element geochemistry, and established a chronological framework based on AMS 14C, optically stimulated luminescence dating and Oxcal age-depth model using Bayesian modeling. The results showed that three interglacial transgressions and one interstadial transgression were revealed in BH1302 since the late Quaternary, corresponding to marine isotope stages (MIS) 7, 5, 3 and 1, and three subinterglacial transgressions were further identified during MIS 7. The sedimentary environments of Laizhou Bay transitioned from an estuary environment dominated by rivers to a neritic environment dominated by marine conditions because of subsidence of the Miaodao uplift in late MIS 7.1. Three subinterstadial transgressions occurred in both MIS5 with two subinterstadial in MIS 3, and the highstand sea level of MIS 3 reached approximately −18 ∼ −21 m. Under the influence of sea level fluctuations and the East Asian monsoon, the sedimentary environments of MIS 1 can be divided into a low salinity tidal-flat environment (12.0–7.0 kyr BP), a low salinity neritic environment (7.0–4.5 kyr BP) and a modern neritic environment (∼4.5 kyr BP). • The isotopes in the foraminifera shells have good indications to the impact of freshwater input on the neritic environments. • Except for 4 interglacial transgressions, the paper further identifies 3 sub-interglacial transgressions in the MIS7 period. [ABSTRACT FROM AUTHOR]

The South Qinling Belt is a key area for understanding the collisional history of the South China and North China blocks during the Lopingian (late Permian) and Triassic. This paper establishes the first integrated timescale based on conodont biostratigraphy and δ13C carb records from a continuous end Permian to the end-Early Triassic succession at Yiwagou, South Qinling Platform (SQP). Ten Early Triassic conodont zones are established. They are, in ascending order, Hindeodus parvus , H. postparvus , Neospathodus dieneri , Eurygnathodus costatus and E. hamadai , Novispathodus waageni - Scythogondolella mosheri , Pachycladina - Parachirognathus assemblage, Triassospathodus hungaricus , Ns. robustispinus and T. clinatus zones. Our record of δ13C carb fluctuations shows close correspondence to known Early Triassic carbon isotope fluctuations and, in combination with the conodont data, helps achieve a high-resolution age model for the region. The use of E. costatus as a good auxiliary marker for the Induan-Olenekian boundary (IOB), within palaeolatitudes of 40°N-40°S, is supported but it can not replace the use of Nv. waageni , because the former is absent in higher-latitude and cooler regions. The conodont faunas from the Palaeo-Tethyan Yiwagou section closely resemble those from the Northern Yangtze Platform (NYP), but they differ somewhat from the contemporaneous Nanpanjiang Basin at species level. Thus, the Qinling Sea was likely well connected with the NYP in the Early Triassic, but was more isolated from the Nanpanjiang Basin. The remarkable reappearance of Hindeodus fauna around the IOB at Yiwagou implies that the shallow-water Qinling Sea was a refuge area for this genus long after its disappearance elsewhere. • Conodont biostratigraphy and δ13C carb records from end Permian to the end-Early Triassic succession at Yiwagou, South Qinling Platform. • Discussion of index conodont for the Induan-Olenekian boundary. • Comparison of the conodont faunas between the eastern Paleo-Tethyan Yiwagou, South China and the western Paleo-Tethyan Europe. • The shallow-water Qinling Sea was a refuge area for Hindeodus fauna after Griesbachian. [ABSTRACT FROM AUTHOR]

[Display omitted] • The shale gas resource potential of the Longmaxi Formation was evaluated by using mud gas isotope logging technology. • The reservoir properties of shale were evaluated based on gas isotope fractionation effects. • The shale gas in the Changning area belongs to late kerogen cracking gas. • The lower part of the Longmaxi Formation has a better shale gas exploration potential. The Longmaxi Formation in the Sichuan Basin is one of the most important shale gas producing formations in China. Previous studies of shale gas were mostly carried out on based on laboratory analyses and did not provide effective guidelines for shale gas exploration. In this paper, we present a large amount of carbon isotopic data from mud gas isotope logging and rock-cutting headspace gas in wellsites. The δ13C 1 values showed a significant decrease at the bottom of the Longmaxi Formation. The δ13C 1 and δ13C 2 values in the Changning area were observed to be heavier than those in the Weiyuan and Jiaoshiba areas. The second half of the N216H27-3 horizontal well had obvious outgassing and carbon isotope fractionation effects. This indicates that the bottom of the Longmaxi Formation has better shale gas exploration potential. The shale gas of the Longmaxi Formation in the Changning area belongs to late kerogen cracking gas, where exploration prospects are poorer than those in the Weiyuan and Jiaoshiba areas. There were more oil cracking gas resources and better reservoir conditions at the end of the N216H27-3 horizontal well; therefore, drilling should be continued at this site. [ABSTRACT FROM AUTHOR]

Molecular parameters are both facies and maturity dependent. Source and maturity assessment remains a difficult task for oils which were derived from multiple source rocks at a wide range of maturities from the early to late oil generation window. In this paper, a new approach was presented to assess oil source on the basis of molecular facies parameters under maturity constraint using crossplots of one source parameter versus one maturity parameter. Concentrations of ΣC 29 steranes and C 30 hopane were tentatively used as maturity indicators. Quantitative GC, GC-MS and GC-IRMS analyses were performed on 52 oils from the southern and central Mahu sag of northwestern Junggar Basin, NW China. The 52 oils are first classified into three groups, i.e., groups I, II and III which were derived from source beds within the Lower Permian Fengcheng Formation (P 1 f), Middle Permian Lower Wuerhe Formation (P 2 w) and both, respectively on the basis of carbon isotopes of individual n -alkanes in combination with reservoir geological settings. These three oil groups, in particular groups I and II from different sources were further distinguished sufficiently using crossplots of ratios of pristane (Pr)/ n -C 17 and phytane (Ph)/ n -C 18 , β-carotane/ n -C 21 and concentrations of n -alkanes, Pr, Ph, β-carotane, Ts, C 29 Ts, C 30 diahopane, C 20 , C 21 and C 23 tricyclic terpanes versus concentrations of ΣC 29 steranes and C 30 hopane, respectively. Variation trends of isotopic reversal index (RI) and δ13C value of n -C 25 , the lowest among those of n -alkanes (n -C 12–34), with decreasing concentrations of ΣC 29 steranes and C 30 hopane demonstrate that carbon isotopes of n -alkanes were unlikely influenced significantly by oil maturities within oil generation window. Concentration of n -alkanes increases while concentrations of Pr, Ph, crotanes, terpanes and steranes generally decrease with decreasing concentrations of ΣC 29 steranes and C 30 hopane. Application of this approach provides numerous choices and opportunities to distinguish oil groups which were derived from different sources in combination with isotopic data and reservoir geological settings. • Molecular facies parameters were used to assess oil sources under maturity constraints. • Concentrations of n -alkanes and isoprenoids can be effective source and maturity indicators. • It is viable to assess oil source using concentration crossplots of biomarkers. • δ13C of individual n -alkanes are effective source indicator for the studied oils. [ABSTRACT FROM AUTHOR]

This paper describes numerous siderite occurrences from Nb-Zr-REY-Ga-enriched beds of tuffaceous mudstone from the Yujingshan borehole, eastern Yunnan, southwestern China. The mineral phases in the samples were identified and characterized through macroscopic observation, XRD (X-ray diffraction) analysis, optical microscopy, and FE-SEM (field emission-scanning electron microscopy). The results show that the siderite occurs in the drill core from depths of 664.07 to 729.21 m, where its content varies from 15.1 to 65.7%, 31.3% on average. Modes of occurrence of authigenic siderite include irregular banded or massive aggregates, discrete fine particles, oolitic aggregates, and double or multi-ring ellipsoid-shaped or rhombohedral aggregates. The mineralogical association with quartz, anatase, ilmenite, chromite, and zircon with sharp-edged outlines, high-temperature cracks and/or corroded embayments, and REE-bearing minerals and geochemical characteristics such as Al 2 O 3 /TiO 2 between 3 and 8, less commonly 8–23.77, indicate that abundant siderite was produced by hydrothermal alteration of airborne volcaniclastic materials. The δ 13C PDB , δ 18O PDB , and δ 18O SMOW values of siderite in the argillized tuff range from −12.56 to −1.32‰, −8.98 to −5.88‰, and 21.60 to 24.80‰, respectively. In the δ 13C PDB - δ 18O SMOW diagram, plots of the studied siderite are distributed between the fields of marine carbonate rocks, sedimentary organic matter, and carbonates of hydrothermal ores. Some siderite from the upper part of the studied borehole is isotopically close to REY carbonates from the Abramovka lignite deposit, Far Eastern Russia, which precipitated from evolved basinal waters mixed with CO 2 from a mantle source. In summary, this indicates a hybrid origin for the studied siderite including carbonate dissolution, dehydroxylation of sedimentary organic matter, and hydrothermal activity. Furthermore, the paleosalinity (Z) and paleotemperature (T) of the ore-forming fluids were calculated based on the age-corrected stable carbon and oxygen isotopic data in the samples. The Z values range from 96.65 to 121.5‰, suggesting the formation of siderite under brackish-water conditions. The T values vary from 19.47 to 47.12 °C, with some sharp fluctuations that may be due to ash falls and/or hydrothermal injections. Overall, our data support the model for critical-metal Nb(Ta)-Zr(Hf)-REY-Ga enrichment in tuffaceous deposits of southwest China including a combination of volcanic activity and terrestrial organic-rich sedimentation under warm and humid conditions, followed by low-temperature alteration evolved from acidic leaching, which is responsible for the Nb-Zr-REY-Ga enrichment, and, subsequently, formation of authigenic siderite with associated quartz, sulfide minerals, and phosphate minerals under reducing neutral/weakly alkaline conditions. • Abundant siderite is documented in the clay-altered tuffaceous horizons. • Fe was primarily derived from airborne pyroclastics. • C and O were sourced from carbonate, organic matter, and hydrotherm. • C-O isotopes show that siderite was affected by seawater and hot fluids. • A genetic model of siderite in Nb-Zr-REY-Ga deposits has been proposed. [ABSTRACT FROM AUTHOR]

Multiple lines of evidence revealed that enormous CO 2 was input into the ocean-atmosphere system during Oceanic Anoxic Event 1a (OAE 1a), which led to a series of environmental perturbations (e.g. temperature rising, enhanced weathering, promoted primary productivity and marine anoxia). Among them, increased carbon isotope fractionation (Δ13C carb-org) between the carbonate (δ13C carb) and organic carbon (δ13C org) in the sediments is one of the most important indicators to the enhanced atmospheric pCO 2. However, only a few research reported high-resolution paired carbon isotopes during OAE 1a, which were almost limited around the western Tethys. Here, we report new paired carbon isotopes of the Early Cretaceous sediments from the ODP site 866A in the western Pacific and the Lingshan Island section in the Sulu orogenic belt. The δ13C carb curves from both sections correlate well with OAE 1a, in which a positive δ13C carb excursion is identified between the C3–C6 segments. The Δ13C carb-org displays a ∼7–11‰ positive shift coinciding with the δ13C carb excursion, indicating a remarkable increase and a gradual decrease in CO 2 in water and atmosphere, which further support significant atmospheric pCO 2 changes during OAE 1a on a global scale. The sediments also show a few variations in carbon isotope records during OAE 1a between different locations, which may reflect different influences from local environments, and the deviations of stratigraphic correlation and diagenesis cannot be ruled out either. • The carbon isotopes from both sections correlate well with OAE 1a. • Atmospheric pCO 2 rose in early OAE 1a and fell in late OAE 1a on a global scale. • The atmospheric pCO 2 changes show a few variations between different locations. [ABSTRACT FROM AUTHOR]