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In the social context of mitigating climate change and achieving carbon neutrality, the improvement of carbon emissions efficiency and the protection of biological carbon sequestration have emerged as hot topics recently due to their prospects in carbon dioxide emissions reductions. A large volume of studies has identified the spatial distribution characteristics and influencing factors of carbon emissions efficiency. The contributions of our study lied in constructing a system to measure net carbon sink efficiency. Secondly, this study discussed the carbon neutrality performance of Chinese cities from three different aspects of carbon dioxide emissions, carbon sequestration of vegetation and net carbon sink efficiency. Thirdly, this paper identified the influencing factors of net carbon sink efficiency, and examined the direct and indirect effect of different factors. For this purpose, we evaluated the net carbon sink efficiency of 285 cities in China from 2012 to 2017 using a slacks-based measure model, and explored its spatial distribution characteristics, then employed a spatial Durbin model to explore the influencing factors of net carbon sink efficiency. Our main findings indicate that the net carbon sink efficiency steadily increased during the study period, whereas their spatial characteristics were "high at both ends and low in the middle" from the south to the north. There is a significant spatial autocorrelation in the net carbon sink efficiency of Chinese cities. Several kinds of measures can be applied to promote net carbon sink efficiency, such as increasing the proportion of tertiary industry, promoting economic growth, attracting foreign direct investment, increasing road area, promoting technological progress and strengthening environmental regulation. However, the increase of urban population may decrease efficiency. Nevertheless, an obvious spatial spillover effect exists in the net carbon sink efficiency of Chinese cities. The results can provide policy recommendations for the government to formulate differentiated carbon neutralization policies. [Display omitted] • The carbon sequestration is considered to calculate net carbon sink efficiency (NCSE). • The NCSE is used to discuss the carbon neutral performance of Chinese cities. • Chinese NCSE steadily increased and showed significant spatial autocorrelation. • Spatial Durbin model was adopted to study the influencing factors of NCSE. [ABSTRACT FROM AUTHOR]