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Waterborne and solvent-based coatings with prominent passive subambient daytime radiative cooling (RC) coatings were fabricated to conserve cooling energy in the summer. Concurrently, water- and alcohol-based superamphiphobic self-cleaning coatings were manufactured and introduced into the RC coatings as topcoats. The contact angles of water and n -hexadecane of the superamphiphobic topcoat containing coating systems were 163.4° and 151.4°, respectively; additionally, the sliding angles of water and n -hexadecane of these systems were 2° and 9°, respectively. Moreover, the introduction of a transparent superamphiphobic topcoat to the RC coatings did not affect their originally high solar reflectance but improved their emissivity values in the atmospheric transparency window, wavelengths between 2.5 and 24 μm, and the entire infrared spectrum due to the presence of plenty of silicon-oxygen bonds formed via hydrolysis and/or alcoholysis reactions and the subsequent co-polycondensation of tetraethoxysilane and 1H,1H,2H,2H-perfluorodecyltriethoxysilane. The solar reflectance of the coating system was 0.986, which is the highest recorded worldwide. The emissivity of the superamphiphobic RC coatings in the atmospheric transparency window was 0.954. The superamphiphobic RC coatings possessed excellent static and dynamic non-wetting capabilities, significantly improving their water resistance, waterproofing properties, and anti-graffiti performance. Additionally, the superamphiphobic RC coatings exhibited outstanding self-cleaning properties, preventing the coating surfaces from being contaminated by dust, soiling, grime, and water/oil-soluble pollutants, thereby enabling them to maintain an extremely high solar reflectance. Water- and alcohol-based superamphiphobic radiative cooling coatings with solar reflectance up to 0.986 were fabricated. The emissivity in the atmospheric transparency window and thereby the overall emissivity were increased to 0.954 and 0.96, respectively, due to the introduction of transparent superamphiphobic topcoats. The contact angles of water and n -hexadecane were 163.4°and 151.4°, respectively, while the sliding angles of water and n -hexadecane were 2°and 9°, respectively. [Display omitted] •The superamphiphobic coating with subambient daytime radiative cooling was produced. •The solar reflectance of the coating was up to 0.986 •The coating's emissivity in the atmospheric transparency window was 0.954 •The coating's contact angles of water and n-hexadecane were higher than 150°. •The coating's sliding angles of water and n-hexadecane were lower than 10°. [ABSTRACT FROM AUTHOR]