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Start Over Author "Bibik, Yurii S." Topic 1,2,4-triazole Publication Year Range Last 3 years

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1 results on '"Bibik, Yurii S."'

1. Synthesis and crystal structure of hydrated μ-oxalato-bis{bis[3-methyl-5-(pyridin-2-yl)-1H-1,2,4-triazole]iron(II)} bis(toluenesulfonate) 2.75-hydrate.

Author

Petrenko, Yuliia P., Bibik, Yurii S., Khomenko, Dmytro M., Doroshchuk, Roman O., Gural'skiy, Il'ya A., Shova, Sergiu, Lampeka, Rostyslav D., and Raspertova, Ilona V.

Subjects
*CRYSTAL structure, *IRON, *OXALATES, *METAL ions, *HYDROGEN bonding, *X-ray crystallography, *CHELATING agents
Abstract

In the title compound [Fe2(C2O4)(C8H8N4)4](CH3C6H4SO3)2·2.75H2O, the two FeII ions have a highly distorted octa­hedral FeN4O2 environment formed by two bidentate triazole-based chelating ligands and a bis-bidentate oxalate bridging anion that connects the metal ions. Stabilization within the crystal structure is provided via a system of O--H⋯O and N--H⋯O hydrogen bonding, which determines the formation of a two-dimensional architecture along the a-axis direction. [ABSTRACT FROM AUTHOR]

Published
2022
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