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1. Iron‐Catalyzed Epoxidation of Linear α‐Olefins with Hydrogen Peroxide.

Author

Mao, Shuxin, Budweg, Svenja, Spannenberg, Anke, Wen, Xiaodong, Yang, Yong, Li, Yong‐Wang, Junge, Kathrin, and Beller, Matthias

Subjects
*HYDROGEN peroxide, *EPOXIDATION, *ALKENES, *PICOLINIC acid, *EPOXY compounds, *IRON
Abstract

The combination of Fe(OTf)2 with N‐methyl bis(picolylamine) (Me‐bpa) L7 enables epoxidation of linear olefins including terminal, internal, and cyclic ones, using hydrogen peroxide as terminal oxidant under mild conditions. In the presence of picolinic acid as additive improved yields of epoxides up to 75 % have been achieved. [ABSTRACT FROM AUTHOR]

Published
2022
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