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• PAH records in Liaodong Bay provides the first detailed reconstruction of industrial activities;. • PAH variations can be divided into four episodes linked to industrialization process since 1815. • Dominant PAH sources of Northeast China shift from wood to coal and petroleum over time;. • PAH fluxes could be used to track the trend for regional anthropogenic CO 2 emissions. Polycyclic aromatic hydrocarbons (PAHs) are excellent tracers for fossil fuel combustion, natural fires and petroleum contamination, and have been widely used for reconstructing past wildfires and industrial activities at a variety of time scales. Here, for the first time, we obtain a high resolution (annual to decadal scale) record of PAHs from two parallel marine sediment cores from the Liaodong Bay, Northeastern China to reconstruct the industrial activities, spanning the past ∼ 200 years from 1815 to 2014. Our data indicate that PAH variations can be divided into four episodes: I) low (probably near background) PAHs from natural fires and domestic wood combustion during the pre-industrial period from 1815 to 1890; II) slightly increased (but with large fluctuations) PAH concentrations derived from intermittent warfare during the World War (1891–1945) and increased industrial activities after 1946 (1946–1965); III) a period of stagnation and, in some cases, reduction in PAHs during the "Cultural Revolution" (1966 to 1979); and IV) a rapid and persistent rise in PAHs post 1979 linked to fast economic development, with PAH concentrations doubled from 1979 to 2014. Changes in PAH distributions demonstrate major shifts in the dominant types of fuels over time from vegetation/wood, to coal and wood, followed by coal and petroleum (including vehicle emissions) over the past 200 years. We find that PAH records also show similar trend to domestic economy and the estimated regional Anthropocene CO 2 emissions from industrial activities, suggesting sedimentary PAH fluxes could be used as an indirect and qualitative proxy to track the trend for regional anthropogenic CO 2 emissions. [Display omitted] [ABSTRACT FROM AUTHOR]