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With the rapid development of wearable electronics, a resistive sensor with high performance and multifunctional monitoring abilities turns out to be a great challenge for industrial application fields. Herein, a wearable 3D porous polyurethane (PU) sponge sensor coated with MXene and carbon nanotubes (CNTs) composites is self‐assembled through a simple ultrasonic dip‐coating process. The alternate assembly and the synergistic effect of MXene and CNTs contribute to a tough and complete 1D/2D conductive network, which significantly extends the measurement ability of the proposed MXene/CNTs@PU sensor from a wide‐compressive strain range (−80%) to a wide‐stretching strain range (60%). Moreover, benefit from this unique tough multidimensional MXene/CNTs structure, the presented sensor is endowed with excellent electrical response and stability during the long‐term reproducibility test over 5000 cycles. This study also demonstrates the versatile applications (stretching and compression) of the MXene/CNTs@PU sensor, such as detecting subtle expressions, vocal vibrations, body actions of human motions, and lighting light emitting diode lamps. Thus, this advanced sensor indicates great potential for emerging applications in human–machine interaction, healthcare, and wearable devices. [ABSTRACT FROM AUTHOR]

Pyrolytic reforming of toluene over Ni-based catalysts loaded on nano-sized and micro-sized γ-Al 2 O 3 is investigated in a fixed bed reactor under the temperature from 500 °C to 800 °C. The physicochemical properties of γ-Al 2 O 3 and Ni/Al 2 O 3 catalysts were characterized by HRTEM, XPS, XRD and H 2 -pulse chemisorption. The metal Ni loaded on micro-sized γ-Al 2 O 3 gave the steady toluene conversion of more than 80% and graphite yield of 87.3% after 1 h of reforming reaction. The rapid decrease of H 2 yield from 5.2 mmol/g-toluene to 0.4 mmol/g-toluene over Ni/nano-Al 2 O 3 was obtained during the 1 h of reforming reaction at 500 °C. The particle size of metal Ni over nano-sized and micro-sized γ-Al 2 O 3 were centered at 7.8 nm and 28.8 nm, respectively. The metastable NiC x crystallites were observed over the spent Ni/nano-Al 2 O 3 catalyst, while only metal Ni were obtained over the spent Ni/micro-Al 2 O 3 catalyst. Ni0+ particle size-dependent crystalline phase was evidenced by MD simulations, where incorporation of more carbon atoms was achieved on small Ni particles. The energy barrier for –CH 2 dehydrogenation over Ni 32 C, Ni 4 C and Ni 3 C were estimated to be 90.2, 105.1 and 116.0 kJ/mol through the DFT simulation, respectively. It can be concluded that the crystalline Ni phase was maintained over Ni/micro-Al 2 O 3 with large Ni particle size, prolonging the catalytic endurance and promoting the CNTs (Carbon Nanotubes) growth without the deposition of unexpected amorphous carbon. • The influence of γ-Al 2 O 3 on Ni/Al 2 O 3 catalytic reforming performance was investigated. • Ni0+ particle size-dependent pyrolytic reforming for co-production of H 2 and CNTs was revealed. • The carbon solubility on Ni particles with different sizes was simulated. [ABSTRACT FROM AUTHOR]