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Methyl-silica superhydrophobic coatings have the capability of providing anti-pollution flashover protection for outdoor electrical insulators. However, in practical applications, the deposition and dissolution of atmospheric pollutants on the coating generates acidic or alkaline ions and leads to chemical degradation of the coating's surface property, which in turn causes a decrease in the anti-pollution flashover performance of the coating. Currently, there is a lack of research on the hydrophobic degradation characteristics of superhydrophobic methyl-silica coatings induced by chemical corrosion. Meanwhile, it is not clear how chemical corrosion affects the anti-pollution flashover performance of methyl-silica superhydrophobic coatings. To address the above issues, the static water contact angle and sliding angle on the corroded methyl-silica superhydrophobic coatings were tested to reflect the surface hydrophobicity degradation, and the results were theoretically interpreted; the surface leakage current amplitudes of the coatings aged to different degrees were measured under dirty and wet conditions to characterize the anti-pollution flashover performance of the corroded coatings. The surface leakage current amplitudes of the aged methyl-silica superhydrophobic coating under different corrosion environment temperatures, different applied electric field strengths, and different wetting times of surface pollutants are measured to characterize the anti-pollution flashover performance of the corrosion-aged coating, and the influences of the above factors on the anti-pollution flashover performance of the methyl-silica superhydrophobic coating are analyzed. [Display omitted] [ABSTRACT FROM AUTHOR]

Using micro-nanostructure superhydrophobic coating with the unique self-cleaning phenomenon is a feasible method to further reduce the frequency of insulator pollution flashover. However, the research on the anti-pollution flashover performance of superhydrophobic coating is still insufficient. This paper analyzes the various types of forces on the polluted particles accumulated on the superhydrophobic coating surface, and calculates that the vertical force or the horizontal force on the nano-scale and micro-scale particles is positive when they are in contact with most types of droplets. After being fully wetted, these particles are easily absorbed or pulled by the droplets and leave the coating surface. So it is necessary to establish a new DC pollution flashover mechanism model of superhydrophobic coatings surface from the electric field perspective. Based on this model, the relationship between the pollution flashover voltage and the dry flashover voltage is clarified in the state of extremely small leakage current. Furthermore, the anti-pollution flashover performance experiment was carried out on superhydrophobic coating, RTV coating, and uncoated surface to test the leakage current under different conditions. The experimental results show that at any pollution degree, the leakage current of superhydrophobic coating surface always remains about 16.3μA after being completely wetted. [Display omitted] [ABSTRACT FROM AUTHOR]

Superhydrophobic (SH) and superamphiphobic (SAP) coatings have been viewed as an alternative to conventional hydrophobic room temperature vulcanizing (RTV) silicone rubber coatings in anti-pollution flashover application. However, being one of the most important properties in RTV-based anti-flashover materials and devices, the hydrophobicity transfer property was rarely documented for SH and SAP coatings, which restricts their practical applications in environments with heavy contamination. Herein, we propose for the first time a superhydrophobicity transfer effect in superwetting (SW) coatings (e.g., SAP and SH coatings) containing low-surface-energy molecules (e.g., polydimethylsiloxane (PDMS)) as a migratory reagent. When the surface is stained by artificial simulated pollutants, PDMS molecules can migrate from the coating to the contamination layer, followed by a surface modification. Through this process, the surface wettability of the contaminant layer gradually evolves from superhydrophilicity to hydrophobicity, and finally to SH state. This evolution is investigated in relation to the amount and species of migratory reagents, migration time, pollution grade, and pollutant species. The superhydrophobicity transfer effect offers the coated glass insulators an outstanding anti-pollution flashover strength. This work can provide a novel and universal protocol to realize a superhydrophobicity transfer property in SW coatings, which may stimulate further investigation and applications in not only anti-pollution flashover but also other fields such as anti-fouling and anti-icing. • Superhydrophobicity transfer effect is proposed for the first time. • Superwetting coatings with superhydrophobicity transfer property are obtained. • The mechanism behind the superhydrophobicity transfer effect is proposed. • Superhydrophobicity transfer effect improves the anti-pollution flashover strength of insulator. [ABSTRACT FROM AUTHOR]

Cleanliness and desiccative are necessary for outdoor insulation surfaces to maintain the voltage withstand capability especially in humid and polluted operation conditions. Once the voltage withstanding capability of insulation coatings is reduced by contaminant electrolyte, flashover accidents would be easier to happen, causing tremendous economy and energy losses. Superhydrophobic coatings, due to their self-cleaning property, are deemed to have great application potential in maintaining outdoor insulation performance, especially in humid and polluted environments. The water patterns on superhydrophobic coating in humid and polluted conditions are obviously different from those on traditional insulation coatings. Flashover voltage is one of the indices for quantifying insulation strength, while to date it is still unclear whether the commonly-used flashover voltage prediction models based on Obenaus's theory are still suitable to be applied in the cases with superhydrophobic surface. Here we proposed a facile and low-cost preparation method of superhydrophobic coating. By analyzing the specific surface condition under humid and polluted conditions, and considering the development of arc path, a novel theoretical model for predicting flashover voltage of superhydrophobic coatings is established from the perspective of electric field. The flashover voltage of the synthesized coating as well as Room Temperature Vulcanized (RTV) silicone rubber coating are tested and compared, for investigating the insulation strength on the synthesized superhydrophobic coating, and verifying the accuracy of the proposed prediction model. It is found the synthesized superhydrophobic coating shows self-cleaning property during the wetting and voltage applying process, the flashover voltage of superhydrophobic coating is higher than that of RTV coating, and is affected less obviously by the change in pollution degree, compared with RTV coating. The established model shows better accuracy in predicting the flashover voltage of superhydrophobic coating than the traditional one, with errors of less than 6%. Based on the proposed model, the flashover voltage of polluted superhydrophobic coating surface is positively and negatively related to the volume and the contact angle of the polluted electrolyte droplet, respectively. [Display omitted] [ABSTRACT FROM AUTHOR]

The application of the superhydrophobic coating is expected to be an effective method to further improve the pollution flashover voltage of insulators. However, so far, the relationship between electric field strength, droplet volume, and sliding angle in strong electric fields is not clear. This is not conducive to the evaluation of the practical application effect of superhydrophobic insulators. In this paper, the self-cleaning property of superhydrophobic coating and the critical motion condition of droplets in the electric field were analyzed theoretically. Then an experimental platform was set up to observe the movement of the droplet driven by the electric field, and the critical electric field strength for droplet motion was measured. Experimental and theoretical analysis results show that the critical electric field strength for positive droplet motion is less than that for the negative droplet. The droplet driven by the electric field can also remove water-insoluble pollution particles. And the maximum pollution concentration that droplets can remove by means of self-cleaning performance is calculated theoretically. The theoretical calculation method of the sliding angle of superhydrophobic coating in uniform DC electric field is obtained, which is in good agreement with the experimental results. This paper provides theoretical support for evaluating the practical performance of the superhydrophobic insulator in strong electric fields. [Display omitted] [ABSTRACT FROM AUTHOR]