1. Multi-responsive supramolecular gel based on uracil as latent fingerprints imaging material.
- Author
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Zhang, Ziqiang, Lv, Kuo, Liu, Cheng, Yue, Yuan, Yang, Xiqiao, Jin, Liuyang, Xiao, Huan, Yao, Chu, Sun, Jingbo, and Lu, Ran
- Subjects
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URACIL derivatives , *FORENSIC fingerprinting , *GELATION , *URACIL , *VAN der Waals forces , *DOUBLE bonds , *HYDROGEN bonding - Abstract
Four fluorescent low molecular weight gelators based on benzoxazole or benzothiazole functionalized pyrimidine were designed and synthesized. The ability of the target was tested, and all compounds could form stable supramolecular gels in an alcohol/water mixture and its fluorescence increased during gel formation. Photophysical spectra during gel formation, SEM, XRD, FT-IR study suggested that the self-assembly was driven by hydrogen bonding, van der Waals forces and weak π-π interaction. Interestingly, the gel collapsed after being illuminated by 365 nm UV light and 1H NMR of the gel before and after illumination proved that the [2 + 2]-cycloaddition between the double bond of pyrimidine was responsible for the light response. Furthermore, the fluorescent of xerogel film could be quenched by volatile acids while the fluorescent of the solution was enhanced after acid was added. The different phenomena were discussed. The nano-fiber assembled via gel formation could be used as fluorescent imaging material of latent fingerprints. [Display omitted] • Design and synthesis of novel uracil derivatives containing benzoxazole and benzothiazole. • Benzoxazole-modified uracil derivatives exhibit good gelation abilities and driving force of gel formation was investigated. • The gel could respond to light and acid. The response mechanism was studied. • The nano-materials assembled via gel formation could be used as fluorescent imaging material of latent fingerprints. [ABSTRACT FROM AUTHOR]
- Published
- 2023
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