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Biomass feedstocks are growing in importance due to their ability to serve as a renewable alternative to fossil fuels for large scale energy generation, with bioenergy projected to be a growing part of the UK's energy mix. Combined with technologies such as carbon capture and storage, sustainable bioenergy has the potential to produce negative emissions with including counterbalancing residual emissions. This paper presents a systematic review of the sustainability impacts of wood biomass (forestry/SRC) and Miscanthus, which are grown as energy fuels, comparing the three key indicators of sustainability: soil organic carbon sequestration rates, biodiversity, and water use efficiency (WUE). Analysis has shown significant influence from primary soil composition (p < 0.001) and previous land use (p < 0.001) on soil organic carbon sequestration rates following conversion to biomass feedstock production. Conversion from arable to forestry can have positive rates of sequestration of 1.4 ± 0.3 Mg C ha−1 year−1 on mineral soils, while similar conversions on a highly organic soils can lead to losses of −25 Mg C ha−1 year−1. This indicates a strong need for careful site selection for future forestry plantations. Miscanthus showed no preference under mineral or organic soils for carbon sequestration rate. Biodiversity at different trophic scales is impacted differently by biomass feedstock production. No significant impact on invertebrates was demonstrated between feedstocks but there is a significant difference between crops (p < 0.001) for vertebrates at higher trophic levels. A limited dataset was collected for WUE from the review, but analysis showed comparable WUE rates for Miscanthus and short rotation coppice, while forestry had significantly lower (p < 0.001) WUE. With global temperatures increasing and changes to climate, water stress is likely to increase. WUE will play an important role in the considerations dfor long term biomass feedstock planning and sourcing. [ABSTRACT FROM AUTHOR]

Iron oxide assemblages are central to many pursuits, ranging from Mars exploration to environmental remediation. Oxides and oxyhydroxides of iron both carry the special properties of color and magnetism. In this paper, we use visible-light spectroscopy and rock magnetic data collected at varying temperatures (~77–973 K) to analyze the concentrations and identities of iron oxides found in natural hematite-dominated samples that were obtained from a scientific drill core of Late Triassic red beds in the American Southwest. Our results suggest that hematite colorization of Earth materials varies from red to blue/purple as crystal size increases. Second-derivative analysis of the collected visible-light spectra allows this variation to be measured through the characteristic wavelength band position. Magnetic coercivity data indicate "hardness" differences that also may suggest smaller grain sizes are associated with redder colors. Yellowish maghemite and goethite have overlapping characteristic wavelength band positions that make it challenging to distinguish their contributions to mixed assemblages from visible-light data alone. Remanent magnetizations acquired at ~77 K and room temperature suggest the presence of hematite and a low-coercivity phase that may be maghemite and/or oxidized magnetite. However, we interpret this phase as maghemite in order to explain the changes in iron oxide concentrations indicated by visible-light intensities near ~425 nm and because the thermal demagnetization data suggest that goethite is absent from the samples. Future research that increases the resolution of hematite, maghemite, and goethite detection in experimental and natural samples will provide opportunities to refine the study of past climates and constrain soil iron availability under future changes in global moisture and temperature. Multimethod datasets improve understanding of environmental conditions that cause iron oxides assemblages to shift in phase dominance, grain size, and crystallinity. [ABSTRACT FROM AUTHOR]

There are many uncertainties in future climate, including how the Earth may react to different types of radiative forcing, such as CO2, aerosols, and even geoengineered changes in the amount of sunlight absorbed by Earth's surface. Here, we analyze model simulations where the climate system is subjected to an abrupt change of the solar constant by ±4%, and where the atmospheric CO2 concentration is abruptly changed to quadruple and half its preindustrial value. Using these experiments, we examine how clouds respond to changes in solar forcing, compared to CO2, and feedback on global surface temperature. The total cloud response can be decomposed into those responses driven by changes in global surface temperature, called the temperature mediated cloud feedbacks, and responses driven directly by the forcing that are independent of the global surface temperature. In this paper, we study the temperature mediated cloud changes to answer two primary questions: (a) How do temperature mediated cloud feedbacks differ in response to abrupt changes in CO2 and solar forcing? And (b) Are there symmetrical (equal and opposite) temperature mediated cloud feedbacks during global warming and global cooling? We find that temperature mediated cloud feedbacks are similar in response to increasing solar and increasing CO2 forcing, and we provide a short review of recent literature regarding the physical mechanisms responsible for these feedbacks. We also find that cloud responses to warming and cooling are not symmetric, due largely to non‐linearity introduced by phase changes in mid‐to‐high latitude low clouds and sea ice loss/formation. Plain Language Summary: As the global mean temperature changes, there are changes in cloud amount, location, and thickness, which can all impact the radiative balance of the Earth. Cloud changes driven directly by global temperature change are called temperature mediated cloud feedbacks. In this paper, we study the temperature mediated cloud feedbacks that occur in model simulations where the amount of sunlight incident upon the Earth is increased or decreased abruptly, and then held constant for 150 years. We compare the cloud changes in these experiments with experiments where the CO2 concentration is similarly increased or decreased abruptly and held constant for 150 years. In doing so we find that the temperature mediated cloud feedbacks following abrupt changes in solar radiation are characteristically similar to those occurring following CO2 increase. There are however substantial differences in the temperature mediated cloud feedbacks that occur while the climate is warming versus cooling. Key Points: The temperature mediated cloud changes and feedbacks incurred by changes in solar and CO2 forcing are similarOptical depth changes at high latitudes produce substantial differences in cloud feedbacks in cooling and warming experimentsLikewise, tropical circulations respond differently in models to cooling and warming, with a stronger change in the Walker circulation in warming experiments [ABSTRACT FROM AUTHOR]

Drawing on ecological economics, post-development studies, and political ecology, this paper argues that sustainable development notions have run their course within sustainability marketing debates and proposes degrowth as an alternative framework to steer disciplinary debates in new directions. We chart unexplored territory, offering sustainability marketing scholars tools to navigate degrowth-minded policies, transformative frameworks, and business models. In doing so, our work contributes to existing sustainability marketing debates in three ways: first, we respond to the paucity of studies engaging with the political economy of sustainability marketing. Second, we make visible the tensions and contradictions that arise as marketers seek to reconcile imperatives of economic growth and sustainability. Finally, we foreground degrowth as an emerging sustainability proposition, with potential for inspiring the radical set of transformations required to avert catastrophic climate change and keep global temperatures well below +2°C (relative to pre-industrial levels), as pledged in the Paris Agreement. [ABSTRACT FROM AUTHOR]