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1. On the competition between six-membered and five-membered NHC towards alane centered ring expansion.

Author

Balayan, Kajal, Sharma, Himanshu, Vanka, Kumar, Ravindranathan, Sapna, Gonnade, Rajesh G., and Sen, Sakya S.

Subjects
HYDRIDES, LIGANDS (Chemistry), IODIDES
Abstract

The combination of 6-SIDipp·AlH3 (1) and 5-IDipp resulted in the ring expansion of 6-NHC, while the five-membered NHC remained unchanged, which was subsequently explained by DFT studies. Besides, the substitution chemistry of 1 was also studied with TMSOTf and I2, which gave rise to the substitution of a hydride by triflate or iodide ligands. [ABSTRACT FROM AUTHOR]

Published
2023
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