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Bottom-up nanofabrication, organizing colloidal nanoparticles into ordered clusters with structural and functional complexity, provides an alternative to yield nanometric smart structures unachievable in traditional top-down approaches. Those remarkable structures assembled of colloidal nanoparticles possessing optical properties feature exotic optical responses under the illumination of incident light, showing highly dependent on the particle separation, composition, and arrangement. Here, the nanoscale electromagnetic coupling in magnetic–plasmonic nanoparticle clusters is analyzed by using a 3D full-wave computational model, and the mechanism of the resonances in a split-ring resonator out of magnetic–plasmonic nanoparticle building blocks is also illustrated. In particular, once assembling those artificial molecules (split-ring resonator) into secondary metamaterial superstructures, such as split-ring resonator dimer and Y-shaped structures, a series of exotic optical responses are presented due to the greatly enhanced near-field coupling of nanoparticles and the generation of antiparallel ring currents in the asymmetrical superstructure, exhibiting flexible sensitivity to the changes of the surrounding environment. Besides, the H-shaped arrangement exhibits high sensitivity with Q = 50.5 at λ = 2.02 μ m. Our finding provides a platform for yielding complex structures with flexible tunability of the optical response through arranging those assembled artificial molecules into complex secondary structures, allowing for the development of smart sensing devices. [ABSTRACT FROM AUTHOR]

Patterning a wide range of colloidal plasmonic nanoparticles into prescribed spatial arrangements, analogous to the formation of natural materials, enables the fabrication of functionalized structures with novel optical properties, such as Fano resonance, magneto-optical Kerr effect, negative refraction, etc. Currently, capillarity-assisted particle assembly is always utilized to place colloidal particles at predetermined positions by exploiting the capillary forces resulting from the motion of an evaporating droplet. However, this technique requires specialized equipment and the assembly process is always carried out in an open system, thereby introducing the risk of contamination and limiting its applications. Here, we present a microfluidic and magnetic field-assisted self-assembly of colloidal magnetic-plasmonic nanoparticles by utilizing magnetic dipole–dipole interactions resulting from the localized magnetic gradient field produced by an array of soft-magnetic elements and external magnetic bias field. The magnetized magnetic-plasmonic nanoparticles are controlled to deposit at the predesigned traps microfabricated onto the soft-magnetic elements. After deposition, the inlet velocity of the microchannel is improved to clear away the particles out of the traps, forming arrays of patterns with consistent structures. Furthermore, a Lagrangian–Eulerian model is introduced for the first time to predict the processing of the microfluidic and magnetic field-assisted self-assembly of colloidal magnetic-plasmonic nanoparticles by taking the magnetic and hydrodynamic forces and particle–fluid interaction into account. Our analysis demonstrates that the particle–fluid interaction not only plays a significant role in determining the final self-assembled nanostructures, but provides an opportunity to improve the consistency of the assembled nanostructures. The microfluidic and magnetic field-assisted self-assembly protocol proposed here enables the patterning of colloidal magnetic-plasmonic nanoparticles to be carried out in a controlled environment and also opens up a new direction for assembling complex structures. [ABSTRACT FROM AUTHOR]

The preparation and storage of aluminum nanoparticles pose significant challenges due to their high chemical reactivity. This paper proposes a one-step method for the production of carbon-coated aluminum nanoparticles using an argon protective arc in a liquid nitrogen environment. The emission spectra of the arc validate that the method proposed in this paper can effectively mitigate the adverse impact of impurity gases such as oxygen and water on the product without the need for expensive vacuum equipment. The obtained nanoparticles underwent characterization through high-resolution transmission electron microscopy, energy-dispersive X-ray spectroscopy, X-ray diffraction, X-ray photoelectron spectroscopy, Raman analysis, thermogravimetric analysis, and dynamic light scattering. The characterization results demonstrate the successful synthesis of carbon-coated aluminum nanoparticles with nitrogen-doped fullerene shells. With an increase in arc current, the nanoparticles exhibit a corresponding enlargement in diameter, accompanied by a broader distribution. The characterization of the electrode erosion suggests that the aluminum droplet ejection plays a more important role in the nanoparticle generation process as the arc current increases. Optimized strategies are proposed to increase the percentage of successfully-formed carbon-coated aluminum nanoparticles. • One-step preparation of carbon-coated aluminum nanoparticles. • Arc discharge in liquid environment without vacuum and sealing equipment. • Core-shell structure: Al core wrapped in N-doped fullerenes. • The arc current impacts electrode erosion pattern and product characteristics. [ABSTRACT FROM AUTHOR]