Search

Understanding ion transport kinetics and electrolyte-electrode interactions at electrode surfaces of batteries in operation is essential to determine their performance and state of health. However, it remains a challenging task to capture in real time the details of surface-localized and rapid ion transport at the microscale. To address this, a promising approach based on an optical fiber plasmonic sensor capable of being inserted near the electrode surface of a working battery to monitor its electrochemical kinetics without disturbing its operation is demonstrated using aqueous Zn-ion batteries as an example. The miniature and chemically inert sensor detects perturbations of surface plasmon waves propagating on its surface to rapidly screen localized electrochemical events on a sub-μm-scale thickness adjacent to the electrode interface. A stable and reproducible correlation between the real-time ion insertions over charge-discharge cycles and the optical plasmon response has been observed and quantified. This new operando measurement tool will provide crucial additional capabilities to battery monitoring methods and help guide the design of better batteries with improved electro-chemistries. Operando tracking the ion dynamics/states of battery is critical to understanding of electrolyte-electrode interactions. Here the authors propose to use the surface plasmon waves to rapidly screen localized electrochemical events on a sub-μm-scale thickness adjacent to the electrode interface, without perturbing battery operation. [ABSTRACT FROM AUTHOR]

In situ and highly sensitive monitoring of tumor cells provides a fundamental understanding of the valuation of cancer diagnosis. However, existing techniques are largely unable to rapidly capture and precisely quantify the tumor cells. To address this, we propose a novel approach based on a nanotube-functionalized & microfluidic-controlling multiresonance optical fiber sensor. The sensor consists of a tilted fiber Bragg grating (TFBG) inscribed in the fiber core and specially designed halloysite nanotubes (HNTs) coated over the fiber surface. In particular, the HNTs are arranged in an orderly manner along the fiber surface to form slit-like patterned layers for enhanced the interaction with tumor cells, resulting in more effective capture of tumor cells. Such a sensor provides a powerful light scattering sensing ability. Based on the spectral area interrogation method, normal cells and tumor cells can be unambiguously discriminated within a few minutes, providing high sensitivity (limit of detection of 10 cells/mL), and a linear response for a large cell concentration range (10 ∼ 105 cells/mL). Meanwhile, by integrating the fiber sensor with a well-designed microfluidic chip, rapid and precise measurement of different tumor cell samples with low consumption (sub-microliter volumes) can be achieved, which provides a potential tool for cancer diagnosis and treatment. • A novel fiber sensor for tumor cells at very low concentrations is proposed. • A new demodulation method based on the light scattering effect is proposed. • The sensor could rapidly capture of tumor cells through HNTs. • The sensor is promising for the in situ initial screening of tumor cells. [ABSTRACT FROM AUTHOR]

• Realizing excellent fusion of optical fiber and lithium-ion battery. • Implementation of internal temperature monitor by implanting FBG. • FBG sensor displays better signal-to-noise ratio than thermocouple. • The internal temperature is 3.83 °C higher than the external temperature at 2C. • Revealing relationship between charge/discharge rates and temperature gradient. Current cell performance monitoring, which relies on measurements of sporadic surface temperature through the battery management system (BMS), does not provide a reliable information on the true internal battery state. Here we proposed and demonstrated in-operation temperature monitoring of lithium-ion batteries using an implanted femtosecond-laser-inscribed fiber Bragg grating (FBG) sensor. For comparison, both FBG and thermocouple are simultaneously implanted in an 18650 cell. Over repeat cycles with different conditions (0.5C, 1C and 2C), we experimentally demonstrated that implanted FBG and thermocouple sensors show very similar temperature response curves but the FBG sensor provide a much better signal-to-noise ratio. The monitored internal temperature by FBG is 3.71 °C higher than the external temperature during 2C cycling, demonstrating the necessity to record internal temperature especially at long cycles and higher rates within BMS. This operando FBG sensor is a powerful tool in current battery monitoring and its state-of-health evolutions. [ABSTRACT FROM AUTHOR]