38 results on '"*CARBON nanofibers"'
Search Results
2. Hydrothermal growth of FeMoO4 nanosheets on electrospun carbon nanofibers as freestanding supercapacitor electrodes.
- Author
-
Khadka, Ashwin, Samuel, Edmund, Pradhan, Shrayas, Joshi, Bhavana, Aldalbahi, Ali, El-Newehy, Mohamed, Lee, Hae-Seok, and Yoon, Sam S.
- Subjects
- *
SUPERCAPACITOR electrodes , *CARBON nanofibers , *NANOSTRUCTURED materials , *SUPERCAPACITORS , *ENERGY density , *AQUEOUS electrolytes , *POWER density - Abstract
In this study, an electrospinning method was used to produce highly conductive freestanding carbon nanofibers (CNFs). The freestanding CNFs are compatible with hierarchical growth techniques, such as hydrothermal processes, for the nanostructure engineering of supercapacitor electrodes with enhanced electrochemically active sites. Therefore, the flower-like FeMoO 4 @CNF nanosheets were investigated to improve the electrochemical performance using aqueous and neutral electrolytes (Na 2 SO 4 and K 2 SO 4). The optimized FeMoO 4 @CNF electrode exhibits areal capacitances of 252 and 220 mF·cm−2 at a high current density of 2.5 mA·cm−2 with Na 2 SO 4 and K 2 SO 4 electrolytes, respectively. The wide potential window (1.6 V) of the symmetric supercapacitor delivered maximum energy densities of 22.4 and 19.6 μWh·cm−2 at a power density of 2 mW·cm−2 for Na 2 SO 4 and K 2 SO 4 electrolytes, respectively. [ABSTRACT FROM AUTHOR]
- Published
- 2024
- Full Text
- View/download PDF
3. N-Doped Porous Carbon-Nanofiber-Supported Fe 3 C/Fe 2 O 3 Nanoparticles as Anode for High-Performance Supercapacitors.
- Author
-
Li, Li, Xie, Fengting, Wu, Heyu, Zhu, Yuanyuan, Zhang, Pinghua, Li, Yanjiang, Li, Hengzheng, Zhao, Litao, and Zhu, Guang
- Subjects
- *
SUPERCAPACITOR electrodes , *FERRIC oxide , *SUPERCAPACITORS , *DOPING agents (Chemistry) , *CARBON nanofibers , *ANODES , *NANOPARTICLES - Abstract
Exploring anode materials with an excellent electrochemical performance is of great significance for supercapacitor applications. In this work, a N-doped-carbon-nanofiber (NCNF)-supported Fe3C/Fe2O3 nanoparticle (NCFCO) composite was synthesized via the facile carbonizing and subsequent annealing of electrospinning nanofibers containing an Fe source. In the hybrid structure, the porous carbon nanofibers used as a substrate could provide fast electron and ion transport for the Faradic reactions of Fe3C/Fe2O3 during charge–discharge cycling. The as-obtained NCFCO yields a high specific capacitance of 590.1 F g−1 at 2 A g−1, superior to that of NCNF-supported Fe3C nanoparticles (NCFC, 261.7 F g−1), and NCNFs/Fe2O3 (NCFO, 398.3 F g−1). The asymmetric supercapacitor, which was assembled using the NCFCO anode and activated carbon cathode, delivered a large energy density of 14.2 Wh kg−1 at 800 W kg−1. Additionally, it demonstrated an impressive capacitance retention of 96.7%, even after 10,000 cycles. The superior electrochemical performance can be ascribed to the synergistic contributions of NCNF and Fe3C/Fe2O3. [ABSTRACT FROM AUTHOR]
- Published
- 2023
- Full Text
- View/download PDF
4. Development of Electrospun Polymer Nanofiber Membrane Based on PAN/PVDF as a Supercapacitor Separator.
- Author
-
Nasikhudin, Azizah, Fina Nur, Sa’adah, Ulwiyatus, Diantoro, Markus, Hartatiek, and Subramaniam, Ramesh T.
- Subjects
- *
POLYMERIC membranes , *SUPERCAPACITORS , *FOURIER transform infrared spectroscopy , *ENERGY storage , *SUPERCAPACITOR performance , *SHORT circuits , *SUPERCAPACITOR electrodes , *CARBON nanofibers - Abstract
Among various types of energy storage, the supercapacitor is regarded as the most promising device due to its long cycling life, good cycling stability, and high power density. A supercapacitor is generally composed of electrodes, electrolytes, and a separator. The separator is one of the most important components, serving to prevent internal short circuits between the anode and the cathode. Herein, a nanostructured-based separator in a PAN/PVDF nanofiber scheme is introduced for improving the electrochemical performance of the supercapacitor. Briefly, the membranes were produced via the electrospinning technique. All of the raw materials were blended in various compositions of PVDF for optimization purposes. Fourier transform infrared spectroscopy (FTIR) and scanning electron microscopy (SEM) were carried out to identify the microstructure of the nanofibers. The electrochemical properties of the membrane were measured using galvanostatic charge-discharge (GCD). Based on GCD, it was shown that the PAN/PVDF 20 wt% membrane exhibited the optimum gravimetric capacitance at 54.104 Fg-1 as evidenced by a high porosity percentage. Thus, the PAN/PVDF nanofiber has good potential as a separator for application in supercapacitors. [ABSTRACT FROM AUTHOR]
- Published
- 2023
- Full Text
- View/download PDF
5. Nickel carbonate Hydroxide-based Core-Triple-Shelled nanofibers with ultrahigh specific capacity for flexible hybrid supercapacitors.
- Author
-
Zhao, Yan, Wang, Yaqing, Huang, Yunpeng, Liu, Wenjie, Hu, Jinzhi, Zheng, Jihua, and Wu, Limin
- Subjects
- *
NICKEL carbonates , *SUPERCAPACITORS , *SUPERCAPACITOR electrodes , *CARBON nanofibers , *NANOFIBERS , *ENERGY density , *NANOSTRUCTURED materials , *POLYANILINES - Abstract
A series of core-triple-shelled GCNF/PANI/NCO nanostructures have been fabricated via a facile strategy. Taking full advantage of the free-standing architecture of graphene-coated electrospun carbon nanofibers (GCNF), high conductivity and flexibility of the polyaniline (PANI) layers, and abundant active sites of nickel carbonate hydroxide (Ni 2 (CO 3)(OH) 2) nanosheets, the optimal electrode exhibits a high specific capacitance of 1565F g−1 at 1 A/g, which exceeds almost all of the reported nickel carbonate hydroxide-based electrodes in literatures. A hybrid supercapacitor delivers a high energy density of 35.4 Wh kg−1@750 W kg−1 and a long cycle lifespan. This strategy enables the controllable synthesis of core-triple-shelled hierarchical materials applicable to diverse electrochemical applications. [Display omitted] • We prepared the core-triple-shelled GCNF/PANI/NCO fiber-based films via a new route. • The optimal electrode exhibits high electrochemical properties via joint actions. • A hybrid supercapacitor displays large specific capacities and high energy density. • This strategy provides a new way to synthesize other core-triple-shelled materials. Designing novel efficient electrode materials with controlled hierarchical structure and composition for advanced supercapacitors remains a great challenge. Herein, a core-triple-shelled hierarchical GCNF/PANI/NCO nanostructure has been designed and fabricated by sequential growth of the conductive polyaniline (PANI) layers and nickel carbonate hydroxide (Ni 2 (CO 3)(OH) 2) nanosheets on the graphene-coated electrospun carbon nanofibers (GCNF) via a facile wet-chemical strategy. Taking full advantage of the free-standing architecture of graphene-coated electrospun carbon nanofibers, high conductivity and flexibility of the PANI layers, and abundant active sites of Ni 2 (CO 3)(OH) 2 nanosheets, the optimal GCNF/PANI/NCO (2 h) electrode exhibits a high specific capacitance of 1565F g−1 at 1 A/g and enhanced rate capability, which are higher than those of the GCNF, GCNF/PANI, and GCNF/NCO (2 h) electrodes at the same situation, and also exceeds most of the reported nickel carbonate hydroxide-based electrodes in literature. The superior performance should be mainly ascribed to the collaborative contribution of each component. Moreover, a self-assembled GCNF/PANI/NCO//AC hybrid supercapacitor delivers a high energy density of 35.4 Wh kg−1@750 W kg−1 and a long cycle lifespan. This strategy enables the controllable synthesis of core-triple-shelled hierarchical materials applicable to advanced electrochemical applications. [ABSTRACT FROM AUTHOR]
- Published
- 2023
- Full Text
- View/download PDF
6. Robust N-doping porous carbon nanofiber membranes with inter-fiber cross-linked structures for supercapacitors.
- Author
-
Zhu, Jianhua, Zhang, Qian, Zhao, Yanjiao, Zhang, Ruiyun, Liu, Lifang, and Yu, Jianyong
- Subjects
- *
SUPERCAPACITORS , *SUPERCAPACITOR electrodes , *ENERGY storage , *ELECTRIC conductivity , *ENERGY density , *CARBON nanofibers , *ENERGY conversion - Abstract
Enhancing the electrochemical performance while maintaining excellent mechanical properties of carbon nanofiber-based flexible electrodes remains a significant challenge, which blocks their potential application in advanced energy storage and conversion. Herein, taking advantage of the thermal stability difference between polyacrylonitrile and polypyrrolidone, we report a simple strategy to fabricate N-doped porous carbon nanofiber membranes with inter-fiber cross-linked structures via eccentric coaxial electrospinning combined with carbonization processes. During carbonization processes, the obstacles of large contact resistance are removed and sufficient contacts among electrospun nanofibers are formed, endowing the carbon nanofiber membranes with outstanding electrical conductivity (25.4 S cm−1) and flexibility in various forms. Further, NiCo 2 O 4 nanoneedles are in-situ decorated onto the prepared carbon nanofiber membranes to construct hybrid electrodes for improving capacitance. The hybrid electrodes (NiCo 2 O 4 @NPCNFs) achieve a competitive specific capacitance (capacity) of 1474.2 F g−1 (245.4 mAh g−1) at the current density of 0.5 A g−1, as well as good rate performance (78.0% capacitance retention at a current density of 10 A g−1). In addition, the assembled asymmetric supercapacitors exhibit a high energy density of 53.0 Wh kg−1. This study paves a promising way toward carbon nanofiber-based electrodes for application in energy storage systems. [Display omitted] • According to the different thermal stabilities of the polymers, cross-linked electrospun carbon nanofibers are prepared. • Design eccentric core-shell nanofibers to facilitate the outflow of the melting core to form abundant crosslinking points. • The novel carbon nanofiber membranes render robust flexibility and high electrical conductivity. • The assembled flexible supercapacitor can supply power stably and continuously even under severe bending states. [ABSTRACT FROM AUTHOR]
- Published
- 2023
- Full Text
- View/download PDF
7. Preparation of Advanced Multi-Porous Carbon Nanofibers for High-Performance Capacitive Electrodes in Supercapacitors.
- Author
-
Zhao, Donghui, Wang, Hui, Bai, Yu, Yang, Hao, Song, Hongfang, and Li, Baohua
- Subjects
- *
CARBON nanofibers , *SUPERCAPACITORS , *ENERGY storage , *PORE size distribution , *ELECTRODES , *ENERGY development - Abstract
The booming demand for energy storage has driven the rapid development of energy storage devices such as supercapacitors, and the research on high-performance electrode materials, a key component of supercapacitors, has gained tremendous attention. In this research, phenolic resin-based multi-porous carbon nanofibers have been prepared by electrospinning, curing, carbonization and activation and then employed as advanced electrode materials in supercapacitors. We demonstrate that the material is nano-scale continuous fiber, and its surface has pore distribution of different sizes. It delivers a high specific capacitance of 242 F g−1 at a current density of 0.2 A g−1 and maintains 148 F g−1 even at a high current density of 20 A g−1. Moreover, it shows almost no capacitance decay at a current density of 2 A g−1 over 1000 cycles, demonstrating its great potential as high-performance electrodes in supercapacitors. [ABSTRACT FROM AUTHOR]
- Published
- 2023
- Full Text
- View/download PDF
8. Design of Ni(OH) 2 Nanosheets@NiMoO 4 Nanofibers' Hierarchical Structure for Asymmetric Supercapacitors.
- Author
-
Li, Junzhu, Chang, Xin, Zhou, Xuejiao, and Zhang, Mingyi
- Subjects
- *
CARBON nanofibers , *NANOFIBERS , *SUPERCAPACITOR electrodes , *SUPERCAPACITORS , *ENERGY conversion , *ENERGY storage , *CHEMICAL properties , *CAPACITORS - Abstract
Transition−metal−based materials show great promise for energy conversion and storage due to their excellent chemical properties, low cost, and excellent natural properties. In this paper, through simple strategies such as classical electrospinning, air calcination, and the one−step hydrothermal method, a large area of Ni(OH)2 nanosheets were grown on NiMoO4 nanofibers, forming NiMoO4@Ni(OH)2 nanofibers. The one−dimensional nanostructure was distributed with loose nanosheets, and this beneficial morphology made charge−transfer and diffusion more rapid, so the newly developed material showed good capacitance and conductivity. Under the most suitable experimental conditions, the optimal electrode exhibited the highest specific capacitance (1293 F/g at 1 A/g) and considerable rate capability (56.8% at 10 A/g) under typical test conditions. Most interestingly, the corresponding asymmetrical capacitors exhibited excellent electrochemical cycle stability, maintaining 77% of the original capacitance. NiMoO4@Ni(OH)2 nanofibers were verified to be simple to prepare and to have good performances as energy−storage devices within this experiment. [ABSTRACT FROM AUTHOR]
- Published
- 2022
- Full Text
- View/download PDF
9. Electrochemical activity of triple-layered boron-containing carbon nanofibers with hollow channels in supercapacitors.
- Author
-
Lee, Hyo Chan, Kim, Yoong Ahm, and Kim, Bo-Hye
- Subjects
- *
CARBON nanofibers , *SUPERCAPACITOR electrodes , *SUPERCAPACITORS , *METHYL methacrylate , *ENERGY density , *CHEMICAL stability , *POWER density - Abstract
Triple-layered boron-containing carbon nanofibers (CNFs) with hollow channels (PPMPB) are fabricated via step-by-step electrospinning for high-performance freestanding supercapacitors. Polyacrylonitrile (PAN)-based CNFs in the first layer are chosen as the support layer material because of their excellent chemical stability and electrospinnability. The well-developed hollow channels provided fast ion diffusion in the second layer of PAN/poly(methyl methacrylate) (PMMA)-based CNFs. The surface boron functional groups constituting the third layer contribute to the pseudo-capacitance. The symmetric supercapacitor of the PPMPB electrodes delivers a maximum specific capacitance of 180 Fg−1 at 1 mAcm−2, a high energy density of 22.38 Whkg−1 at a power density of 400 Wkg−1, and an excellent retention rate of 96% after 10,000 cycles in aqueous solution. The excellent electrochemical performance is attributed to the unique sandwich nanostructure with a three-layer structure, in which the factors representing the electrochemical properties of each layer do not interfere with each other. Therefore, a moderate amount of boron and the high surface area of the triple-layer structured PPMPB can be fully utilized as an excellent conductive network and electroactive sites, which is expected in a high-performance supercapacitor electrode. [Display omitted] • Triple-layered boron-containing CNFs were fabricated by step-by-step electrospinning. • The CNFs in the first layer provide active adsorption sites for EDLC. • Hollow core present in the interlayer serves as an excellent conductive network. • A moderate amount of boron in the third layer is utilized as the electroactive site. • Symmetric PPMPB(20) electrode showed good rate capability and long cycle life. [ABSTRACT FROM AUTHOR]
- Published
- 2022
- Full Text
- View/download PDF
10. Biomass-based carbon nanofibers enhanced by carbon quantum dots for high-performance supercapacitors and moist-electric generators.
- Author
-
Jin, Zhenxing, Cao, Qiping, Gong, Hui, Chen, Bo, Jiang, Yuewei, Su, Yingying, Zhou, Jinghui, and Li, Yao
- Subjects
- *
CARBON nanofibers , *QUANTUM dots , *ELECTRIC generators , *SUPERCAPACITORS , *LIGNIN structure , *POWER resources , *ELECTRIC power production - Abstract
Developing a simple and effective method for optimizing lignin structure is a key challenge for the application of biomass-based carbon nanofibers in energy storage and moisture-enabled electricity generation fields. In this work, an effective strategy is designed to prepare novel biomass-based carbon nanofibers. Carbon quantum dots (CQDs) are introduced as functional components into biomass-based carbon nanofibers to optimize the inherent structural defects of lignin. The introduction of CQDs effectively reduces the interaction between lignin macromolecules, thereby increasing the flexibility of lignin macromolecule chain segments. The obtained biomass-based carbon nanofibers exhibit excellent microfiber morphologies and a high degree of graphitization. The specific capacitance and energy density for biomass-based carbon nanofibers as the energy storage device reach 294.4 F/g and 28.3 W h/kg, respectively. Furthermore, the biomass-based moist-electric generator shows high power generation efficiency, the output voltage and output current of a single device reach 0.75 V and 1.8 μA, respectively. Notably, as the number of biomass-based moist-electric generators in series or parallel increases, the overall output efficiency of the device system has a linear relationship, which means that a sufficient number of biomass-based moist-electric generator devices can meet the power supply requirements of larger power systems. This work puts forward a promising strategy to prepare low-consumption, high-performance, and environmentally friendly biomass-based carbon nanofibers for the supercapacitors and moist-electric generators. [Display omitted] • The introduction of CQDs optimize the inherent structural defects of lignin. • CQDs improve the fiber morphology and graphitization degree of carbon nanofibers. • Biomass-based carbon nanofibers exhibit excellent electrochemical performance. • Biomass-based carbon nanofibers can be used for a novel moist-electric generator. • The preparation of novel biomass-based carbon nanofibers was proposed. [ABSTRACT FROM AUTHOR]
- Published
- 2024
- Full Text
- View/download PDF
11. Dual-role KCl-assisted fabrication of porous carbon with controllable architecture from coal liquefaction residue for supercapacitors.
- Author
-
Yang, Xiaoxia, Sun, Guoxiao, Wang, Fei, Chen, Long, Zhang, Zhuangzhuang, Zhen, Yanzhong, Wang, Danjun, Fu, Feng, and Chi, Ru'an
- Subjects
- *
CARBON nanofibers , *COAL liquefaction , *SUPERCAPACITORS , *POROSITY , *CARBON , *ENERGY density , *CARBON dioxide - Abstract
Schematic illustration of the preparation of porous carbons. [Display omitted] • The porous carbons with controllable architecture were fabricated by a dual-role KCl-assisted activation method. • KCl not only serves as an auxiliary template but also contributes to an enhancement in the melting of K 2 CO 3. • The prepared porous carbons possess well-developed pore structure and excellent electrochemical performance. • This work paves a path to prepare porous carbons via an environment-friendly and cost-effective route for supercapacitors. Preparation of high-performance electrode materials in a low-cost and simple way is of great significance for the application and development of supercapacitors. Herein, a dual-role KCl-assisted KOH activation method with low KOH consumption was employed to fabricate porous carbons with controllable architecture, using the coal liquefaction residue (CLR) as the raw material. It is indicated that KCl not only serves as an auxiliary template for pore-forming but also contributes to an enhancement in the melting of K 2 CO 3 , an intermediate of KOH activation, resulting in an improvement in the efficiency of KOH activation. As a consequence, the prepared samples possess highly developed pore structure even at a low KOH consumption, which endow them with excellent capacitive performance. The as-fabricated optimal porous carbon (LR-KPC-4) displays a maximum specific capacitance of 375 F g−1 at 0.5 A/g and superior rate capacity, which are much better than those of the porous carbon prepared without KCl. The fabricated symmetric supercapacitor shows a high specific capacitance of 256 F g−1 at 0.5 A/g, energy density of 8.9 Wh kg−1 at 125 W kg−1 and great cycling stability. This work demonstrates a facile strategy to efficiently convert CLR into porous carbons for high-performance supercapacitors. Meanwhile, it paves a promising way for value-added utilization of CLR. [ABSTRACT FROM AUTHOR]
- Published
- 2024
- Full Text
- View/download PDF
12. Intumescent flame retardants inspired template-assistant synthesis of N/P dual-doped three-dimensional porous carbons for high-performance supercapacitors.
- Author
-
Xu, Xiaodong, Wang, Ting, Wen, Yanliang, Wen, Xin, Chen, Xuecheng, Hao, Chuncheng, Lei, Qingquan, and Mijowska, Ewa
- Subjects
- *
CARBON nanofibers , *SUPERCAPACITORS , *SUPERCAPACITOR electrodes , *FIREPROOFING agents , *ENERGY density , *ENERGY storage , *POWER density , *CARBON - Abstract
N/P dual-doped three-dimensional porous carbon was synthesized via nano-CaCO 3 template-assistant carbonization of intumescent flame retardants (IFRs) precursor. [Display omitted] Heteroatom-doped three-dimensional (3D) porous carbons possess great potential as promising electrodes for high-performance supercapacitors. Inspired by the inherent features of intumescent flame retardants (IFRs) with universal availability, rich heteroatoms and easy thermal-carbonization to form porous carbons, herein we proposed a self-assembling and template self-activation strategy to produce N/P dual-doped 3D porous carbons by nano-CaCO 3 template-assistant carbonization of IFRs. The IFRs-derived carbon exhibited large specific surface area, well-balanced hierarchical porosity, high N/P contents and interconnected 3D skeleton. Benefitting from these predominant characteristics on structure and composition, the assembled supercapacitive electrodes exhibited outstanding electrochemical performances. In three-electrode 6 M KOH system, it delivered high specific capacitances of 407 F g−1 at 0.5 A g−1, and good rate capability of 61.2% capacitance retention at 20 A g−1. In two-electrode organic EMIMBF 4 /PC system, its displayed high energy density of 62.8 Wh kg−1 at a power density of 748.4 W kg−1, meanwhile it had excellent cycling stability with 84.7% capacitance retention after 10,000 cycles. To our best knowledge, it is the first example to synthesize porous carbon from IFRs precursor. Thus, the current work paved a novel and low-cost way for the production of high-valued carbon material, and expanded its application for high-performance energy storage devices. [ABSTRACT FROM AUTHOR]
- Published
- 2022
- Full Text
- View/download PDF
13. Porous hollow biomass‐based carbon nanofiber/nanosheet for high‐performance supercapacitor.
- Author
-
Taer, Erman, Apriwandi, Apriwandi, Agustino, Agustino, Dewi, Mega Ratna, and Taslim, Rika
- Subjects
- *
CARBON nanofibers , *ACTIVATED carbon , *SUPERCAPACITOR electrodes , *SUPERCAPACITORS , *AQUEOUS electrolytes , *ACTIVATION (Chemistry) , *ENERGY density , *POWER density - Abstract
Summary: The development of efficient methods to achieve a porous activated carbon nanostructures electrode for high‐performance electrochemical double‐layer capacitor (EDLC) is urgently needed at present. In this study, biomass‐based porous hollow carbon nanofiber/nanosheet with suitable micro/mesopores was successfully prepared using a low‐cost simple approach through chemical activation at direct pyrolysis. Biomass‐based porous carbon was performed in two different chemical activation of KOH and ZnCl2. The effects of the different KOH/ZnCl2 concentrations at high‐temperature pyrolysis on the morphological structure and porosity were investigated. The synthesized activated carbon possesses micro/mesopores hollow nanofiber/nanosheet, which enhanced specific surface area from 15.163 m2 g−1 to ultrahigh specific surface area of 1041.900 m2 g−1. These behaviors exhibit a high specific capacitance of 213 F g−1 in a two‐electrode system with excellent energy and power density of 29.6 Wh kg−1 and 106.6 W kg−1 at 1 M H2SO4 aqueous electrolyte. These results provided accurate information about a feasible approach to synthesize biomass‐based porous hollow carbon nanofiber/nanosheet to boost high‐performance energy storage devices. [ABSTRACT FROM AUTHOR]
- Published
- 2022
- Full Text
- View/download PDF
14. Flexible porous carbon nanofibers derived from cuttlefish ink as self-supporting electrodes for supercapacitors.
- Author
-
Wang, Dawei, Lian, Yue, Fu, Hongliang, Zhou, Qiuping, Zheng, Yujing, and Zhang, Huaihao
- Subjects
- *
SUPERCAPACITORS , *CARBON nanofibers , *CUTTLEFISH , *CARBON-based materials , *CARBON electrodes , *SUPERCAPACITOR electrodes , *ENERGY density - Abstract
Using renewable biomass precursors to develop high-performance carbon electrodes is a promising approach for the advancement of supercapacitors. This work proposes a feasible strategy to prepare self-supporting flexible porous carbon nanofibers by electrospinning and carbonizing the mixture of cuttlefish ink, polyacrylonitrile (PAN) and polymethyl methacrylate (PMMA). The impacts of cuttlefish ink precursor on the structure, elemental composition, and capacitance properties of carbon nanofibers have been studied. Herein, the unique structural advantage of cuttlefish ink can significantly optimize the porous structure of carbon nanofibers. Due to the hierarchical porous structure, large specific surface area, hollow channels and high nitrogen content, the carbon nanofibers offer a high specific capacitance of 364.8 F g−1 at 0.5 A g−1 current density, alongside desirable rate performance and cycle life. Furthermore, the carbon nanofiber electrode performs good mechanical flexibility. The flexible solid-state supercapacitor based on this electrode exhibits 14.1 Wh kg−1 energy density at 0.4 kW kg−1 power density, and 97.8% capacitance retention after 5000 cycles. The favorable capacitive properties make this carbon nanofiber material a potential candidate for supercapacitor electrodes. [Display omitted] • Electrospun porous carbon nanofibers (CPP–CNF) were prepared from cuttlefish ink. • CPP-CNF features hierarchical pores and hollow channels. • CPP-CNF is mechanically flexible with superior capacitive performance. • The flexible supercapacitor achieves high energy density and cycling stability. [ABSTRACT FROM AUTHOR]
- Published
- 2024
- Full Text
- View/download PDF
15. Self-single-doped hierarchical porous carbon nanofiber derived Alpinia galanga stem-based for boosted supercapacitor performance.
- Author
-
Taer, Erman, Nursyafni, Nursyafni, Febriani, Widya, Apriwandi, Apriwandi, Manjunatha, Jamballi G., Deraman, Mohamad, and Taslim, Rika
- Subjects
- *
CARBON nanofibers , *SUPERCAPACITOR performance , *ALPINIA , *SUPERCAPACITOR electrodes , *SUPERCAPACITORS , *ENERGY density , *OXIDATION-reduction reaction , *CARBON - Abstract
[Display omitted] • Self-O-doped Alpinia galanga stem-based carbon nanofiber succesfully synthesis. • The hierarchical porous carbon exhibit high specific surface area of 1065.58 m2/g. • The porous carbon was performed in solid-free binder form. • In 2-electrode system, supercapacitor possessed specific capacitance of 226F g−1. In this study, activated carbon with hierarchical pores and a nanofiber structure doped with oxygen was prepared using a pure biomass-based sustainable strategy involving integrated chemical impregnation and pyrolysis. Alpinia galangal stem was chosen as it functions as fast conductive network with abundant electrochemical active sites for high-grade electrode materials. The optimal precursor exhibited self-doping of oxygen ranging from 6.15 to 15.69 % with 1065.58 m2/g, which contributed to the redox reaction of the electrode material. When tested in a 2-electrode system, the porous carbon nanofibers showed a high specific capacitance of 226F g−1 at 1 A g−1 in 1 M H 2 SO 4 electrolyte, producing an energy density of 9.3483 Wh kg−1 with a coulombic efficiency of 89.01 %. The results showed that oxygen-doped hierarchical porous carbon nanofibers produced from Alpinia galangal stem biomass and designed to be solid-free of binders are highly promising as high-quality electrode materials that can improve sustainable supercapacitor performance. [ABSTRACT FROM AUTHOR]
- Published
- 2024
- Full Text
- View/download PDF
16. Nanohole-created carbon nanofibers for graphene-based supercapacitors.
- Author
-
Seol, Jaechang, Lim, Gil Hwan, Lee, Jimin, David, Selvaraj, and Kahng, Yung Ho
- Subjects
- *
CARBON nanofibers , *ELECTRODE performance , *SUPERCAPACITORS , *STANDARD hydrogen electrode , *ELECTROCHEMICAL analysis , *POTASSIUM hydroxide - Abstract
Manifold graphene-based supercapacitor (GSC) electrodes have been extensively studied recently. Numerous studies have aimed to improve the performance of GSCs by amending the surface using various treatments or by incorporating diverse materials. However, few studies have been conducted on the treatments for the back electrodes which support the active material in the GSCs. Herein, the activation of carbon nanofibers (CNFs) back electrodes was achieved through simple thermal activation using potassium hydroxide (KOH) as an activating agent to enhance the electrochemical performance of GSC electrodes. The optimized sample exhibited a specific capacitance (C sp) of 210 F/g at 100 mV/s without adversely affecting the self-discharge behavior of the electrodes. Compared to the reference electrodes formed on the nonactivated CNFs, the C sp at high rate operations of the GSC electrodes was markedly increased by 1.6 times. Morphological, elemental, and electrochemical analyses were conducted to study the effects of KOH activation on the performance enhancement of GSC electrodes. Our results present a novel research approach for enhancing GSC performance. [Display omitted] • KOH thermal activation for carbon nanofiber back electrodes was conducted. • An optimum temperature for the activation was found to be 800 °C. • The activation increased the specific capacitance for graphene supercapacitors. • The self-discharging did not worsen, indicating the practicality of this discovery. [ABSTRACT FROM AUTHOR]
- Published
- 2024
- Full Text
- View/download PDF
17. Biomass-derived multifunctional nanoscale carbon fibers toward fire warning sensors, supercapacitors and moist-electric generators.
- Author
-
Huang, Chen, Su, Yingying, Gong, Hui, Jiang, Yuewei, Chen, Bo, Xie, Zhanghong, Zhou, Jinghui, and Li, Yao
- Subjects
- *
CARBON fibers , *CARBON nanofibers , *DEIONIZATION of water , *FIRE detectors , *ENERGY density , *SUPERCAPACITORS , *DETECTORS , *ENERGY function , *ENERGY storage - Abstract
Nowadays, great effort has been devoted to designing biomass-derived nanoscale carbon fibers with controllable fibrous morphology, high conductivity, big specific surface area and multifunctional characteristics. Herein, a green and renewable strategy is performed to prepare the biomass-based nanoscale carbon fibers for fire warning sensor, supercapacitor and moist-electric generator. This preparation strategy thoroughly gets over the dependence of petroleum-based polymeride, and effectually improves the energy storage capacity, sensing sensitivity, humidity power generation efficiency of the obtaining biomass-based carbon nanofibers. Without the introduction of any active components or pseudocapacitive materials, the specific capacitance and energy density for biomass-based nanoscale carbon fibers achieve 143.58 F/g and 19.9 Wh/kg, severally. The biomass-based fire sensor displays excellent fire resistance, stability, and flame sensitivity with a response time of 2 s. Furthermore, the biomass-based moist-electric generator shows high power generation efficiency. The output voltage and current of five series connected and parallel-connected biomass-based moist-electric generators reaches 4.30 V and 43 μA, respectively. Notably, as the number of biomass-based moist-electric generators in series or parallel increases, the overall output voltage and current of the device system have a linear relationship. This work proposes a self-powered fire prediction system based on nanoscale carbon fibers that integrates sensing, power generation, and energy storage functions. [ABSTRACT FROM AUTHOR]
- Published
- 2024
- Full Text
- View/download PDF
18. Nickel-cobalt-TiO2 co-doped lignin based carbon nanofibers: Versatile integrated material for supercapacitor and microwave absorption.
- Author
-
Dai, Zhong, Zhang, Yazeng, Ma, Yin, Wu, Ying, Miao, Chuyu, and Li, Yuchun
- Subjects
- *
SUPERCAPACITORS , *MICROWAVE materials , *LIGNINS , *CARBON nanofibers , *DOPING agents (Chemistry) , *TITANIUM dioxide , *NANOWIRES , *ENERGY density - Abstract
The development of multifunctional composites is a challenging but necessary path for the miniaturization and integration of electronic products. Herein, versatile bimetal hydroxide (NiCo 2 (OH) 6) nanowires coated on TiO 2 modified lignin based carbon nanofibers (CNFs/TiO 2 @NiCo 2 (OH) 6) have been prepared successfully by the method of electrospinning followed by hydrothermal treatment. The loading of NiCo 2 (OH) 6 , the doping of N, and the modification of TiO 2 endow the CNFs/TiO 2 @NiCo 2 (OH) 6 with multifunctional application in energy storage and microwave absorption (MA). The abundant pores and active sites result in an excellent electrochemical performance with a high specific capacitance of 752.47 F g−1 at 1 A g−1. More importantly, the assembled supercapacitor exhibits a maximum energy density of 60.64 Wh kg−1 and a superior stability of 90.2 % even after 4000 cycles at the current density of 10 A g−1. Moreover, considering the unique porous layered-structure as well as eminent electromagnetic matching properties, as-prepared composites display an excellent MA property, which possesses a minimum reflection loss (RL min) of −46.48 dB and a maximum effective absorption bandwidth (EAB, RL < 10 dB) of 2 GHz (covering 47.62 % of X-band frequency). This work simultaneously delivers the potential application in the field of energy storage and MA. [Display omitted] • Bimetal hydroxide nanowires are grown on TiO 2 modified lignin based CNFs. • TiO 2 doping can enhance the MA properties of composites by improving the permittivity. • The doped TiO 2 generates more micro-defects and oxygen vacancies in CNFs. • The proposed design endows the versatile composites with excellent performance. • Providing a promising approach for the high-value utilization of lignin [ABSTRACT FROM AUTHOR]
- Published
- 2023
- Full Text
- View/download PDF
19. Performance enhancement of Hf-Ta-O nanofiber based energy storage materials using oxygen-vacancy and its application for supercapacitor.
- Author
-
Cao, Yi, Ruan, Piao, Xue, YuFeng, Cao, Yue, He, Huang, and Qiu, Wenfeng
- Subjects
- *
ENERGY storage , *CARBON nanofibers , *SUPERCAPACITORS , *NANOFIBERS , *ENERGY density , *POWER density , *CRYSTAL grain boundaries , *ELECTRODE potential - Abstract
Nowadays, materials that possess high activity and natural oxygen vacancy have garnered significant attention as potential electrode materials for supercapacitors. In this study, we successfully prepared the Hf 6 Ta 2 O 17 (HTO) nanofibres (NFs) with an orthorhombic superlattice structure using the electrospinning technique and sintering process. The characterization results indicate that the HTO NFs synthesized at 750 °C show good micro nanostructures and outstanding electrochemical properties. To enhance its energy storage performance, additional oxygen vacancies (OVs) were introduced through a carbothermal treatment under an Ar atmosphere. Although longer reduction reaction times can produce more OVs, the integration of grain boundaries and the growth of grain size caused by large annealing times may limit its electrochemical performance. Therefore, the HTO NFs treated for 1 h (HTO/C-1) exhibited the maximum C s of 925 F·g−1 at 1 A·g−1 with a larger voltage window of 2.1 V. Furthermore, a symmetric supercapacitor fabricated by two reduced HTO NFs electrodes and 1 M Na 2 SO 4 solution, recorded as r-HTO NFs//r-HTO NFs. The device demonstrated excellent energy density of 73.3 Wh·kg−1 (at power density of 1050 W·kg−1) and a long cycling life (81.8% retained after 5000 cycles). These results suggest that the optimized reduction process can provide appropriate oxygen vacancies in HTO NFs, thereby effectively enhancing its performance. [Display omitted] • The Hf 6 Ta 2 O 17 (HTO) nanofibres (NFs) are synthesized by electrospinning method. • The micro nanostructures and electrochemical property of HTO NFs can be designed by controlling the synthesis temperature. • The carbothermal treatment carried under Ar atmosphere is used to improve the amount of oxygen vacancies of HTO NFs. • The HTO NFs treated of 1 h (HTO/C-1) presents excellent capacitance of 925 F·g−1 at 1 A·g−1. • The r-HTO NFs//r-HTO NFs device shows high energy density of 73.3 Wh·kg−1 at power density of 1050 W·kg−1. [ABSTRACT FROM AUTHOR]
- Published
- 2023
- Full Text
- View/download PDF
20. Self-supporting NiO-coated activated carbon nanofibers based on atomic layer deposition for supercapacitor.
- Author
-
Yang, Xiaomeng, Cui, Yajiao, Qi, Yingyu, Fu, Luyan, Rezayan, Armin, Xu, Chunbao Charles, Wang, Jianshe, Sui, Dong, and Zhang, Yongsheng
- Subjects
- *
SUPERCAPACITORS , *SUPERCAPACITOR electrodes , *ATOMIC layer deposition , *CARBON nanofibers , *ACTIVATED carbon , *ENERGY density , *X-ray photoelectron spectroscopy - Abstract
The rapid development of consumer electronics, electric vehicles, and smart meters demands high-performance energy storage devices. By now, supercapacitors are expected to become one of the most promising energy devices for future energy technology. In this work, NiO nanoparticles supported on activated carbon nanofibers (NiO/ACNFs) have been synthesized by atomic layer deposition technique, which is directly used as self-supporting binder-free electrodes for supercapacitors. Scanning electron microscopy, transmission electron microscopy, X-ray photoelectron spectroscopy, and Raman results show that NiO nanoparticles (3.1 nm) are uniformly coated on ACNFs. The NiO/ACNFs-600 electrodes demonstrate a specific capacitance of 870 F·g−1 (1 A·g−1) and good rate capability (remain 67% at 10 A·g−1). The asymmetric supercapacitor devices with NiO/ACNFs-600//ACNFs electrodes yield a fairly high energy density of 39.85 Wh·kg−1 at 2000 W·kg−1 and excellent capacitance retention of 87% after 10,000 cycles. The excellent electrochemical capacitance performance for NiO/ACNFs is attributed to the high conductivity and large specific surface area of ACNFs, high capacity, small size, and even dispersion of NiO as well as the synergistic effect between them. These results demonstrate that NiO/ACNFs can serve as excellent electrode materials for high-performance asymmetric supercapacitors. [Display omitted] • NiO is dispersed evenly on lignin-derived ACNFs by ALD for the first time. • The oxygen-containing functional groups of ACNFs provide the active site for the anchoring of NiO. • Combined advantages of porous ACNFs and highly dispersed NiO nanoparticles. • NiO/ACNFs-600 electrode exhibits excellent specific capacitance of 870 F·g−1 (1 A·g−1). • NiO/ACNFs-600//ACNFs device yields outstanding energy density of 39.85 Wh·kg−1 at 2000 W·kg−1. [ABSTRACT FROM AUTHOR]
- Published
- 2023
- Full Text
- View/download PDF
21. Fabrication of hierarchical Co doped Ni3Se4 on ZIF-67 modified carbon nanofibers for high-performance hybrid supercapacitors.
- Author
-
Liu, Guangjun, Yan, Keling, Zhou, Fei, Wang, Ying, Zhuang, Changfu, Wang, Ce, and Tian, Di
- Subjects
- *
CARBON nanofibers , *SUPERCAPACITORS , *ENERGY density , *POWER density , *DOPING agents (Chemistry) , *LUMINESCENCE - Abstract
ZIF derived selenides have become a promising battery-type electrode material, but pure ZIF derived materials tend to agglomerate, averting active sites from full exposure. Herein, a hierarchical Co doped Ni 3 Se 4 on carbon nanofibers modified by ZIF-67 was fabricated by co-electrospinning, calcination and solvothermal synthesis, whose mass ratio of ZIF-67 to PAN and the type of chalcogenides were regulated. Among them, CNF-Co(1:1)@NiSe, with the feature of battery-type materials, displayed the large specific capacitance of 749.27 F g−1 at 0.5 A g−1 and superb rate performance when the current density increased from 0.5 to 10 A g−1, owing to its unique hierarchical structure along with synergistic effect of Co-doped Ni 3 Se 4 , Co-N-C, and CNF. Notably, a solid-state hybrid supercapacitor (CNF-Co(1:1)@NiSe//active carbon) was build, and delivered the maximum energy density of 32.36 Wh kg−1 at 1 A g−1 along with the maximum power density of 7999.99 W kg−1 at 10 A g−1. In addition, the supercapacitor exhibited excellent cycle stability during 5000 cycles and was successfully used for the luminescence of LED, revealing a good application prospect for CNF-Co(1:1)@NiSe. [ABSTRACT FROM AUTHOR]
- Published
- 2023
- Full Text
- View/download PDF
22. Designed formation of lignin-derived hollow particle-based carbon nanofibers for high-performance supercapacitors.
- Author
-
Zhou, Man, Wang, Ping, Yu, Yuanyuan, Ma, Wujun, Cai, Zaisheng, Ko, Frank, Li, Min, and Wang, Qiang
- Subjects
- *
CARBON nanofibers , *SUPERCAPACITOR electrodes , *ENERGY density , *SUPERCAPACITORS , *POROSITY , *POWER density , *CARBON fibers - Abstract
This work constructs a 1D hollow particle-based carbon nanofibers (HCNFs) derived from Zn-based metal-organic-frameworks (MOFs) particles embedded in biomass-based electrospinning nanofibers as high-performance supercapacitor (SC) electrodes. Abundant mesopores are introduced by the pyrolysis of MOFs, which generates uniformly distributed electrolyte storage pools for a fast electrolyte ions channel. Owing to its uniquely hierarchical pore structure, the derived HCNFs exhibit much enhanced supercapacitive performance. The prepared HCNF-1000 electrode has not only a high specific capacitance (229.6 F g−1 at a current density of 2 A g−1) but also good rate performance (176.8 F g−1 at 10 A g−1, 99.1 F g−1 at 30 A g−1). The two-electrode symmetrical system HCNF-SC has an energy density of 5.1 Wh kg−1 when the power density is 0.5 kW kg−1. HCNF-1000-based solid-state supercapacitor HCNF-FSC shows good electrochemical performance even in different folded states, displaying the potential application value for the development of portable wearable devices. [Display omitted] • The hollow lignin-derived carbon fibers (HCNFs) enhance electrolyte ion transfer. • The rate capability is improved by the abundantly hierarchical pores of HCNFs. • The flexible HCNF-FSC shows promising potential in powering wearable electronics. [ABSTRACT FROM AUTHOR]
- Published
- 2023
- Full Text
- View/download PDF
23. Slit needleless electrospun heteroatoms-doped hollow porous carbon nanofibers for solid-state flexible supercapacitors.
- Author
-
Zhang, Xunlong, Yan, Guilong, Li, Han, Li, Zhenyu, Chen, Jingyu, Wang, Li, and Wu, Yuanpeng
- Subjects
- *
CARBON nanofibers , *SUPERCAPACITOR electrodes , *SUPERCAPACITORS , *ENERGY storage , *DOPING agents (Chemistry) , *SURFACE area , *ELECTRIC capacity - Abstract
Flexible electrode materials play an important role in flexible portable energy storage devices. Carbon-based nanofiber has attracted numerous attentions due to its advantages on flexibility, safety, and reliability. Herein, we reported a novel and simple method to fabricate nitrogen-boron co-doped hollow porous carbon nanofiber (HPCNF) membranes as flexible supercapacitor electrodes. The higher specific surface area (413.98 m2/g) of HPCNF and the co-doping of N and B resulted in a high specific capacitance of 200.2 F/g (0.1 A/g). After 3000 cycles, NB-HPCNF still maintained high capacitance retention (104.81%). This study provides a new idea for electrochemical energy storage, which is beneficial to the deeper development of portable flexible devices. [Display omitted] • A novel and simple method was used to fabricate nitrogen-boron co-doped hollow porous carbon nanofiber membranes. • The well-developed hollow channels facilitated fast and efficient charge transport in carbon nanofibers. • A solid-state symmetric supercapacitor has good electrochemical properties and good mechanical stability. [ABSTRACT FROM AUTHOR]
- Published
- 2023
- Full Text
- View/download PDF
24. Laser carbonization of lignin-based fiber membranes with heating treatment for flexible supercapacitors.
- Author
-
Huang, Fei, Zhou, Sikun, Yan, Ziyang, Wang, Sha, Zhang, Hong, Wang, Shutong, and Zhou, Shouhuan
- Subjects
- *
HEAT treatment , *SUPERCAPACITOR electrodes , *SUPERCAPACITOR performance , *SUPERCAPACITORS , *CARBONIZATION , *ENERGY density , *CARBON nanofibers - Abstract
[Display omitted] • Direct laser writing carbonization and heating treatment are used to manufacture carbon fibers. • Heat treatment can increase the specific surface area of carbonized lignin fiber. • A flexible supercapacitor constructed of carbon fibers has the qualities of being light, thin, and breathable. Electrode materials significantly impact supercapacitor performance and developing high-performance electrode materials is crucial in energy storage. Commonly used laser-induced electrode materials are currently limited by severe contamination and hard-to-change intrinsic properties. This paper proposes a method for fabricating high-performance supercapacitors by laser carbonizing the lignin composite fiber membranes with heating treatment. Lignin fiber can achieve superior tensile strength, stiffness, and carbonization degree under suitable heat treatment temperatures. Heat treatment at 450 °C has been proven to be the ideal temperature for supercapacitor performance. At a current density of 1 A/g, the supercapacitor can reach the highest specific capacitance of ∼391.2F/g. In addition, doping MoS 2 boosted the device's performance to a specific capacitance of ∼527.8F/g, a power density of ∼500 W/kg, and an energy density of ∼73 Wh/kg at the same current density. In addition, lignin fibers are ideal materials in electronic textiles due to their soft, thin, and breathable properties. This study provides supportive evidence and technical guidance for improving the performance of flexible wearable supercapacitors. [ABSTRACT FROM AUTHOR]
- Published
- 2023
- Full Text
- View/download PDF
25. SiO2 anchored stacked-petal structure CoO-NiO/CNF as electrodes for high-rate-performance supercapacitors.
- Author
-
Jia, Jia, Qin, Zhihong, Yang, Xiaoqin, Peng, Xiaoxue, Ren, Guohang, and Lin, Zhe
- Subjects
- *
SUPERCAPACITOR electrodes , *SUPERCAPACITORS , *TRANSITION metal oxides , *CARBON nanofibers , *ENERGY density , *POWER density , *ELECTRODES - Abstract
The composites of transition metal oxide and carbon nanofibers (CNF) are promising electrode materials for supercapacitors in alkali solutions. However, the weak binding and unsatisfactory rate performance limit their application. To improve the weak binding, this study prepared the SiO 2 -modified carbon nanofibers (Si 1 -C) via electrospinning. Then the fully encapsulated CoO-NiO (NiCo@Si 1 -C) was fabricated on Si 1 -C by solvent-thermal and calcination. As is revealed, CNF containing SiO 2 is conducive to forming a full coverage of CoO-NiO coating with a stacked petal structure. More importantly, nano-SiO 2 plays the anchoring role of NiO-CoO and CNF, making the combination more firmly. The NiCo@Si 1 -C delivers a specific capacitance of 518.1 F g−1 at 0.5 A g−1, almost 2.25 times that of NiCo@Si 0 -C (229.9 F g−1 at 0.5 A g−1). When the current density increases to 50 A g−1, it is only 3.9 % lower than the capacitance (497.9 F g−1), which means a high rate performance. Moreover, asymmetric supercapacitor devices are assembled with activated carbon (NiCo@Si 1 -C//AC) with an energy density of 11.7 Wh kg−1, even at a high power density of 14,000.7 W kg−1. [Display omitted] • Nano-SiO 2 plays the anchoring role of NiO-CoO and CNF, making the combination more firmly. • The NiCo@Si 1 -C has a unique all-encapsulated CoO-NiO with a stacked petals structure. • The NiCo@Si 1 -C has ultra-high rate performance. [ABSTRACT FROM AUTHOR]
- Published
- 2023
- Full Text
- View/download PDF
26. Hydrodynamic cavitation-assisted preparation of porous carbon from garlic peels for supercapacitors.
- Author
-
Xuan, Xiaoxu, Wang, Mengjie, You, Weibin, Manickam, Sivakumar, Tao, Yang, Yoon, Joon Yong, and Sun, Xun
- Subjects
- *
CARBON nanofibers , *SUPERCAPACITORS , *GARLIC , *AMORPHOUS carbon , *ENERGY density , *ENERGY storage - Abstract
• HC is used to prepare porous carbon for SCs for the first time. • A SSA of 3272 m2/g with a capacitance of 227 F/g is maximumly achieved. • HC/KOH treatment doubles the performance of SCs compared with sole KOH activation. • HC is a potential preparation method of porous carbon with high efficiency. Hydrodynamic cavitation (HC), which can effectively induce sonochemical effects, is widely considered a promising process intensification technology. In the present study, HC was successfully utilized to intensify the alkali activation of GPs for SCs, for the first time. Five BDCMs were synthesized following the method reported in the literature. For comparison, four more BDCMs with HC-treated, among which a sample was further doped with nitrogen during the HC treatment, were prepared. Then all the samples were compared from microscopical characteristics to electrochemical performance as SCs materials. The morphology study demonstrated that the HC treatment had created many defects and amorphous carbon structures on the GP-based BDCMs, with the highest SSA reaching 3272 m2/g (1:6-HCGP), which 32 folded that of the Raw carbon sample's. The HC treatment also intensified the N-doping process. XRD and XPS results manifested that the N content had been increased and consequently changed the electronic structure of the carbon atoms, leading to the increase of specific capacitance (1:6-HCGP+N-based SC, 227 F/g at 10 A/g). The cycle performance proved that the GP-based BDCMs have long-term stability, indicating that the HC-treated BDCMs were good choices for energy storage technologies. Compared with the ultrasound-assisted method, which may have a high energy density, the HC-assisted method enables high production and energy efficiency. This work is a first time attempt towards the industrial application of HC method in energy-related materials synthesis and encourages more in-depth studies in the future. [ABSTRACT FROM AUTHOR]
- Published
- 2023
- Full Text
- View/download PDF
27. High-porosity carbon nanofibers prepared from polyacrylonitrile blended with amylose starch for application in supercapacitors.
- Author
-
Wang, He, Wang, Hongjie, Ruan, Fangtao, Feng, Quan, Wei, Yuhui, and Fang, Jian
- Subjects
- *
AMYLOSE , *POLYACRYLONITRILES , *STARCH , *SUPERCAPACITORS , *ELECTRODE performance , *POROUS polymers , *ENERGY density , *CARBON nanofibers , *SUPERCAPACITOR electrodes - Abstract
Porous carbon nanofibers (PCNFs) have been the hotpot material for supercapacitor due to their porous structure, outstanding conductivity, excellent electrochemical properties, and high specific surface area. The template method is a facile approach to prepare PCNFs through blending a thermally decomposable substance, subsequently heating treatment. High amylose starch (HAS) is a natural carbohydrate including carbon, hydrogen and oxygen elements. Herein, a simple template method utilizing HAS as the sacrificial polymer to prepare porous carbon nanofibers with high specific surface areas has been reported. The resulted carbon nanofibers have a hierarchical micro/meso porous structure with high level of microporous pores, more importantly, their specific surface area can reach 1204 m2 g−1. The electrochemical performances of PCNFs electrodes are studied using a three-electrode system and button-type devices. The specific capacitance of carbon nanofiber electrode is 344 F g−1 at 1.0 A g−1 when 20 wt% HAS is added. The cycling durability of corresponding device is 99.9% capacitance retention after 10000 cycles. And the maximum energy density of 12 Wh kg−1 is obtained at a lower power density of 125 W kg−1. As a green natural material, HAS may provide a low-cost solution to prepare high-performance carbon nanofibers for energy storage applications. [Display omitted] • An in-situ activation method is used to prepare hierarchical micro/meso porous carbon nanofibers. • High amylose starch can be as a sacrificial polymer to prepare carbon nanofiber with a high specific surface area. • Supercapacitor electrodes prepared from the carbon nanofibers show large specific capacitance and excellent durability. [ABSTRACT FROM AUTHOR]
- Published
- 2023
- Full Text
- View/download PDF
28. Green H2O2 activation of electrospun polyimide-based carbon nanofibers towards high-performance free-standing electrodes for supercapacitors.
- Author
-
Yan, Bing, Zheng, Jiaojiao, Feng, Li, Zhang, Qian, Han, Jingquan, Hou, Haoqing, Zhang, Chunmei, Ding, Yichun, Jiang, Shaohua, and He, Shuijian
- Subjects
- *
SUPERCAPACITORS , *CARBON nanofibers , *SUPERCAPACITOR electrodes , *POROUS materials , *CARBON electrodes , *ELECTRODES , *POROSITY - Abstract
Free-standing carbon nanofibrous membranes are prepared by carbonization and H 2 O 2 activation of electrospun polyimide nanofibrous membranes. The green and facile H 2 O 2 activation method not only regulates the pore structure of carbon nanofibers but also introduces rich oxygen species, rendering a hierarchically porous and heteroatom-doped carbon electrode for supercapacitors. The optimal electrode (PI800-8) shows a high specific capacitance of 339.9 F g−1 (0.5 A g−1, 6 M KOH electrolyte) and excellent cycle durability with a capacitance retention of 98.4 % after 50,000 cycles (5 A g−1). Particularly, a non-aqueous symmetric supercapacitor assembled with 1 M Et 4 NBF 4 electrolyte shows a high operating voltage of 2.8 V, and delivers the maximum energy/power density of 37.3 Wh kg−1 and 28.0 kW kg−1, respectively. The H 2 O 2 activation method provides a green, efficient, and versatile strategy to improve the pore properties and chemical compositions of porous carbon materials towards energy applications. [Display omitted] • The N/O-codoped carbon nanofibrous membranes were prepared by commercial electrospun polyimide nanofibrous membranes. • The green H 2 O 2 activation was proposed to ameliorate the pore and chemical properties of carbon nanofibrous membranes. • Excellent comprehensive performance was presented for both aqueous/non-aqueous symmetric supercapacitor. [ABSTRACT FROM AUTHOR]
- Published
- 2022
- Full Text
- View/download PDF
29. Facile and low-cost fabrication of interconnected hierarchically porous carbon for high-performance supercapacitors.
- Author
-
Yang, Xiaoxia, Wang, Fei, Li, Xi, Zhang, Zhuangzhuang, Wang, Chuantao, Yang, Chunming, Zhen, Yanzhong, Wang, Danjun, Fu, Feng, and Chi, Ru'an
- Subjects
- *
SUPERCAPACITORS , *CARBON nanofibers , *SUPERCAPACITOR electrodes , *COAL tar , *SUPERCAPACITOR performance , *AQUEOUS electrolytes , *POROUS electrodes , *ENERGY storage - Abstract
Construction of hierarchically porous carbon electrode materials is considered as an efficient strategy for improving the performance of supercapacitors. Nevertheless, how to precisely control the pore structure for preferable improvement the capacitance performance and fabricate in a cost-efficient way is still a scientific challenge. In this paper, an industrial by-product of coal tar pitch is used as precursor to prepare interconnected hierarchically porous carbons, with another domestic waste of eggshell as a pore-forming template and an inner-activator, combined with KOH in-situ activation. The as-prepared porous carbons exhibit large specific surface area (S BET , 1398–2103 cm2 g−1), well-developed interconnected hierarchically architecture, and excellent electrochemical performance. Among them, the optimal TS-PCE-4 based symmetric supercapacitor possesses a high capacitance of 238 F g−1 at 0.5 A g−1 with an excellent rate capability, exhibits long cycle stability with capacitance retention of 95.85 % after 10,000 cycles, and delivers energy densities of 8.27–5.47 Wh kg−1 at power density in the range of 125–4925 W kg−1 in 6 M KOH aqueous electrolyte. This work offers a facile and low-cost route to construct interconnected hierarchically porous carbons for energy storage devices. [Display omitted] • An industrial by-product of coal tar pitch was used to fabricate the hierarchically porous carbons via a facile route. • The domestic waste of eggshell was served as a pore-forming template and an inner-activator. • The carbons show large specific surface area and well-developed interconnected hierarchically porous architecture. • The optimum sample displays outstanding supercapacitor performance. [ABSTRACT FROM AUTHOR]
- Published
- 2022
- Full Text
- View/download PDF
30. The hybrid structure of nanoflower-like CoxMnyNizO4 nanoparticles embedded biomass-lignin carbon nanofibers as free-standing and binder-free electrodes for high performance supercapacitors.
- Author
-
Panith, Pasinee, Butnoi, Pichitchai, and Intasanta, Varol
- Subjects
- *
ELECTRODE performance , *NANOFIBERS , *CARBON nanofibers , *OXIDATION states , *NANOPARTICLES , *MANGANESE oxides , *SUPERCAPACITORS , *METALLIC oxides - Abstract
We introduced the concept of a novel hybrid faradaic structure as a mechanism to improve the performance of biomass-derived carbon-based supercapacitors (SCs). Organic-inorganic hybrid composition, nanostructures, porosity, surface area and active redox reactions were carefully designed. We reported the facile, cost-effective and environmentally friendly fabrication of pure lignin carbon nanofibers (LCNFs) incorporated with flower-like, multi-metal and intrinsically capacitive (Ni-Co@MnO 2) nanoparticles in a flexible and binder-free electrode for SCs by the electrospinning technique using various electrolytes (1 M Na 2 SO 4 , 0.5 M KI and 1 M Na 2 SO 4 +0.5 M KI). Mechanically robust LCNFs were used as a free-standing electrode and characterized for electrochemical performance using a two-electrode system in a Swagelok cell. Specific capacitance of the LCNFs in 1 M Na 2 SO 4 electrolyte (current density 0.1 A/g) of 129 F/g increased to 200 F/g when adding 1 % manganese oxide nanoparticles that introduced intrinsic capacitance into the nanofibers. This value further increased to 303 F/g by adding 1 % Ni-Co to the manganese oxide. The nanoflower morphology significantly increased the surface area via micro and mesopore modification on carbonization and via macropore expansion on activation. After applying a mixed electrolyte (1 M Na 2 SO 4 + 0.5 M KI), the capacitance reached 400 F/g and remained stable up to 1000 GDC cycles. Using the same composite nanofibers, 1,021 F/g was achieved using 0.5 M KI as an electrolyte. However, the latter system appeared unstable beyond 200 GDC cycles, suggesting that it can be applied as a disposable fast-charge supercapacitor. In the presence of a chemically-stable, highly-porous and partially-conductive carbon matrix, we concluded that interplay between the multi-metal oxides and electrolytes increased oxidation numbers, thereby boosting the faradaic reaction and enhancing electronic conductivity. [Display omitted] • EDLC carbon-based supercapacitor was fabricated from flower-like Ni-Co@MnO 2 nanoparticles and biomass lignin. • The unique metal oxide nanostructure led to highly-porous carbon nanofibers with unblocked micro-, meso- and macropores. • Mixed electrolyte of Na 2 SO 4 and KI led to capacitance of 400 F/g up to 1000 GDC cycles. • With KI as electrolyte, capacitance of 1,021 F/g was achieved and stable up to 200 GDC cycles. [ABSTRACT FROM AUTHOR]
- Published
- 2022
- Full Text
- View/download PDF
31. One-dimensional hierarchical porous carbon nanofibers with cobalt oxide in a hollow channel for electrochemical applications.
- Author
-
Kim, Guetae and Kim, Bo-Hye
- Subjects
- *
COBALT oxides , *CARBON nanofibers , *SUPERCAPACITOR electrodes , *ELECTROACTIVE substances , *SUPERCAPACITORS , *ELECTRODE performance , *ELECTRON transport - Abstract
One-dimensional hierarchical porous carbon nanofibers (CNFs) embedded with Co 3 O 4 nanoparticles in a hollow channel (PPMCo) are fabricated by coaxial electrospinning followed by thermal treatment. The degree to which the CNF surface is exposed to Co 3 O 4 nanoparticles was controlled by the cobalt(II) acetate concentration. The well-controlled structure of PPMCo with porous structure, heteroatoms, and amorphous Co 3 O 4 nanoparticles provided fast ion transport and large reaction surface area, resulting in effective ion migration to the active site and a high rate capacity of the electrode. Benefitting from the unique structure, the PPMCo supercapacitor electrodes displays a high specific capacitance of 188 Fg−1 at 1 mAcm−2, rate capability of 82% when the current density is increased from 1 to 20 mAcm−2, and cycling stability of 93% for 10,000 cycles. The good capacitive performance of the PPMCo electrode is attributed to the synergistic effect of the hierarchical porosity, electroactive material of Co 3 O 4 , high effective surface area, and polar effects by heteroatoms. [Display omitted] • Hierarchical porous CNF embedded with Co3O4 was prepared by coaxial electrospinning. • The degree of CNF exposed to Co3O4 was controlled by the Co(OAc)2 concentration. • The hollow core of the core part provides a fast electron transport channel. • Amorphous Co3O4 helps transport ions by reducing the charge transfer resistance. • The heteroatom functional groups on the carbon surface enhance the pseudocapacitance. [ABSTRACT FROM AUTHOR]
- Published
- 2022
- Full Text
- View/download PDF
32. Review of recent progress in electrospinning-derived freestanding and binder-free electrodes for supercapacitors.
- Author
-
Joshi, Bhavana, Samuel, Edmund, Kim, Yong-il, Yarin, Alexander L., Swihart, Mark T., and Yoon, Sam S.
- Subjects
- *
CARBON nanofibers , *METAL-organic frameworks , *SUPERCAPACITORS , *ELECTRODES , *ENERGY storage , *ELECTRONIC equipment , *OXIDE electrodes - Abstract
• The review focuses on potential of flexible, freestanding binder-free nanofiber electrodes for real time applications. • The advancement of the hollow/porous composite nanofibers, and process parameters are presented. • Morphology engineering over composite nanofibers for enhancing electrochemical performance is reviewed. • Current challenges and future prospect of binder free composite nanofibers for flexible SCs are suggested. The versatile electrospinning technique is scalable and suitable to fabricate highly conducting freestanding carbon nanofiber composite electrodes for energy storage devices. Freestanding/flexible electrodes hold enormous potential for use in wearable electronic devices. Carbon-yielding polymers and the optimal use of sacrificial polymers, metal oxides, and sulfides retain the flexibility and enhance the surface area and pseudocapacitance of electrodes. Both as-prepared electrospun fibers and carbonized nanofibers are compatible with surface decoration via various chemical and electrochemical routes. Metal oxides/sulfides with various morphologies, such as nanocones and nanosheets, can be grown on the carbon nanofibers or on the as-prepared electrospun fibers using chemical synthesis methods such as electrodeposition, hydrothermal processes, and chemical impregnation to enhance the pseudocapacitance of the electrodes. Similarly, the deposition of metal organic frameworks on as-prepared electrospun fibers embellishes these fibers with nanostructures of specific morphologies such as dodecahedral and spindle-shaped structures. Under optimal conditions, these morphologies do not hamper the flexibility of the fibers, and binders are not required to retain them or maintain the electrode integrity. The engineering of electrodes with various morphologies and process parameters is presented systematically. Electrospinning-derived electrodes that have demonstrated significant electrochemical performance are highlighted and critically analyzed, and the energy storage mechanisms of these supercapacitors are described in detail. [ABSTRACT FROM AUTHOR]
- Published
- 2022
- Full Text
- View/download PDF
33. Highly flexible, freestanding supercapacitor electrodes based on hollow hierarchical porous carbon nanofibers bridged by carbon nanotubes.
- Author
-
Zhu, Jianhua, Zhang, Qian, guo, Lefan, Zhao, Yanjiao, Zhang, Ruiyun, Liu, Lifang, and Yu, Jianyong
- Subjects
- *
SUPERCAPACITORS , *CARBON nanofibers , *CARBON nanotubes , *SUPERCAPACITOR electrodes , *ENERGY density , *POWER density , *ENERGY storage - Abstract
[Display omitted] • The fancy carbon nanofibers (CNFs) were prepared via coaxial electrospinning and carbonization. • The CNFs featured hollow and hierarchical porous structure. • The bridging structure formed by the carbon nanotubes (CNTs) endowed the CNFs with outstanding flexibility. • The CNFs decorated with polyaniline showed good electrochemical performance. • The assembled device could successfully power the electronics. Supercapacitors are considered to be the next generation of wearable energy storage devices because of reliable safety, high power density, and long cycle life, but the flexibility and energy density limit their practical applications. Herein, the flexible hollow hierarchical porous carbon nanofibers bridged by carbon nanotubes (HPCNFs@CNTs) are designed and constructed, followed by polyaniline (PANI) decorating to fabricate PANI@HPCNFs@CNTs. The synergistic effect of the hollow structure, hierarchical pores, in-situ nitrogen doping, and the bridging structure endows the HPCNFs@CNTs with a high specific capacitance of 461.0F g−1 (207.4 mF cm−2) while maintaining glorious flexibility under various deformation states. Besides, PANI@HPCNFs@CNTs possesses a high specific capacitance of 629.1F g−1 (405.2 mF cm−2) and remarkable cycle stability with 88.5 % capacitance retention after 5000 charging-discharging cycles. The device assembled by PANI@HPCNFs@CNTs renders an ultra-high energy density of 23.3 Wh kg−1 at a power density of 202.7 W kg−1. Furthermore, the device provides remarkable cycle stability and high-rate capability with a capacity retention of 91.3 % after 5000 cycles at 5 A g−1 and 76.7 % at 10 A g−1, respectively, demonstrating a tremendous potential to construct high-performance flexible energy storage devices. [ABSTRACT FROM AUTHOR]
- Published
- 2022
- Full Text
- View/download PDF
34. Design of Zn0.76Co0.24S nanoparticles anchored to orthohexagonal Co3S4 nanosheets for high-performance asymmetric supercapacitors.
- Author
-
Zhang, Wenjun, Fu, Hao, Zhou, Ting, Hao, Yonghao, Wang, Zhongbing, and Chen, Chunnian
- Subjects
- *
NANOSTRUCTURED materials , *ENERGY storage equipment , *SUPERCAPACITORS , *CARBON nanofibers , *PROBLEM solving , *ENERGY density , *NANOCOMPOSITE materials - Abstract
The design of nanocomposite materials with special stable structure has become the consensus of researchers working on the exploitation of new materials for effective energy storage equipment. Herein, for the purpose of solving the problem of low capacity and short cycle life of the materials used for supercapacitors, we use Co 3 (VO 4) 2 with orthohexagonal nanosheet structure as the transition template, utilizing ion exchange reaction to prepare Co 3 S 4 with a two-dimensional structure. At the same time, the surface of Co 3 S 4 nanosheets were anchored by some Zn 0.76 Co 0.24 S nanoparticles through hydrothermal reaction. The prepared Co 3 S 4 /Zn 0.76 Co 0.24 S composite displays a satisfactory specific capacitance of 1832.1 F g−1 at a current density of 1 A g−1 and an outstanding conductivity. After 4000 times of continuous charge and discharge cycles, it still presents a good capacitance (94.6% retention). The tests on the assembled Co 3 S 4 /Zn 0.76 Co 0.24 S//AC device show an energy density of 55.6 Wh kg−1, while the power density is 690.9 W kg−1. With such a remarkable electrochemical performance, the prepared Co 3 S 4 /Zn 0.76 Co 0.24 S composite is considered as an excellent candidate for supercapacitors application. [ABSTRACT FROM AUTHOR]
- Published
- 2022
- Full Text
- View/download PDF
35. Achieving ion accessibility within graphene films by carbon nanofiber intercalation for high mass loading electrodes in supercapacitors.
- Author
-
Zhang, Ran, Yan, Jiawei, Wang, Lei, Shen, Wenzhuo, Zhang, Jiali, Zhong, Min, and Guo, Shouwu
- Subjects
- *
CARBON films , *CARBON nanofibers , *GRAPHENE , *SUPERCAPACITORS , *ENERGY density , *ELECTRODES , *IONIC structure - Abstract
Achieving high specific surface area and ion accessibility in graphene-based electrodes with a high mass loading for supercapacitors poses a significant challenge because strong π-π stacking of graphene sheets often blocks the access of electrolyte ions to active sites. Herein, we report a novel protocol to prepare free-standing laminated graphene/carbon nanofiber films as high areal mass-loading electrodes through a layer-by-layer electrospinning technique. The unique laminated structure of graphene/carbon nanofiber thin films can enhance electrolyte penetration and increase transportations of ions/electrons. The symmetric supercapacitors (SCs) using the as-obtained graphene/carbon nanofiber films as electrodes reach areal specific capacitance of 1536 mF cm−2 at a current density of 1 mA cm−2. Most importantly, the areal energy density of the SCs can reach 0.22 mWh cm−2 at a power density of 1 mW cm−2 with a high areal mass loading of 24 mg cm−2. The exceptional electrochemical properties of the laminated graphene/carbon nanofiber films render them promising materials for electrodes in SCs. [Display omitted] • Laminated graphene/CNFs were prepared via layer-by-layer electrospinning. • The unique laminated structure enhances ions accessibility at high mass loading. • The assembled symmetric supercapacitor exhibits high areal specific capacitance. [ABSTRACT FROM AUTHOR]
- Published
- 2021
- Full Text
- View/download PDF
36. Effects of Precursors and Carbon Nanotubes on Electrochemical Properties of Electrospun Nickel Oxide Nanofibers-Based Supercapacitors.
- Author
-
Aihemaitituoheti, Reziwanguli, Alhebshi, Nuha A., and Abudula, Tuerdimaimaiti
- Subjects
- *
NICKEL oxide , *SUPERCAPACITORS , *ELECTRODE performance , *SUPERCAPACITOR performance , *CARBON nanotubes , *CARBON nanofibers , *SUPERCAPACITOR electrodes , *SINGLE walled carbon nanotubes - Abstract
Supercapacitors have been considered as one of the main energy storage devices. Recently, electrospun nanofibers have served as promising supercapacitor electrodes because of their high surface area, high porosity, flexibility, and resistance to aggregation. Here, we investigate the effects of electrospinning parameters and nickel precursors on the nanostructure of electrospun nickel oxide (NiO), as well as on their electrochemical performance as supercapacitor electrodes. In contrast to the case of using nickel nitrate, increasing the nickel acetate molar concentration maintains the flexible fibrous sheet morphology of the as-spun sample during the polycondensation and calcination of NiO. As a result, our flexible electrode of NiO nanofibers derived from nickel acetate (NiO-A) exhibits much better electrochemical performance values than that of nickel nitrate-derived NiO. To further improve the electrochemical storage performance, we combined NiO-A nanofibers with single-walled carbon nanotubes (CNTs) as a hybrid electrode. In both half-cell and full-cell configurations, the hybrid electrode displayed a higher and steadier areal capacitance than the NiO-A nanofibers because of the synergetic effect between the NiO-A nanofibers and CNTs. Altogether, this work demonstrates the potency of the hybrid electrodes combined with the electrospun NiO-A nanofibers and CNTs for supercapacitor applications. [ABSTRACT FROM AUTHOR]
- Published
- 2021
- Full Text
- View/download PDF
37. Rational design of ZIF-8 assimilated hierarchical porous carbon nanofibers as binder-free electrodes for supercapacitors.
- Author
-
Sun, Yao, Xue, Jianjun, Li, Zhiwei, Ding, Bing, An, Yufeng, Zang, Shuai, Dou, Hui, Jiang, Jiangmin, and Zhang, Xiaogang
- Subjects
- *
CARBON nanofibers , *ENERGY density , *SUPERCAPACITORS , *SUPERCAPACITOR electrodes , *CARBON fibers , *ELECTRODES , *ELECTRODE potential - Abstract
[Display omitted] • An eco-friendly yet facile approach is proposed to fabricate nano porous fibers. • The porous carbon fibers exhibit satisfactory electrochemical performance. • A high-performance supercapacitor is constructed. Recently, tremendous attention has been paid to carbon-based fibers, particularly porous carbon fibers (PCFs), because of their great potential as electrodes for advanced supercapacitors (SCs). However, the relatively complex preparation and monotonous pore structure are still the most important challenge that PCFs needs to counter. In this work, an eco-friendly yet facile approach has been applied to synthesis PCFs with tunable multi-level pores and satisfactory electrochemical performance. By using the combinations of electrospinning technology, hard-template method and carbonization process, nanofibers with interconnected multi-level pores can be achieved. It is demonstrated that the pore engineered PCF possesses enhanced electrochemical performance. For instance, the PCF electrode possesses a high capacitance of 211 F g−1 in 6 mol L−1 KOH at a density of 0.5 A g−1 together with excellent rate capability. Meanwhile, a high areal capacitance of 1.2 F cm−2 also can be achieved at a mass loading of 10 mg cm−2. Additionally, symmetrical supercapacitor assembled by PCF electrodes exhibits good capacitance of 101.9 F g−1 at the current density of 0.5 A g−1, such device also can deliver an energy density up to 60.1 Wh kg−1 with ionic liquid electrolyte. [ABSTRACT FROM AUTHOR]
- Published
- 2021
- Full Text
- View/download PDF
38. Integration of RuO2/conductive fiber composites within carbonized micro-electrode array for supercapacitors.
- Author
-
Huang, Mao-Jung, Chen, Wen-Hsi, Cheng, Chia, Chen, Shin-Rung, Lin, Jeng-Yu, and Yang, Chii-Rong
- Subjects
- *
SUPERCAPACITOR electrodes , *SUPERCAPACITORS , *FIBROUS composites , *ENERGY density , *COMPOSITE materials , *CARBON nanofibers , *MICROELECTROMECHANICAL systems - Abstract
• Micro-electrode arrays were fabricated on a graphite substrate using lithography and carbonization. • Conductive fibers produced via electrospinning and carbonization were decorated with RuO 2 particles. • The 3D micro-electrodes were used in fabrication of all - carbon symmetric supercapacitors. • The specific capacitance reached 219.2 F g−1 at a current density of 1 A g−1 in 1 M H 2 SO 4 electrolyte. [Display omitted] This study employed a carbon microelectromechanical system (C-MEMS) in fabricating a 3D micro-electrode array of conductive carbon cylinders directly on the surface of a graphite substrate. The capacitance of the array was further enhanced by decorating it with a composite material comprising highly-porous carbon nanofibers (CF) and electroactive RuO 2 nanoparticles to function as an active electrode. In galvanostatic charge-discharge tests, the specific capacitance of an electrode decorated with RuO 2 30 wt%/CF was 219.2 F g−1 at a current density of 0.5 A g−1, which is 2.27 times higher than that of the pristine CF electrode. When the current density was increased from 0.5 A g−1 to 3 A g−1, the capacitance retention of the RuO 2 30 wt%/CF electrode was 54.8%. A symmetric supercapacitor based on the RuO 2 30 wt%/CF composite electrode exhibited an impressive energy density of 74.2 Wh kg−1 with power density of 4333 W kg−1. It also demonstrated good capacitance retention of 80.2% following 3000 consecutive charge/discharge cycles at a current density of 2 A g−1. [ABSTRACT FROM AUTHOR]
- Published
- 2021
- Full Text
- View/download PDF
Catalog
Discovery Service for Jio Institute Digital Library
For full access to our library's resources, please sign in.