6 results on '"Đorđević, Antonije"'
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2. Morphological and structural characterization of MgAl2O4 spinel
- Author
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Obradović Nina, Filipović Suzana, Fahrenholtz William G., Marinković Bojan A., Rogan Jelena, Lević Steva, Đorđević Antonije, and Pavlović Vladimir B.
- Subjects
spinel ,mechanical activation ,sintering ,structure ,Chemical technology ,TP1-1185 - Abstract
Magnesium aluminate has the spinel structure along with good mechanical, chemical, and thermal properties. Magnesium aluminate has a wide range of applications including refractory ceramics, optically transparent ceramic windows, and armors. Its low dielectric permeability and low loss tangent enable its applications for integrated electronic devices, as well. In this paper, MgO and Al2O3 powders were mixed in a one-to-one molar ratio and calcined at temperatures ranging from 1500 to 1800oC to produce phase pure spinel. Thereafter, pellets were crushed and treated in a planetary ball mill for 60 min to obtain a fine powder. All powders were examined for phase composition, crystal structure, and morphology. The obtained results showed that by increasing the temperature, samples with higher density were synthesized. Milling for 1 h led to formation of larger particles, but finer powders after milling. XRPD and Raman spectroscopy showed disorder in the crystal structure after milling.
- Published
- 2023
- Full Text
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3. Effect of the filler morphology on the crystallization behavior and dielectric properties of the polyvinylidene fluoride‐based composite.
- Author
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Filipović, Suzana, Obradović, Nina, Corlett, Cole, Fahrenholtz, William G., Rosenschon, Martin, Füglein, Ekkehard, Dojčilović, Radovan, Tošić, Dragana, Petrović, Jovana, Đorđević, Antonije, Vlahović, Branislav, and Pavlović, Vladimir B.
- Abstract
Ceramic/polymer composites can be chemically stable, mechanically strong, and flexible, which make them candidates for electric devices, such as pressure or temperature sensors, energy storage or harvesting devices, actuators, and so forth. Depending on the application, various electrical properties are of importance. Polymers usually have low dielectric permittivity, but increased dielectric permittivity can be achieved by the addition of the ceramic fillers with high dielectric constant. With the aim to enhance dielectric properties of the composite without loss of flexibility, 5 wt% of BaTiO3‐Fe2O3 powder was added into a polyvinylidene fluoride matrix. The powder was prepared by different synthesis conditions to produce core/shell structures. The effect of the phase composition and morphology of the BaTiO3‐Fe2O3 core/shell filler on the structure and lattice dynamics of the polymer composites was investigated. Based on the results of the thermal analysis, various parameters of ceramic/polymer composites were determined. Differences in the phase composition and morphology of the filler have an influence on the formation of various polyvinylidene fluoride allomorphs and the degree of crystallinity. Furthermore, the dielectric performances of pure polyvinylidene fluoride and the polymer/ceramic composites were measured. [ABSTRACT FROM AUTHOR]
- Published
- 2024
- Full Text
- View/download PDF
4. Spark plasma sintering of mechanically activated MGO-TiO2 system
- Author
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Filipović, Suzana, Obradović, Nina, Fahrenholtz, William G., Smith, Steven, Mirković, Miljana M., Peleš, Adriana, and Đorđević, Antonije
- Subjects
mechanical activation ,dielectric properties ,magnesium titanate ,spark plasma sintering ,hardness - Abstract
MgTiO3 is a material often used in different types of high-frequency capacitors, temperature compensating capacitors, and chip capacitors, so the enhancement of this material is still the focus of many research groups due to its remarkable dielectric properties. Outstanding features can only be achieved when the ceramics are highly dense. Densification of magnesium titanate by Spark Plasma Sintering (SPS) was the aim of this work. Magnesium titanate ceramics were prepared by applying mechanical activation as the first step. Powders prepared in this way were SPS sintered, at 1200 °C with a heating rate of 100 °C/min. After reaching the desired temperature, a uniaxial pressure of 50 MPa was applied. The dwell time at this condition was 5 min, followed by cooling to room temperature at 5°C/min. X-ray diffraction was performed in order to establish the phase composition of milled powders and obtained ceramics. Differences between samples milled in various times intervals, as well as sintered ceramics were examined by means of scanning electron microscopy (SEM) and energy dispersive spectroscopy (EDS). The presence of MgTiz0s phase was detected in XRD and was confirmed by EDS analysis for the non-milled ceramics. In the samples obtained from milled powders, no MgTi2O5 was detected in XRD patterns, but this phase was detected in EDS spectra in a lower amount. Dielectric measurements were performed at a wide range of frequencies, while the hardness of the SPS samples was measured at loads up to 10 N. The highest value of the hardness was obtained from powder milled for 15 min before SPS.
- Published
- 2022
5. Effect of high energy ball milling on sintering of MgO-TiO2 system
- Author
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Filipović, Suzana, Obradović, Nina, Fahrenholtz, William G., Smith, Steven, Mirković, M., Peleš, Adriana, Tadić, Nenad, and Đorđević, Antonije
- Subjects
ceramic materials ,MgTiO3 ,perovskites ,ball milling ,spark plasma sintering - Abstract
Perovskite ceramic material based on MgTiO3 is used in various types of electronic devices owing to its dielectric properties, high dielectric constant, and low losses. These features can be tailored by setting preparation conditions. Densification of magnesium titanate by Spark Plasma Sintering (SPS) was the aim of this work. First, the mechanical activation in the highenergy ball mill was applied on the powder of MgO-TiO2 mixed in mole ratio 1:1. Prepared powder mixtures, activated for different times, were SPS sintered, at 1200 o C with a heating rate of 100o C/min. After reaching the desired temperature, a uniaxial pressure of 50 MPa was applied, and dwelled at this condition for 5 min, followed by cooling to room temperature at 5o C/min. The starting powders, activated mixtures, and sintered ceramics bodies were investigated by X-ray diffraction, scanning electron microscopy (SEM), and energy dispersive spectroscopy (EDS). The presence of the MgTi2O5 phase was noticed for the nonmilled ceramics. In the samples obtained from milled powders, MgTi2O5 was detected in EDS spectra in a lower amount, below the threshold of the XRD method. Dielectric measurements were performed at a wide range of frequencies and temperatures. The highest value of the hardness was obtained from powder milled for 15 min before SPS. X Serbian Ceramic Society Conference - Advanced Ceramics and Application : new frontiers in multifunctional material science and processing : program and the book of abstracts; September 26-27, 2022; Belgrade
- Published
- 2022
6. Nonuniform helical antennas
- Author
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Dinkić, Jelena Lj., Đorđević, Antonije, Olćan, Dragan, Stevanović, Marija, Javor, Vesna, and Gvozdić, Dejan
- Subjects
antenna design, helical antennas, optimization, quad arrays of helical antennas ,дизајн антена, хеликоидалне антене, оптимизација, низови хеликоидалних антена - Abstract
The objective of this thesis is to systematically analyze and optimize nonuniformly-wound helical antennas, along with classical (uniform) helical antennas. The optimization of the nonuniform helical antennas has many degrees of freedom. Hence, the optimization space is large and the optimization task is challenging. It is shown that, in most practical cases, the optimal nonuniform helical antennas outperform the uniform helical antennas presented in the literature. It is also shown that the nonuniform helical antennas are the preferable choice when the losses are low or medium, whereas for high losses, the uniform helical antennas should be used. A large database is assembled from the optimization results, wherefrom a complete design procedure is developed for the nonuniform helical antennas. This procedure comprises all necessary equations and graphs for evaluating the optimal antenna parameters and estimating the antenna characteristics. The design procedure is verified experimentally, by measurements of a fabricated prototype. Quad (2 x 2) arrays of nonuniform helical antennas are also investigated. Their design procedure includes the optimization of single antennas along with their positions in the array. The solution of a real engineering problem is presented: a quad array that meets predefined specifications is designed and a prototype is fabricated and measured. Циљ ове тезе је систематична анализа и оптимизација неуниформно мотаних хеликоидалних антена, као и класичних (униформних) хеликоидалних антена. Оптимизација неуниформних хеликоидалних антена има много степени слободе. Стога је оптимизациони простор велики, а оптимизација изазован задатак. Показано је да, у највећем броју практичних случајева, оптималне неуниформне хеликоидалне антене надмашују по перформансама униформне хеликоидалне антене представљене у литератури. Осим тога, показано је да су неуниформне хеликоидалне антене бољи избор када су губици мали или средњи, док би у случају великих губитака требало користити униформне хеликоидалне антене. Резултати оптимизације чине велику базу података, на основу које је развијен поступак пројектовања неуниформних хеликоидалних антена. Овај поступак обухвата све потребне једначине и графике за одређивање оптималних параметара антена и процену карактеристика антена. Поступак дизајна је потврђен експериментално, мерењем карактеристика реализованог прототипа. Такође су испитивани низови од 2 x 2 неуниформне хеликоидалне антене. Процедура за њихов дизајн садржи оптимизацију засебних антена, као и оптимизацију положаја антена у низу. Представљено је и решење реалног инжењерског проблема: дизајниран је низ од 2 x 2 антене који испуњава унапред дефинисане спецификације, а прототип је направљен и измерен.
- Published
- 2021
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