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1. Validation of a post-radiolabeling bioconjugation strategy for radioactive rare earth complexes with minimal structural footprint

Author

Raphael Lengacher, Alexia G. Cosby, Dariusz Śmiłowicz, and Eszter Boros

Subjects
Materials Chemistry, Metals and Alloys, Ceramics and Composites, General Chemistry, Catalysis, Surfaces, Coatings and Films, Electronic, Optical and Magnetic Materials
Abstract

The nine-coordinate aza-macrocycle DO3Apic-NO2 and its kinetically inert rare earth complexes [M(DO3A-pic-NO2)]- (M = La, Tb, Eu, Lu, Y) can be readily bioconjugated to surface accessible thioles on peptides and proteins with a minimal structural footprint. All complexes express thioconjugation rate constants in the same order of magnitude (

Published
2022
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