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The morphology of dodecane in a nanopore at temperatures typical in exploited or depleted oil reservoirs is investigated using molecular dynamics simulation. The dodecane morphology is found to be determined by interactions between interfacial crystallization and surface wetting of the simplified oil, while "evaporation" only plays a minor role. The morphology changes from an isolated, solidified dodecane droplet to a film with orderly lamellae structures remaining within, and finally to a film containing randomly distributed dodecane molecules, as the system temperature increases. In a nanoslit under the impact of water, since water wins against oil in surface wetting on the silica surface due to electrostatic interaction induced hydrogen bonding between water and the silanol group of silica, the spreading of dodecane molecules over the silica surface is impeded by this water confinement mechanism. Meanwhile, interfacial crystallization is enhanced, leading to always an isolated dodecane "droplet," with crystallization weakening as the temperature increases. Since dodecane is immiscible to water, there is no mechanism for dodecane to escape the silica surface, and the competition of surface wetting between water and oil determines the morphology of the crystallized dodecane droplet. For the CO2–dodecane system in a nanoslit, CO2 is an efficient solvent for dodecane at all temperatures. Therefore, interfacial crystallization rapidly disappears. The competition of surface adsorption between CO2 and dodecane is secondary for all cases. The dissolution mechanism is a clear clue for the fact that CO2 is more effective than water flooding in oil recovery for a depleted oil reservoir. [ABSTRACT FROM AUTHOR]

The morphology of dodecane in a nanopore at temperatures typical in exploited or depleted oil reservoirs is investigated using molecular dynamics simulation. The dodecane morphology is found to be determined by interactions between interfacial crystallization and surface wetting of the simplified oil, while "evaporation" only plays a minor role. The morphology changes from an isolated, solidified dodecane droplet to a film with orderly lamellae structures remaining within, and finally to a film containing randomly distributed dodecane molecules, as the system temperature increases. In a nanoslit under the impact of water, since water wins against oil in surface wetting on the silica surface due to electrostatic interaction induced hydrogen bonding between water and the silanol group of silica, the spreading of dodecane molecules over the silica surface is impeded by this water confinement mechanism. Meanwhile, interfacial crystallization is enhanced, leading to always an isolated dodecane "droplet," with crystallization weakening as the temperature increases. Since dodecane is immiscible to water, there is no mechanism for dodecane to escape the silica surface, and the competition of surface wetting between water and oil determines the morphology of the crystallized dodecane droplet. For the CO2–dodecane system in a nanoslit, CO2 is an efficient solvent for dodecane at all temperatures. Therefore, interfacial crystallization rapidly disappears. The competition of surface adsorption between CO2 and dodecane is secondary for all cases. The dissolution mechanism is a clear clue for the fact that CO2 is more effective than water flooding in oil recovery for a depleted oil reservoir. [ABSTRACT FROM AUTHOR]

Underground H 2 storage (UHS) is a promising technology to achieve large-scale, long-term H 2 storage. Using CO 2 as a cushion gas to maintain the pressure of the reservoir and withdraw stored H 2 in the saline aquifer simultaneously enables the implementation of UHS and underground CO 2 storage (UCS). The difference in the molecular properties of CO 2 and H 2 leads to distinct interfacial behavior when in contact with the brine and rock, thereby affecting the flow patterns and trapping mechanisms of gases in geological formations. Accurate prediction of the interfacial properties of CO 2 , H 2 , and the mixtures when interacting with brine and rock is crucial to minimizing the uncertainties in UHS and UCS projects. In this study, molecular dynamics (MD) simulations are performed to predict the interfacial tension, surface excess, bubble evolution, and contact angle of CO 2 , H 2 , and the mixtures at 10 MPa and 300-400 K. The MD results show that the interaction of CO 2 with H 2 O and hydrophilic silica is considerably stronger than that of H 2 . The interfacial tension reduces linearly with the temperature in H 2 -dominated mixture systems, and the surface adsorption of H 2 can diminish in a CO 2 -dominated system or at high-temperature conditions. The hydrophilic silica is more CO 2 -wet than H 2 -wet, and the attached CO 2 bubble is more easily disconnected. Ions and the temperature play different roles in the contact angle., Competing Interests: The authors declare no competing financial interest., (© 2023 The Authors. Published by American Chemical Society.)

In this review, we provide a detailed coverage of multi-sensor fusion techniques that use RGB stereo images and a sparse LiDAR-projected depth map as input data to output a dense depth map prediction. We cover state-of-the-art fusion techniques which, in recent years, have been deep learning-based methods that are end-to-end trainable. We then conduct a comparative evaluation of the state-of-the-art techniques and provide a detailed analysis of their strengths and limitations as well as the applications they are best suited for.