Search

Your search keyword '"Barry M. Trost"' showing total 1 results
Start Over Author "Barry M. Trost" Publication Year Range Last 3 years

Refine your results

1 results on '"Barry M. Trost"'

1. ProPhenol Derived Ligands to Simultaneously Coordinate a Main-Group Metal and a Transition Metal: Application to a Zn-Cu Catalyzed Reaction

Author

Barry M. Trost, Guoting Zhang, Minghao Xu, and Xiaotian Qi

Subjects
Organic Chemistry, General Chemistry, Catalysis
Abstract

A new bifunctional ligand bearing chiral N-heterocyclic carbene (NHC) and prolinol moieties is presented. Utilizing the designed ligand, an in situ formed Cu/Zn hetero-bimetallic complex unlocks the asymmetric allylic alkylation reactions of allyl phosphates with zinc keto-homoenolates, leading to the formation of various γ-vinyl ketones with good regio- and enantio-selectivity. DF sT calculation supports that the chelation of allyl phosphates with catalyst promotes the S

Published
2021

Catalog

Books, media, physical & digital resources
See catalog results