1. Enhanced photocatalytic degradation of organic dyes by La3+ doped SrBi4Ti4O15.
- Author
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Zou, Lindun, Tian, Chun, Lin, Zhaoyang, Wang, Yuquan, Gu, Tianyi, Wang, Zuchun, Tang, Tao, and Shi, Hongqi
- Subjects
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ENVIRONMENTAL degradation , *ORGANIC dyes , *GENTIAN violet , *CONDUCTION bands , *POLLUTION - Abstract
The rampant misuse of organic dyes has exacerbated environmental pollution to an alarming degree. SrBi 4 Ti 4 O 15 , a layered perovskite semiconductor material, demonstrates considerable potential in the degradation of organic dyes, and efforts have been made to enhance its photocatalytic efficiency. In this study, La3+ doping was utilized to synthesize SrBi 4-x La x Ti 4 O 15 (x = 0, 0.10, 0.15, 0.25, 0.40) nanosheet photocatalysts, and their photocatalytic performance and underlying mechanisms were comprehensively investigated. XRD and Raman spectroscopy revealed that La3+ doping replaced Bi3+ at the A-site, resulting in a reduction of the interlayer spacing of [TiO 6 ] octahedra. Combined with DFT calculations, La3+ doping was found to widen the band gap of SrBi 4 Ti 4 O 15 and raise the Fermi level. Additionally, La3+ doping significantly increased the ratio of the Ti 3d component at the bottom of the conduction band, favoring the migration of photogenerated electrons along the [TiO 6 ] octahedra and accelerating the separation of photogenerated carriers. SEM and BET analyses revealed that La3+ doping not only increased the size of the nanosheets but also significantly enhanced their specific surface area, thereby exposing more active sites. Degradation experiments of Rhodamine B (Rh B) under UV light demonstrated that the photocatalytic efficiency of SrBi 3.75 La 0.25 Ti 4 O 15 (k = 0.0514 min-1) was 2.66 times higher than that of the original SrBi 4 Ti 4 O 15 (k = 0.0193 min-1). The theoretical degradation pathway of Rh B was elucidated using LC-MS analysis and the developmental toxicity of potential intermediates was analyzed. Moreover, the SrBi 3.75 La 0.25 Ti 4 O 15 photocatalyst also exhibited excellent degradation efficacy against Methylene Blue (MB), Crystal Violet (CV), and Methyl Orange (MO). This study provides both theoretical and experimental insights into improving the photocatalytic performance of SrBi 4 Ti 4 O 15 , thereby enhancing its potential for industrial application. [Display omitted] [ABSTRACT FROM AUTHOR]
- Published
- 2024
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