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Everything began with the discovery that pesticides have long had unintended side effects on non-target species, which is illustrated by Ponepal et al [...]

Organic and non-organic equivalent corresponding type of foods were assessed for pollutants, polycyclic aromatic hydrocarbons (PAHs), pesticides and heavy metals. In total, 35 samples of sausages and cheeses were tested from three western European countries, Spain, France, and Germany. These samples were chosen because they are meat and milk products presenting some bioaccumulation capacity. Petroleum residues were demonstrated in pesticide formulants. These include polycyclic aromatic hydrocarbons (PAHs) and metals. We measured in these human foods 800 pesticides, 24 PAHs, using accredited methods, as well as eleven metals and elements. Pesticides’ measurements were performed either by gas or liquid chromatography, followed by mass spectrometry, according to regulatory standard methods, that were measured over the threshold of 10 μg/kg for this reason. This could be insufficient to detect all toxic contaminations. Metals were analysed by high frequency induced plasma emission spectrometry and mass spectrometry after pressurized digestion. PAHs were assessed by gas and/or high-performance liquid chromatography with reverse phase polarity and if necessary double mass spectrometry. The raw data are summarized in Tables 1 and 2. The dataset can be reused for statistical analyses by the scientific community to evidence food pollution and to be compared with other measurements.

Toxicological investigations of pesticides largely focus on the declared active ingredient, which constitutes only between a few percent to around 50% of the total formulation. The complete formulations are unknown. For each declared active ingredient, there are dozens or hundreds of formulations. We demonstrate that petroleum has always been and is still always in pesticides. Gas chromatography and mass spectrometry (GC-MS) were applied for 24 pesticides. The measured compounds were the 16-priority polycyclic aromatic hydrocarbons (PAHs). The ratio of the PAHs to the threshold of toxicity was from 2.16 to 8288 times. The levels and distribution of PAHs per pesticide were different. Petroleum residues appear to be a waste product. The declared active component is taken alone for toxicity calculations, such as the acceptable daily intake (ADI). The PAHs with 2–3 cycles are more represented in pesticides than those with 4–6 cycles, which underlines that the petroleum residues appear to come mainly from crude unburned material. The ADI should be divided by 1000 if it is considered that petroleum residues amplify the toxicity by 1000. The admixture of PAHs in pesticides can be highly carcinogenic or toxic in the long term, even more than the declared active ingredient itself.