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BACKGROUND AND OBJECTIVES: The coffee agroindustry in Indonesia plays a significant economic role as the third largest coffee producer worldwide. Despite the high economic contribution, the coffee agroindustry also raises environmental issues along its supply chain. Coffee solid waste constitutes biomass containing useful compounds promising as raw materials for added-value products through the implementation of industrial symbiosis. Eco-industrial parks create value through industrial symbiosis, emphasizing the principle of a closed-loop production system, simultaneously decreasing the use of raw materials and waste. This study aimed to analyze and develop a coffee-based eco-industrial park design via a systems engineering approach and optimization of industrial symbiosis in closed-loop coffee production. METHODS: This study employed a case study in the Ketakasi coffee-producing center in Jember, Indonesia. Data collection was conducted through field observation and a series of in-depth interviews. The development of eco-industrial park design followed a systems engineering methodology, as demonstrated through the utilization of Business Process Model and Notation. Subsequently, the optimization of industrial symbiosis within eco-industrial parks was realized using a mixed-integer linear programming mathematical model. FINDINGS: The eco-industrial park design presents the actors, internal business processes, material and data exchanges, various actors' interdependence and critical roles in material exchanges, and value creation processes using valorization within the eco-industrial park. The role of the Ketakasi cooperative as a facilitator of material exchange and manager of the eco-industrial park is pivotal. The utilization of data integration enhances the transparency and efficiency of information exchange among eco-industrial park participants, promoting predictability and reliability in material exchange. The application of the mixed-integer linear programming optimization model has provided a structured approach to maximizing the value creation within the eco-industrial park through the valorization of 72.3 percent of coffee pulp and 68.5 percent of spent coffee grounds into cellulase enzymes and ultraviolet shields. CONCLUSION: This paper presents a structured framework for efficiently managing material exchange processes within an eco-industrial park, contributing to environmental sustainability and economic value creation. This study contributes to the knowledge gap in the literature by developing an inclusive eco-industrial park design that facilitates the optimization of the value creation process through valorization technology. This study also adds to sustainable agriculture management literature through a coffee-based eco-industrial park design. [ABSTRACT FROM AUTHOR]

BACKGROUND AND OBJECTIVES: Polychlorinated biphenyls are pervasive contaminants that are receiving attention worldwide. Due to their well-known propensity to have harmful impacts on both humans and the environment, polychlorinated biphenyls have been internationally banned for use. In this study, dechlorination of five polychlorinated biphenyl congeners, 2,2',5,5'-tetrachlorobiphenyl, 2,2',4,5,5'-pentachlorobiphenyl, 2,2',3,4,4',5'-hexachlorobiphenyl, 2,2',3,4,4',5'-hexachlorobiphenyl, 2,2',4,4',5,5'-hexachlorobiphenyl, and 2,2',3,4,4',5,5'-heptachlorobiphenyl, are evaluated. The chlorines from polychlorinated biphenyl congeners were removed using a heterogeneous catalyst synthesized via microwave-assisted impregnation of zinc metal onto pulverized shrimp shell waste. METHODS: The five polychlorinated biphenyl congeners were dechlorinated through treatments combination of time (1-4 hours), heat (150-250 degree celsius), and catalyst proportion (1-5 percent weight/weight basis). The dechlorination trials followed the Box-Behnken experimental design and then analyzed using response surface methodology. Levels of the remaining polychlorinated biphenyl congeners were monitored by using a gas chromatograph equipped with an electron capture detector. FINDINGS: The results of the trials demonstrated that among the five polychlorinated biphenyl congeners, only 2,2',3,4,4',5,5'-heptachlorobiphenyl did not respond to the provided treatments. Three congeners, namely, 2,2',5,5'-tetrachlorobiphenyl, 2,2',4,5,5'-pentachlorobiphenyl, and 2,2',4,4',5,5'-hexachlorobiphenyl, showed positive response, and one congener 2,2',3,4,4',5'-hexachlorobiphenyl showed negative response to the provided treatments. These findings suggested that chlorine attached to the para position of the biphenyls ring was easier to remove. The efficiency calculation of total polychlorinated biphenyl concentrations after treatments was approximately 25 percent. Such a low degree of effectiveness may be caused by the catalyst becoming inactive, either chemically through the deposition of chlorines that have been removed from the biphenyl ring or mechanically by the leaching of zinc from the surface of the pulverized shrimp shell due to insufficient mechanical strength. Optimization via response surface methodology produced optimal results for dechlorination at 150 degree celcius for 2.4 hours with 5 percent additional catalyst. CONCLUSION: The total amount of polychlorinated biphenyls that remained after dechlorination was not significantly impacted by the treatment combination of temperature, duration, and weight of the catalyst. However, the treatments had significant effects on the chlorine removal at the para positions of the biphenyl ring. In this case 2,2',5,5'-tetrachlorobiphenyl, 2,2',4,5,5'-pentachlorobiphenyl, and 2,2',4,4',5,5'-hexachlorobiphenyl congeners have positive responses and 2,2',3,4,4',5'-hexachlorobiphenyl congener has a negative response. For polychlorinated biphenyl congeners having more than six chlorines, no chlorine removal was observed. [ABSTRACT FROM AUTHOR]

BACKGROUND AND OBJECTIVES: Coconuts and their derivatives, such as copra and charcoal, are leading commodities of Indonesia contributing to local consumption and exports. Life cycle assessment is a tool for evaluating the inputs, outputs, and potential impacts of a product system throughout its life cycle and is associated with product sustainability. The cradle-to-gate life cycle assessment of copra and coconut shell charcoal aims to determine the impacts of coconut, copra, and charcoal production from copra byproducts quantitatively and identify scenario improvements to reduce the impacts and enhance sustainability. METHODS: Field observations were conducted in tall coconuts in Agrabinta, South Cianjur, and in copra and coconut shell charcoal factories in Sukabumi, West Java, Indonesia. The life cycle assessment method comprises the following four stages: goal and scope definition, inventory analysis, impact assessment, and interpretation. The scope of this study was based on land preparation, nurseries, planting, fertilization, harvesting of mature coconuts, transportation of mature coconuts, copra production, transportation of coconut shells, and charcoal production. Ten impacts were calculated using the Center of Environmental Science of Leiden University Impact Assessment baseline method with Simapro software. FINDINGS: This study obtained ten impact categories, not only the global warming potential impact similar to most studies of perennial crop products in Indonesia. Normalization results showed that the category with enormous impacts on humans from coconut cultivation and copra processing activities had terrestrial ecotoxicity potential. The largest impact on charcoal production was on the human toxicity potential. Separated coconut factories from plantations have a high impact because of high fuel transportation. Four recommendation scenarios were formulated: 1) utilization of smoke from pyrolysis into liquid, 2) implementation of organic coconut cultivation practices, 3) integration of coconut plantations with copra and charcoal processing plants and processing smoke into liquid, and 4) combining scenarios 1, 2, and 3. In scenario 3, seven of ten impacts showed the lowest value among other scenarios. This scenario potentially decreases the impact from 68.35 to 99.62 percent. The human toxic potential of coconut shell charcoal decreased from 2.92 × 105 to 109.43 kilogram 1,4-dichlorobenzene equivalent, terrestrial ecotoxicity potential decreased from 59 to 19 kilogram 1,4-dichlorobenzene equivalent, and the global warming potential decreased from 1753.55 to 93.03 kilogram carbon dioxide equivalent. CONCLUSION: Life cycle assessment can evaluate the impacts of copra and coconut shell charcoal from the coconut cultivation to the production stages. Opportunities for improvement can be identified from the interpretation and hotspots. Scenario analysis results showed the potential of developing integrated coconut agroindustry with coconut plantations, copra factories, and charcoal factories to produce liquid smoke in one location. This integration markedly reduces the impact due to the reduction of transportation fuel and emissions and the treatment of air pollution from pyrolysis. [ABSTRACT FROM AUTHOR]

Chicken meat agroindustry is one of the industries that contribute to environmental impacts. The environmental impacts are due to the use of resources, energy, and waste along the chicken meat chain. This study aimed to evaluate the environmental impacts along the life cycle of the chicken meat chain from cradle-to-grave using a life cycle assessment (LCA) approach. The data inventory consisted of inputs and outputs from five sub-systems: feed production, broiler production on the farm, carcass production at the slaughterhouse, supplier distribution, and consumer use. The impact categories included global warming, acidification, and eutrophication. The process of impact calculation used the CML-IA (Centre of Environmental Science of Leiden University Impact Assessment) baseline method on the SimaPro software. The results showed that consuming 1 kg of fried chicken resulted in a global warming impact of 5.86 kg CO2 eq, acidification of 38.3 g SO2 eq, and eutrophication of 24.1 g PO4 3-eq. Feed production, litter, and energy usage were the most significant contributors to the environmental impacts. Improvement scenarios in reducing environmental impacts included reducing crude protein in feed, composting litter, installing inverters on refrigeration compressors, and electrical energy efficiency. The present study indicated the importance of environmental impact assessment on the entire chicken meat chain to improve environmental performance in the Indonesian chicken agroindustry. [ABSTRACT FROM AUTHOR]