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Abstract The micro‐defects in epoxy‐based insulation materials generate a local high electric field which results in continuous degradation, seriously endangering the insulation system of gas‐insulated switchgears. A highly sensitive detection technique is reported for micro‐defects of insulation pull rods based on the photon counting (PC) technique. The results demonstrated that for an epoxy‐based insulation pull rod, the photons released during electroluminescence and ionisation at 2 kV, which is less than the partial discharge inception voltage, can be clearly detected. The findings presented a strong correlation between photon counts and defect severity. Discourse has been conducted to elucidate the mechanism behind defect‐induced PC, employing the amplification of ionising luminescence through electric field distortion induced by micro defects and the augmentation of electroluminescence through the aggregation of trap charge. In this regard, the authors verified that PC can serve as a potential tool in the detection of micro‐insulation defects, which also has huge potential in online insulation condition monitoring.

Abstract Discerning weak electric fields has important implications for cosmology, quantum technology, and identifying power system failures. Photonic integration of electric field sensors is highly desired for practical considerations and offers opportunities to improve performance by enhancing microwave and lightwave interactions. Here, we demonstrate a high-Q microcavity electric field sensor (MEFS) by leveraging the silicon chip-based thin film lithium niobate photonic integrated circuits. Using the Pound-Drever-Hall detection scheme, our MEFS achieves a detection sensitivity of 5.2 μV/(m $$\sqrt{{{{{{{{\rm{Hz}}}}}}}}}$$ Hz ), which surpasses previous lithium niobate electro-optical electric field sensors by nearly two orders of magnitude, and is comparable to atom-based quantum sensing approaches. Furthermore, our MEFS has a bandwidth that can be up to three orders of magnitude broader than quantum sensing approaches and measures fast electric field amplitude and phase variations in real-time. The ultra-sensitive MEFSs represent a significant step towards building electric field sensing networks and broaden the application spectrum of integrated microcavities.

The ubiquitous power Internet of Things (UPIoT) uses modern information technology and advanced communication technologies to realize interconnection and human-computer interaction in all aspects of the power system. UPIoT has the characteristics of comprehensive state perception and efficient information processing, and has broad application prospects for transformation of the energy industry. The fundamental facility of the UPIoT is the sensor-based information network. By using advanced sensors, Wireless Sensor Networks (WSNs), and advanced data processing technologies, Internet of Things can be realized in the power system. In this paper, a framework of WSNs based on advanced sensors towards UPIoT is proposed. In addition, the most advanced sensors for UPIoT purposes are reviewed, along with an explanation of how the sensor data obtained in UPIoT is utilized in various scenarios.

Polypropylene (PP) is considered to be a rather promising material for HVDC cable insulation. Grafting modi-fication has proved to be an effective method on the electrical property improvements of PP. This paper reports on the highly-enhanced electrical properties of styrene-grafted polypropylene (PP-g-St) and their related mechanism. The influence of grafting styrene on crystallization structures, thermal properties and electrical properties of PP-g-St are characterized and analyzed. These results show that PP-g-St exhibits remarkably enhanced DC volume resistivity, suppressed space charge accumulation and improved DC breakdown strengths as compared to PP. Crystallization observation shows PP-g-St has small, imperfect spherulites with indistinct boundaries, which is strongly correlated to enhanced electrical properties. This study provides an effective grafting strategy to design high-performance HVDC cable insulation materials for bulk power transmission systems.

Abstract With the increase in applied voltage and the decrease in volume, integrated electronic modules have become electrostatic sensitive. ZnO microvaristors doped silicone rubber (SiR) composite, with electric field‐dependent conductivity, shows promising prospects for solving the electrostatic problem. In this study, 20 vol% to 50 vol% ZnO/SiR composite films, filled with 10–30 μm ZnO microvaristors, were prepared and put into the test of electrostatic discharge. Compared with the insulating and conducting materials, ZnO/SiR composites achieve the lowest initial voltage and a short time constant of electrostatic discharge. With the increase of ZnO microvaristors volume fraction, from 20% to 50%, the initial voltage and the time constant of electrostatic discharge drop from 1.78 to 0.72 kV and 3.1 ms to 0.4 μs. When the ZnO volume fraction is higher than 30%, there is no residual voltage after 0.1 s. To explore the reason behind different electrostatic discharge performances of the ZnO/SiR composites, the conductivities of the composites were measured. It is found that the break‐over voltage of the composite drops with the increase in the ZnO microvaristors volume fraction. When a high voltage impulse is applied on the ZnO/SiR film, the composite will turn to the conducting state and release the electrostatic charge adaptively so that the initial voltage can be controlled. This work supplies a novel electrostatic discharge idea for electric and electronic devices.

The requirements for the construction of a new power system inevitably pose significant challenges and changes to the operation and maintenance of the power grid. To ensure the safe and stable operation of ultra-high voltage (UHV) transmission equipment, this work reports on the principles and preliminary results of using electroluminescence (EL)-based photon counting (PC) methods for early detection of micro-defects in GIS/GIL insulation spacer. In this study, the impact of voltage, gas pressure, and gas composition on the photon response of insulation is examined. Furthermore, the corresponding relationship between defect status and photon response characteristics is explored, along with the discussion of the EL mechanism and its evolution induced by defects. The research results demonstrate that PC measurement exhibits high sensitivity to variations in millimeter-scale defect size, position, and morphology at lower electric fields before partial discharge (PD) initiation. With this regard, this paper reveals promising prospects for the early detection of micro-defects in UHV transmission equipment using PC measurement-based methods.

Abstract Recently, demands for high‐performance polymer film capacitors at elevated temperatures have become more urgent. High dielectric constant is essential for dielectric materials to achieve substantial energy density at relatively low electric fields, which is of great significance to practical applications, while improving the permittivity of high‐temperature polymer dielectrics without a remarkable deterioration in other electrical properties still remains a challenge. Here, a polymer nanocomposite containing z‐aligned high‐k nanowires sandwiched by e‐beam evaporation deposited Al2O3 films was developed based on the optimal structure proposed by the phase‐field simulation. It is found that z‐aligned nanowires are more effective in promoting the dielectric constant than random‐aligned ones, and a large increase in dielectric constant is observed at relatively low content of nanofillers. Outer insulating layers effectively suppress the electric conduction and improve the breakdown strength. Consequently, the nanocomposite with only 1 volume fraction of z‐aligned nanowires exhibits a breakdown strength, electrical resistance, and charge–discharge efficiency as high as neat PEI, but more than twice the discharged energy density than it at 150 °C. This study realises the optimal structure predicted by simulation in experiment, obtaining high‐permittivity, high‐temperature nanocomposites at no expense of other electrical properties, and making it possible to achieve high discharged energy density at relatively low electric fields.

Abstract The concept of self‐healing dielectric polymers has been heatedly discussed, with the expectation of high damage resistance and longer service time. However, there is still a lack of analysis on the competitive relationship between electrical degradation and self‐healing. The authors discussed this relationship in two stages: the design of self‐healing strategies and the operation of self‐healing polymers. Since the requirements for excellent insulating or mechanical properties are not consistent with the demands for high self‐healing capability, trade‐offs are necessary during the design of self‐healing polymeric systems. In the operation stage of dielectric polymers, some key factors that affect the service lifetime of non‐autonomous self‐healing dielectric polymers are analysed, including the efficiency and repeatability of self‐healing, and the frequency of healing maintenance. For autonomous self‐healing dielectrics, the simultaneous processes of ageing and healing are investigated using a self‐healing epoxy resin based on microcapsules and in situ‐generated radicals. A quicker recovery of insulating properties, in terms of partial discharge magnitude, was observed under appropriate healing voltages. However, the self‐healing ability might vanish when the voltage was too high, verifying the competitive relationship between electrical degradation and self‐healing.

With the development of smart grids and the energy internet, large-scale monitoring of voltage and electric field data is required in all aspects of power systems, which requires the arrangement of various advanced sensors. Measurement of the electric field can replace traditional voltage transformers to realize the non-contact measurement of voltage, which reduces the insulation cost and the difficulty of operation and maintenance. Electric field measurement can also be applied in various other areas, such as equipment fault diagnosis, lightning warning, and electromagnetic environment measurement. Traditional electric field measurement devices, such as field mills, are bulky and costly, so they cannot be arranged flexibly on a large scale. In this paper, we present an electrostatically actuated micro-electric field sensor (E-sensor) with a piezoresistive sensing structure. The presented E-sensor is fabricated into a four-cantilever structure using microfabrication technology. The cantilevers are displaced under the drive of the electrostatic force, and the generated strain is transformed into measurable signals through piezoresistive materials. The presented E-sensor has the advantages of small size, low cost, low power consumption, and easy mass production. Moreover, the E-sensor has a high signal-to-noise ratio, high resolution, and wide measuring range. The experimental results show that the E-sensor has a linear electric field measurement range from 1.1 to 1100.0 kV·m−1 with an alternating current (AC) resolution of up to 112 V·m−1·Hz−1/2 and a cut-off frequency of 496 Hz, making it suitable for most applications in smart grids and the energy internet.

Abstract Many mainstream dielectric energy storage technologies in the emergent applications, such as renewable energy, electrified transportations and advanced propulsion systems, are usually required to operate under harsh-temperature conditions. However, excellent capacitive performance and thermal stability tend to be mutually exclusive in the current polymer dielectric materials and applications. Here, we report a strategy to tailor structural units for the design of high-temperature polymer dielectrics. A library of polyimide-derived polymers from diverse combinations of structural units are predicted, and 12 representative polymers are synthesized for direct experimental investigation. This study provides important insights into decisive structural factors necessary to achieve robust and stable dielectrics with high energy storage capabilities at elevated temperature. We also find that the high-temperature insulation performance would experience diminishing marginal utility as the bandgap increases beyond a critical point, which is strongly correlated to the dihedral angle between neighboring planes of conjugation in these polymers. By experimentally testing the optimized and predicted structures, an increased energy storage at temperatures up to 250 °C is observed. We discuss the possibility for this strategy to be generally applied to other polymer dielectrics to achieve further performance enhancement.

Abstract Attaining compact energy storage under extreme temperature conditions is of paramount importance in the development of advanced dielectric materials. The polymer composite approach has proved effective towards this goal, and addressing the correlation between filler distribution and electrical properties is foremost in designing composite dielectrics, especially in multifiller systems. Here, the design of a bi‐gradient polymer composite dielectric using an integrated framework based on the phase field model is reported. This framework can predict the charge‐inhibiting behavior of composite dielectrics, which is a key factor impacting the high‐temperature capacitive performance but unfortunately is ignored in conventional phase field models. It is found that due to the traps provided by the functional organic fillers, more carriers are trapped near the electrodes and weaken the electric field, thus significantly suppressing the breakdown initialization process. An interpenetrating gradient structure is designed rationally and synthesized experimentally, which exhibits concurrent high energy density (5.51 J cm−3) and high charge‐discharge efficiency (90%) up to 200 °C. This work provides a strategy to predict the high‐temperature energy storage performance of polymer composites containing charge‐inhibiting components and helps broaden the scope of data‐driven materials design based on phase‐field modeling.

The construction of the future energy structure of China under the 2050 carbon-neutral vision requires compact direct current (DC) gas-insulation equipment as important nodes and solutions to support electric power transmission and distribution of long-distance and large-capacity. This paper reviews China's 10-year progress in DC gas-insulated equipment. Important progresses in basic research and industry perspective are presented, with related scientific issues and technical bottlenecks being discussed. The progress in DC gas-insulated equipment worldwide (Europe, Japan, America) is also reported briefly.

Highlights A strategy that combines multi-mode scanning probe microscopy-based electrical characterization and nano-infrared spectroscopy is developed. A series of samples with different coupling agents and nanoparticles are characterized to unveil the local structure-property correlation of the interface in ferroelectric polymer nanocomposites. The formation of hydrogen bond between the surface modifiers and the ferroelectric polymer enhances the β-phase content and reduces the domain size of the interface, and hence promotes the local piezoelectric effect and breakdown strength.

Abstract The 2050 carbon‐neutral vision spawns a novel energy structure revolution, and the construction of the future energy structure is based on equipment innovation. Insulating material, as the core of electrical power equipment and electrified transportation asset, faces unprecedented challenges and opportunities. The goal of carbon neutral and the urgent need for innovation in electric power equipment and electrification assets are first discussed. The engineering challenges constrained by the insulation system in future electric power equipment/devices and electrified transportation assets are investigated. Insulating materials, including intelligent insulating material, high thermal conductivity insulating material, high energy storage density insulating material, extreme environment resistant insulating material, and environmental‐friendly insulating material, are categorised with their scientific issues, opportunities and challenges under the goal of carbon neutrality being discussed. In the context of carbon neutrality, not only improves the understanding of the insulation problems from a macro level, that is, electrical power equipment and electrified transportation asset, but also offers opportunities, remaining issues and challenges from the insulating material level. It is hoped that this paper envisions the challenges regarding design and reliability of insulations in electrical equipment and electric vehicles in the context of policies towards carbon neutrality rules. The authors also hope that this paper can be helpful in future development and research of novel insulating materials, which promote the realisation of the carbon‐neutral vision.

Abstract To suppress the charge accumulation on the spacer surface in direct current (DC) gas insulated transmission line (GIL) is an important and emergent issue for the development of a clean, safe and economic smart grid. A design method of the DC spacer is proposed, and a spacer prototype is prepared and evaluated both by simulation and type test. The DC withstand voltage test and polarity reversal test are performed using the new DC spacer compared with a commercialised 220 kV AC spacer. The simulation results indicate that the surface electric field and surface charge of the DC spacer are lower than those of the alternating current (AC) spacer under DC voltage. The test results verify that the surface flashover voltage of this DC spacer is higher than that of the AC spacer. The potential feasibility of the spacer design for HVDC is discussed. It is hoped that the content of this paper can bring new ideas in the development of HVDC gas insulated equipment.

Smart dielectric materials with bioinspired and autonomous functions are expected to be designed and fabricated for next-generation electrical insulation. Similar to organisms, such dielectrics with self-adaptive, self-reporting, and self-healing capabilities can be employed to avoid, diagnose, and repair electrical damage to prevent catastrophic failure and even a blackout. Compared with traditional dielectrics, the utilization of smart materials not only increases the stability and durability of power apparatus but also reduces the costs of production and manufacturing. In this review, researches on self-adaptive, self-reporting, and self-healing dielectrics in the field of electrical insulation, and illuminating studies on smart polymers with autonomous functions in other fields are both introduced. The principles, methods, mechanisms, applications, and challenges of these materials are also briefly presented.

Abstract This work reports the effect of octavinyl polyhedral oligomeric silsesquioxane (OvPOSS) on tuning the electrical performance of polypropylene (PP). OvPOSS with different content are introduced into PP using the solution method. The microstructural morphology, crystallinity behaviour, breakdown strength, DC conductivity, space charge formation, and trapping level distribution are measured. The results indicate that the OvPOSS nanofiller can be dispersed uniformly with a doping content of 2.0 phr or less. The DC conductivity is decreased, and the breakdown strength of OvPOSS/PP nanocomposites is significantly increased. The space charge accumulation of the OvPOSS/PP nanocomposites is significantly suppressed due to the introduction of deeper traps by the OvPOSS nanofiller. Finally, the experimental results demonstrate that the OvPOSS nanofiller can greatly increase the electrical performance of the base PP and the OvPOSS/PP nanocomposites have much potential for HVDC applications. They further demonstrate that the PP is environmental‐friendly due to its thermo‐plastic property, which can be recycled after the manufacture.

Abstract ZnO microvaristors/epoxy resin composite has drawn great attention from academia and industry for its adjustable non‐linear conductivity, high mechanical strength, and good ageing resistance. However, the sedimentation of ZnO microvaristors in epoxy resin during preparation is the key problem, which limits its application in engineering. In this study, a novel method of wet winding with polyester fibre cloth is proposed to prepare the ZnO microvaristors/epoxy resin composite. The anti‐settling effect of ZnO microvaristors in the composite is verified by scanning electron microscopy (SEM) and thermal gravimetric analysis (TGA). The microstructure shows that ZnO microvaristors distribute uniformly in the composite, and the content difference of ZnO microvaristors at the top and bottom part is only 0.4%. The composite shows typical non‐linear conductivity, and the threshold electric field and the non‐linear coefficient decrease with the content of ZnO microvaristors, while the conductivity in the insulating state shows an increasing trend. To verify the field grading effect of the composite with non‐linear conductivity (CNC), a finite element model of a needle‐plate electrode, simulating the condition of a conductive tip in a solid insulated system, is set up. CNC can adaptively grade the electric field, which reduces the surface electric field of the needle tip by 86.6% and the highest electric field in the system by 82.1%. This wet winding method solidifies the industrial application of CNC in high‐voltage power equipment.

Polypropylene (PP) exhibits excellent insulation properties, high thermo-stability, and recyclable nature, thus expected to be the next-generation insulation material for HV cable application. Chemical grafting modification is an effective technology to improve the electrical properties of polypropylene. In this paper, we develop and report a new-type grafted PP insulation material by water-phase grafting technology. The comprehensive properties including electrical, thermal, and mechanical of it are tested and compared with traditional cable insulation material—crosslinked polyethylene (XLPE). The results show that the grafted PP holds superior thermal properties and enough mechanical flexibility. The electrical properties are of significant advantages, including resistivity enhanced by nearly two degrees of magnitudes, AC/DC breakdown strength raised by over 20%, and obviously suppressed space charge accumulation. These results indicate that grafted PP is very suitable for application in HV cable systems, either AC or DC. This research lays a foundation for the research and development of the next-generation recyclable polypropylene cables at higher voltage levels.