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The gradients in surfactant distribution at a fluid-fluid interface can induce fluid flow known as the Marangoni flow. Fluid interfaces found in biological and environmental systems are seldom clean, where mixtures of various surfactants are present. The presence of multi-component surfactant mixtures introduces the possibility of interactions among constituents, which may impact Marangoni flows and alter flow dynamics. We employed flow visualization, surface tension and reaction kinetic measurements, and numerical simulations to quantitatively investigate the Marangoni flows induced by the reacting surfactant mixtures. Different binary surfactant mixtures were utilized for comparative analysis. The impact of surfactant interactions on Marangoni flows is confirmed through the observation of diverse complex flow patterns that result from the combination of oppositely charged surfactants in varying composition ratios and concentrations. Unique flow patterns originate from the composition-dependent interfacial phenomena upon mixing surfactants. Our findings provide vital insights that could be used to guide the development of effective oil remediation or the spreading of waterborne pathogens in contaminated regions. [ABSTRACT FROM AUTHOR]

This study explores the impact of electrostatic interactions and hydrogen bonding on tear film stability, a crucial factor for ocular surface health. While mucosal and meibomian layers have been extensively studied, the role of electrolytes in the aqueous phase remains unclear. Dry eye syndrome, characterized by insufficient tear quantity or quality, is associated with hyperosmolality, making electrolyte composition an important factor that might impact tear stability. Using a model buffer solution on a silica glass dome, we simulated physiologically relevant tear film conditions. Sodium chloride alone induced premature dewetting through salt crystal nucleation. In contrast, trace amounts of solutes with hydroxyl groups (sodium phosphate dibasic, potassium phosphate monobasic, and glucose) exhibited intriguing phenomena: quasi-stable films, solutal Marangoni-driven fluid influx increasing film thickness, and viscous fingering due to Saffman-Taylor instability. These observations are rationalized by the association of salt solutions with increased surface tension and the propensity of hydroxyl-group-containing solutes to engage in significant hydrogen bonding, altering local viscosity. This creates a viscosity contrast between the bulk buffer solution and the film region. Moreover, these solutes shield the glass dome, counteracting sodium chloride crystallization. These insights not only advance our understanding of tear film mechanics but also pave the way for predictive diagnostics in dry eye syndrome, offering a robust platform for personalized medical interventions based on individual tear film composition. [ABSTRACT FROM AUTHOR]

Poor mass transport to or from vertical gas-evolving electrodes can adversely impact energy efficiency and product purity in the production of hydrogen, chlorine, and various metals. A proper description that combines natural convection with micromixing of growing, coalescing, and departing bubbles is presently lacking. This work develops a simple, physically sound analytical model that includes the influence of bubble size, flow regime, and bubble surface coverage. By comprehensively reviewing mass transfer measurements from the water electrolysis literature, we observe that the surface coverage of oxygen bubbles increases much more strongly with increasing current density than an often-used square root scaling predicts. Strong differences are observed in the degree of micromixing of hydrogen and oxygen bubbles in alkaline and acidic electrolytes. These varied results can all be explained by a combination of electrocapillarity, and coalescence induced by either a high surface coverage or Marangoni flows. [Display omitted] • A simple formula for adding micromixing and natural convection is derived. • A single micromixing parameter between 0 and 5 describes all literature data. • Micromixing is strongest for oxygen in alkaline and hydrogen in acidic electrolytes. • Marangoni forces are attractive in this case, causing coalescence and larger bubbles. • Bubble coverage increases with the square/square root of current for oxygen/hydrogen. [ABSTRACT FROM AUTHOR]

For small droplets undergoing phase change, gravity is generally considered negligible. In the case of binary droplets evaporation, convective flows can be induced due to various mechanisms, such as continuity, buoyancy and/or selective evaporation of one of the components. Convection can also be induced by surface tension gradients resulting from concentration variations along the interface. This study presents experimental results of evaporation for binary mixture droplets. We concurrently investigate sessile and pendant droplets to assess gravity’s impact on binary droplet evaporation. We examine compositions including, pure butanol, pure methanol, pure water, and 50% per volume mixtures of water-butanol and water-methanol, evaporating in a controlled atmosphere. In the case of water-butanol mixtures, the drops contact line ‘depins’ during the evaporation process whereas the case of water-methanol mixture, the contact line of the drops remains pinned most of the lifetimes. The analysis of the evaporation dynamics reveals differences in the evaporation of these two mixtures and the effect of orientation (gravity). For water-butanol mixtures the evaporation occurs in four stages linked to preferential evaporation of the more volatile component and the ensuing surface tension gradients. In the case of water-methanol mixtures, contact lines tend to be pinned during most of the lifetimes of drops. The evaporation rate of the mixture is found to be between the ones of the pure components, i.e. water and methanol. The case of sessile drops exhibits a slight enhancement in evaporation rate in the case of the sessile configuration compared to the pendant one for pure water and mixture cases, which is explained by density differences and buoyancy driven flows. Solutal Marangoni flows in the case of water-methanol mixtures are deemed weaker compared to water-butanol ones. The use of the two mixtures allowed to have a good comparison between two cases where solutal-Marangoni effect can be strong (water-butanol) and weak (water- methanol) influence. The densities of the two organic liquids also highlighted gravitational effect due to the large difference in vapor densities. [ABSTRACT FROM AUTHOR]

We probe the temporal evolution of internal thermo-hydrodynamic features of evaporating sessile droplets under external forced convection. A transient numerical model based on Arbitrary Lagrangian-Eulerian (ALE) framework is adopted. The governing equations corresponding to the transport phenomena (mass, momentum and energy) are solved in a fully coupled manner in both the droplet (liquid) and ambient (gaseous) domains while accurately tracing the droplet interface evolution. The role of initial wetting state, external convection velocity and convective heating/cooling effects due to the air-flow are explored in details, and good agreements are noted with previous reports from literature. Results show that although the evaporation rate is augmented significantly in forced convection conditions, the same does not increase in proportion at higher Reynolds numbers. This is primarily due to the enhanced cooling effects that reduce saturated vapor concentration at droplet surface, and thereby supress the diffusion mechanism. Also, depending upon the contact angle, the evaporative cooling effects are compensated partially or completely due to convective heating. This altered thermal profile substantially influences internal hydrodynamic features (Marangoni flow and heat advection) during the transient and stable regimes of droplet evaporation. At higher degrees of convective heating, the droplet interface temperature becomes higher than its base temperature. This condition results in a completely opposite internal Marangoni vortex at stable state compared to that induced due to evaporative cooling effects. We also provide a regime map to show the role of the gas-phase Stefan number on the droplet-phase hydrodynamic regimes. [ABSTRACT FROM AUTHOR]

Microscopic active droplets are able to swim autonomously in viscous flows. This puzzling feature stems from solute exchanges with the surrounding fluid via surface reactions or their spontaneous solubilization and from the interfacial flows resulting from these solutes' gradients. Contrary to asymmetric active colloids, these isotropic droplets swim spontaneously by exploiting the nonlinear coupling of solute transport with self-generated Marangoni flows; such coupling is also responsible for secondary transitions to more complex individual and collective dynamics. Thanks to their simple design and their sensitivity to physico-chemical signals, these droplets are fascinating to physicists, chemists, biologists, and fluid dynamicists alike in analyzing viscous self-propulsion and collective dynamics in active-matter systems, developing synthetic cellular models, or performing targeted biomedical or engineering applications. I review here the most recent and significant developments of this rapidly growing field, focusing on the mathematical and physical modeling of these intriguing droplets, together with their experimental design and characterization. [ABSTRACT FROM AUTHOR]