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We present a radiative cooling material capable of enhancing albedo while reducing ground surface temperatures beneath fielded bifacial solar panels. Electrospinning a layer of polyacrylonitrile nanofibers, or nanoPAN, onto a polymer-coated silver mirror yields a total solar reflectance of 99 %, an albedo of 0.96, and a thermal emittance of 0.80. The combination of high albedo and high emittance is enabled by wavelength-selective scattering induced by the hierarchical morphology of nanoPAN, which includes both thin fibers and bead-like structures. During outdoor testing, the material outperforms the radiative cooling power of a state-of-the-art control by ∼20 W/m2 and boosts the photocurrent produced by a commercial silicon cell by up to 6.4 mA/cm2 compared to sand. These experiments validate essential characteristics of a high-albedo radiative-cooling reflector with promising potential applications in thermal and light management of fielded bifacial panels.

Functional thin film superlattices with stability in extreme environments can lead to transformative performance in optical and thermal applications such as thermophotovoltaics. In this work, key issues associated with defects that prevent layer-by-layer growth in epitaxial, low-miscibility oxide superlattices are investigated. Layer protrusions, approximately 8 nm wide and 3 nm thick, arise from a strain relaxation mechanism in 8 nm bilayer superlattices of Ba(Zr0.5Hf0.5)O3/MgO and propagate through the subsequent superlattice layers forming an inverted pyramid structure that is spatially phase offset from the matrix. The density and size of these defects scales with the number of interfaces in the sample, indicating that surface roughness during growth is a significant factor in the formation of these defects. In situ high temperature transmission electron microscopy (1000 °C, in vacuo) measurement reveals that phase decomposition of Ba(Zr0.5Hf0.5)O3 and decoherence of the superlattice is nucleated by these defects. This work highlights that achieving optimum growth conditions is imperative to the synthesis of single-crystalline superlattices with sharp interfaces for optimized performance in extreme environments. [ABSTRACT FROM AUTHOR]

We present a radiative cooling material capable of enhancing albedo while reducing ground surface temperatures beneath fielded bifacial solar panels. Electrospinning a layer of polyacrylonitrile nanofibers, or nanoPAN, onto a polymer-coated silver mirror yields a total solar reflectance of 99 %, an albedo of 0.96, and a thermal emittance of 0.80. The combination of high albedo and high emittance is enabled by wavelength-selective scattering induced by the hierarchical morphology of nanoPAN, which includes both thin fibers and bead-like structures. During outdoor testing, the material outperforms the radiative cooling power of a state-of-the-art control by ∼20 W/m2 and boosts the photocurrent produced by a commercial silicon cell by up to 6.4 mA/cm2 compared to sand. These experiments validate essential characteristics of a high-albedo radiative-cooling reflector with promising potential applications in thermal and light management of fielded bifacial panels. [ABSTRACT FROM AUTHOR]