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3. An alternate synthesis of sporiolide B from (R)-glyceraldehyde

Author

Kokkiligadda, Suresh Babu, Musunuri, Sivanadh, Syed, Tasqeeruddin, Maiti, Bhimcharan, and Venkata, Basaveswara Rao Mandava

Abstract

In this article, a novel synthetic route was described for the total synthesis of Sporiolide B from inexpensive and commercially available starting materials by a concise fourteen-step sequence in 6.50% overall yield. This convergent synthesis utilizes Grignard reaction, Asymmetric dihydroxylation, Yamaguchi macrolactonization and ring closing metathesis as the key steps.

Published
2023
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