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ZnO--TiO2 thin films containing 0.5 mol%, 1.0 mol%, and 5.0 mol% ZnO were synthesized by oxidative solidphase pyrolysis. The materials contained anatase and rutile phases with particle size of 6-13 nm, as confirmed using X-ray phase analysis and scanning electron microscopy. When a certain number of ZnO crystallites appeared in the TiO2 film structure in the temperature range of room temperature to 220 °C, a two-level response of the film resistance was observed, differing by approximately 10%, as obtained by electrophysical measurements. The two-level response correlates with the formation of two donor energy levels of 0.28 and 0.33 eV in the band structure of the ZnO--TiO2 films. The donor level with a higher activation energy corresponded to the Ti vacancy (V-Ti), and that with a lower activation energy corresponded to the Zn vacancy (V-Zn). Two levels of gas-sensitive properties were noted for 0.5ZnO--TiO2, 1ZnO--TiO2, and 5ZnO--TiO2 under the influence of 50 ppm NO2 at 250 °C. Such two-level responses can be ascribed to the pinning of the Fermi level on ZnO and TiO2 nanocrystallites. The mechanism of the beak-shaped and two-level responses of sensors based on composite nanomaterials when exposed to various gases was elucidated. [ABSTRACT FROM AUTHOR]

Thin nanocomposite films based on tin dioxide with a low content of zinc oxide (0.5–5 mol.%) were obtained by the sol–gel method. The synthesized films are 300–600 nm thick and contains pore sizes of 19–29 nm. The resulting ZnO–SnO2 films were comprehensively studied by atomic force and Kelvin probe force microscopy, X-ray diffraction, scanning electron microscopy, and high-resolution X-ray photoelectron spectroscopy spectra. The photoconductivity parameters on exposure to light with a wavelength of 470 nm were also studied. The study of the photosensitivity kinetics of ZnO–SnO2 films showed that the film with the Zn:Sn ratio equal to 0.5:99.5 has the minimum value of the charge carrier generation time constant. Measurements of the activation energy of the conductivity, potential barrier, and surface potential of ZnO–SnO2 films showed that these parameters have maxima at ZnO concentrations of 0.5 mol.% and 1 mol.%. Films with 1 mol.% ZnO exhibit high response values when exposed to 5–50 ppm of nitrogen dioxide at operating temperatures of 2 0 0 ∘ C and 2 5 0 ∘ C. [ABSTRACT FROM AUTHOR]

High-resolution two-phase flow data in the rod bundle are important in the development and validation of high-fidelity models for computational fluid dynamics and subchannel codes, in particular, those pertaining to light water reactor cooling systems. The Michigan Adiabatic Rod Bundle Flow Experiment (MARBLE) has been constructed as a modular assembly of an 8 × 8 lattice rod bundle to simulate scaled pressurized water reactor and boiling water reactor subchannel assemblies. To establish a high-spatial resolution database of the void fraction in the reactor fuel assembly geometries, tomographic measurements were performed with the High-Resolution Gamma-ray Tomography System, which was designed and built in house; the detector system has a spatial resolution of less than 1.0 mm using 240 LYSO (Lu1.8Y0.2SiO5) scintillators with a fan-beam array. In the present study, the local void fraction was measured with the MARBLE facility under various air-water flow conditions (jg = 0.04 to 0.85 m/s and jl = 0.12 to 0.77 m/s) covering from bubbly to cap-turbulent flows. The local void fraction was also successfully measured under nonuniform and asymmetric air bubble distribution conditions with an investigation of the effect of spacer grids and mixing vanes on void drift across subchannels. [ABSTRACT FROM AUTHOR]

Measuring the flow rate in High-Temperature Gas-cooled Reactors is a challenge for traditional flowmeters due to the high flow rate (10 to 15 m/s at nominal operating conditions), high operating temperatures (>700°C), and high neutron flux and gamma fields in the reactor core. This paper discusses developing a novel flowmeter that can work under these extreme conditions. Oak Ridge National Laboratory first proposed using acoustics to measure the flow in the reactor, more specifically, using a Kelvin-Helmholtz resonator to correlate the gas flow rate with vibration frequency. With the primary goal of developing an acoustic measurement technique, we propose an acoustic corrugated pipe as a candidate for the development of a novel gas flowmeter. Experimental investigations on corrugated pipes have confirmed the dependence of the whistling frequency on the gas flow rate. Also, a tube-in-tube configuration is proposed for the flowmeter prototype, which can help mitigate resonance between the system and the flowmeter. Experimental investigation using the prototype has shown good independence from the piping system. Furthermore, Unsteady Reynolds-Averaged Navier-Stokes (URANS) simulations have been performed and validated with a satisfactory agreement, providing confidence that URANS models can adequately predict the characteristic curve (flow rate versus frequency) of the corrugated pipe and can therefore be used to optimize the flowmeter designs cost-effectively. [ABSTRACT FROM AUTHOR]

Air ingress measurements using the 1/20th-scaled Helium Air Ingress gas Reactor Experiment (HAIRE) facility show key geometric variables of interest and their effect on air ingress in small- and medium-sized breaks in High Temperature Gas cooled Reactors. These variables include but are not limited to break diameter, break angle, and break wall thickness. Differing wall thicknesses for the same break diameter can have order-of-magnitude changes to the air ingress rate, which is a key figure of merit in the air ingress accident scenario. Additionally, different break sizes can change the importance of the angle in the break scenario. With smaller breaks, the flow will not transition from intermittent flow, to countercurrent flow, to diffusive flow as the break rotates from vertically upward toward vertically downward. This would lead to less variability with smaller breaks, which in turn would make the accident scenario more predictable for smaller-sized breaks. [ABSTRACT FROM AUTHOR]

Radiation transmission measurement methods have become widely implemented in the study of two-phase flow due to leaping advancements in detector efficiency, spatial resolution, and high-speed measurement capabilities. However, radiation-based measurements of boiling experiments bear several challenges due to the mismatch of calibration to experimental conditions, beam hardening, thermal expansion, and material and working fluid density changes with temperature. The present research focuses on developing methods to analyze the high-resolution X-ray radiography measurements of the post-critical heat flux (Post-CHF) heat transfer facility built at the University of Michigan that is intended to perform high-pressure and high-temperature measurements; the experimental test section is made of Incoloy-800H and is characterized as a cylindrical geometry expanding 1.0 m in length. The broad goal of the experiment is to build a high-resolution database to develop models for inverted annular film boiling and inverted slug film boiling through dispersed flow film boiling. The methods developed in this research model the thermal effects of the postulated challenges in order to properly scale the X-ray calibration measurements to the experimental conditions. Additionally, a cross-section-weighted method is developed to estimate the axial void fraction; this method is validated by modeling the test section with synthetic void fraction data. Last, preliminary high-speed X-ray measurements performed at subcooled boiling conditions are presented and analyzed with the developed methods, which include bubbly, slug, and churn flows. [ABSTRACT FROM AUTHOR]

Thin nanocomposite films based on zinc oxide (ZnO) added with cobalt oxide (Co3O4) were synthesized by solid-phase pyrolysis. According to XRD, the films consist of a ZnO wurtzite phase and a cubic structure of Co3O4 spinel. The crystallite sizes in the films increased from 18 nm to 24 nm with growing annealing temperature and Co3O4 concentration. Optical and X-ray photoelectron spectroscopy data revealed that enhancing the Co3O4 concentration leads to a change in the optical absorption spectrum and the appearance of allowed transitions in the material. Electrophysical measurements showed that Co3O4-ZnO films have a resistivity up to 3 × 104 Ohm∙cm and a semiconductor conductivity close to intrinsic. With advancing the Co3O4 concentration, the mobility of the charge carriers was found to increase by almost four times. The photosensors based on the 10Co-90Zn film exhibited a maximum normalized photoresponse when exposed to radiation with wavelengths of 400 nm and 660 nm. It was found that the same film has a minimum response time of ca. 26.2 ms upon exposure to radiation of 660 nm wavelength. The photosensors based on the 3Co-97Zn film have a minimum response time of ca. 58.3 ms versus the radiation of 400 nm wavelength. Thus, the Co3O4 content was found to be an effective impurity to tune the photosensitivity of radiation sensors based on Co3O4-ZnO films in the wavelength range of 400–660 nm. [ABSTRACT FROM AUTHOR]