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Landfills are the most affordable and popular method for managing waste in many parts of the world, However, in most developing nations, including India, the infiltration of hazardous materials from improperly managed dumping site continues to be a significant environmental problem. Around the world, leachate is a significant point source of contamination in numerous environmental media, including soil, groundwater, and surface water. Soil is an important asset as it is the key factor for food production and has tremendous significance in achieving sustainable development goals (SDGs). The contaminants from soil enter into food chain and ultimately reach humans. So in order to prevent the adverse effects of toxic elements on humans, there is need to maintain the soil quality and to prevent deterioration. Keeping in view the consequences of unscientific management of waste, the goal of the experiment was to determine how landfill leachate from Achan landfill affected the soil quality in the temperate Himalayas. All four seasons of the year, viz Spring, Summer, Autumn, and Winter, at four sites viz, Center of dumping site, inside, Outside and Control were monitored. Among sites center was found to have maximum value of EC (3.04 dS/m), Moisture content (42.51%), N (285.43 mg/kg), P (70.07 mg/kg), K (265.71 mg/kg), Ca (957.67 mg/kg), Mg(402.42 mg/kg), Zn (2.02 mg/kg), Fe (10.56 mg/kg), Cu (2.07 mg/kg), Mn (10.73 mg/kg), Pb (85.02 mg/kg), Cd (4.50 mg/kg), Ni (29.04 mg/kg), Cr (23.37 mg/kg), As (14.10 mg/kg). While as the lowest value of all parameters was reported at control site. From the study it is recommended that the waste generated is mostly organic (65-75%), thus can be segregated and treated at source. The waste can be treated at source using microbial consortium technology in order to transform the waste in to wealth in a sustainable way and to prevent the deterioration of soil quality., Competing Interests: The authors have declared that no competing interests exist., (Copyright: © 2024 Islam et al. This is an open access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.)

The demand for strategic and environment-friendly swine waste (SW) management is critical in the northeastern states of India, which account for 46.7% of the country's total swine population. This paper examines nutrient-rich compost production from SW with minimal negative environmental fallout, using cow dung microbiological inoculum and sawdust bulking agent for expeditious rotary drum composting. Aerobic biodegradation conducted in a rotary drum composter (RDC), raised the feedstock temperature to > 40 °C in just 24 h, which stimulated thermophilic decomposition. The thermophilic phase remained for 16 days in the cow dung-amended 10:1:1 (swine waste:cow dung:sawdust) trial (RDC1) versus 7 days for the sawdust-amended 10:1 (swine waste:sawdust) trial (RDC2). After 20 days, the RDC1 product exhibited superior nutritional characteristics, with a total nitrogen content of 2.52%, a significantly reduced coliform population, and an overall weight loss of 25%. These findings highlight that incorporating cow dung (10% w/w) into SW and bulking agents through RDC produces high-quality compost in just 20 days. Thus, the livestock industry benefits significantly from this laboratory-scale method of improved waste management by producing valuable bioproducts via RDC., Competing Interests: Declarations Ethical approval We declared that we do not have human participants, human data or human tissue. Consent to participate Not applicable. Consent to publish Not applicable. Competing interests The authors declare no competing interests., (© 2024. The Author(s), under exclusive licence to Springer Nature Switzerland AG.)

Lignocellulosic biomass has a promising role in a circular bioeconomy and may be used to produce valuable molecules for green chemistry. Lignocellulosic biomass, such as food waste, agricultural waste, wood, paper or cardboard, corresponded to 15.7% of all waste produced in Europe in 2020, and has a high potential as a secondary raw material for industrial processes. This review first presents industrial lignocellulosic waste sources, in terms of their composition, quantities and types of lignocellulosic residues. Secondly, the possible high added-value chemicals obtained from transformation of lignocellulosic waste are detailed, as well as their potential for applications in the food industry, biomedical, energy or chemistry sectors, including as sources of polyphenols, enzymes, bioplastic precursors or biofuels. In a third part, various available transformation treatments, such as physical treatments with ultrasound or heat, chemical treatments with acids or bases, and biological treatments with enzymes or microorganisms, are presented. The last part discusses the perspectives of the use of lignocellulosic waste and the fact that decreasing the cost of transformation is one of the major issues for improving the use of lignocellulosic biomass in a circular economy and green chemistry approach, since it is currently often more expensive than petroleum-based counterparts., Competing Interests: Declaration of competing interest The authors declare the following financial interests/personal relationships which may be considered as potential competing interests: [Cazier Elisabeth A. reports financial support was provided by MANE compagny. Pham Thanh-Nhat reports financial support was provided by MANE Compagny. If there are other authors, they declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper]., (Copyright © 2024 The Author(s). Published by Elsevier Ltd.. All rights reserved.)

This study is an inventory analysis and environmental life cycle assessment of hotel food waste management that seeks to inform efforts towards the development of bio circular economy in Zimbabwe. An audit of food waste generation and an inventory analysis of the prevailing food waste management practices at three selected hotels was undertaken. The greenhouse gas emissions from the prevailing disposal of food waste at dumpsites and the proposed biological treatment of food waste were evaluated using the Tier 1 FOD method and Tier 1 method of biological treatment using the 2019 refined 2006 Intergovernmental Panel on Climate Change guidelines. Environmental life cycle assessment was also conducted for the open dumping, composting, and anaerobic digestion. The average food waste generation within the Zimbabwean hospitality industry was estimated at 1.63 kg/guest/day, with a minimum and maximum of 1.01 and 2.25 kg/guest/day, respectively. Source-separated food waste is currently being collected indiscriminately by municipal waste collection trucks for final disposal at the official landfills or dumpsites. This calls for the need for an offtake system of the source-separated food waste in the form of composting or anaerobic digestion. Study results showed that the disposal of food waste at solid waste disposal sites contributes to the highest greenhouse gas emissions, followed by composting with a 75% reduction in greenhouse emissions. Anaerobic digestion brings about a maximum reduction in greenhouse emissions of 97%. Environmental life cycle assessment results also show that anaerobic digestion is the best method leading to net negative environmental impacts., Competing Interests: Declarations Competing interest The authors declare no competing interests., (© 2024. The Author(s).)

The final disposal of the soils removed from the area affected by the Fukushima nuclear accident will be carried out by 2045. This study investigated how acceptance of final disposal differed between top-down, opinion-aggregative, and opinion-reflective approaches to the decision outcome, and what factors influenced these differences. In 2022, a survey of 3000 randomly selected participants living outside Fukushima Prefecture was conducted using the postal method, with responses obtained from 871 consenting participants. The proportions of respondents who agreed to accept the final disposal were 22.6, 37.6 and 56.9% for the top-down, opinion-aggregative, and opinion-reflective approaches, respectively. The preferences for both opinion-aggregative and opinion-reflective approaches showed significant positive associations with interest in final disposal and social benefits, and significant negative associations with intergenerational expectations and age. This study highlights the importance of procedural fairness in determining final disposal sites, and identifies factors that contribute to greater acceptance through this process., (© The Author(s) 2024. Published by Oxford University Press. All rights reserved. For Permissions, please email: journals.permissions@oup.com.)

Leachate from municipal solid waste landfills poses a significant threat to aquatic ecosystems due to poor management practices. This study evaluated thirty leachate samples from Iranian metropolises using the Leachate Pollution Index (LPI). Various parameters, including BOD₅, COD, TDS, pH, EC, heavy metals, turbidity, PAHs, phthalates, and humic acid, were analysed. The BOD₅ levels ranged from 350 to 20,000 mg/L, and the COD levels ranged from 2,000 to 90,000 mg/L. The TDS content varied between 14.7 and 67 g/L, while the turbidity ranged from 15 to 186 NTU. Heavy metals were present but within standard limits. The phthalate concentrations ranged from 6 to 150.8 mg/L, and the humic acid concentrations ranged from 135 to 2,200 mg/L. Naphthalene was the most frequent hydrocarbon detected. The LPIs were less than 30 for all the samples, with the highest in Ahvaz and the lowest in the treated samples from Tehran. This study highlights the presence of persistent organic and hazardous contaminants in Iran's municipal landfills, emphasizing the need for effective leachate treatment and improved waste management practices. Enhanced final disposal methods, increased waste recovery, and improved solid residue separation are crucial for preventing further leachate production and environmental contamination., (© 2024. The Author(s).)

Indiscriminate disposal of dry cell battery (DCB) waste contributes to environmental and public health issues in developing countries such as Ghana, due to the toxic nature of this specific waste. Accordingly, a study was conducted in Accra, Ghana, to determine the socio-economic and demographic factors influencing handling DCB waste, aiming a sustainable environment. Using a random sampling technique, a descriptive cross-sectional survey was conducted, encompassing 367 respondents from the Accra-Tema Metropolitan areas and Tema West Municipal Assembly in Greater Accra, Ghana. Using descriptive and multivariate statistical methods, the survey data were analysed with the Statistical Package for Social Sciences (SPSS) version 27. The results of this study show that female gender and residential area are likely to positively influence the use of DCB at home. Education significantly affects the use of DCB and its proper disposal. The results also suggest that 78% of the respondents disposed of DCB waste in waste bins. The mean monthly income of the respondents stands at USD 270, which is average and likely partially to positively influence the disposal of the DCB. The data collected revealed that female gender, age group, family size, and education level influence the indiscriminate disposal of DCB waste and DCB waste recycling. The results highlight that educated females above the age of 55, with a monthly income, are likely to properly segregate DCB waste. This study contributes to the knowledge gap in relation to dry cell battery waste management (DCBWM) in developing countries, aiming to advance global sustainability. This study is expected to contribute to educate and create awareness in managing DCB waste to reduce its indiscriminate disposal which leads to environmental pollution and negatively affects human health and environmental sustainability in Ghana., (© 2024. The Author(s).)

In this study, low-temperature pyrolysis is applied to raw and chelated municipal solid waste incinerator fly ash to degrade and remove PCDD/F (polychlorinated dibenzo-p-dioxins, and dibenzofurans) and corresponding I-TEQs (international toxic equivalents), respectively. Additionally, PCDD/F degradation pathways are identified based on PCDD/F signatures. From the analysis of the average signal intensity of dioxin isomers in thermally treated fly ashes, the PCDD/F degradation rate was between 89.97 and 99.80 %, and the I-TEQs removal rate was 98.96 and 99.90% across all samples compared to untreated raw fly ash. The chelating agent EDTA enhanced the thermal degradation of PCDD/F, but the addition of Na 2 HPO 4 in chelated fly ash as an inhibitor promoted PCDD/F regeneration. Further, there is a variable output of dioxins and corresponding I-TEQs under different temperatures and reaction times; however, longer reaction duration and higher temperatures proved highly effective. The overall toxicity of all thermally tested fly ashes was lesser than the permissible value of 50 ng I-TEQ/kg for resource utilization and observed in the range of 1.84 ± 0.15 to 19.45 ± 0.89 ng I-TEQ/kg. The investigation of the PCDD and PCDF signatures suggests that thermal destruction was a major pathway of degradation by breakage of the C-O bond, compared to dechlorination as observed by a high percentage contribution of HpCDD/F and OCDD/F congeners in thermally treated fly ashes. Low-temperature pyrolysis is an auspicious disposal technology that requires additional studies for large-scale applications., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Landfills pose a global issue for soil functionality and health, especially in underdeveloped nations where limited resources impede the adoption of comprehensive waste management policies, such as waste processing and sorting techniques. Leachate emissions from waste landfills are a cause for concern, primarily due to their toxic effect if left uncontrolled in the environment, and the potential for waste storage sites to produce leachate for hundreds of years after closure. Few efforts have been made to improve waste collection and disposal facilities in the world, especially in developing countries. This research aims to investigate the influence of waste leachate on soil health indicators in natural woodland and rangeland ecological systems in a semi-arid mountainous region in the north of Iran. Based on results, forest unpolluted sites (2008) exhibited the highest values of nutrient elements in litter and root components. Landfills led to a rise in soil bulk density and a simultaneous decrease in soil organic matter (SOM), porosity, aggregate stability, particulate organic carbon and nitrogen (POC and PON), as well as available nutrients, ammonium (NH 4 + ) and nitrate (NO 3 - ) levels. Additionally, microbial parameters (respiration and biomass) and enzymes (urease, acid phosphatase, arylsulfatase and invertase) experienced a decrease in areas affected by the landfill sites over time of 2008-2023. Forest and rangeland landfill sites (2023) sites had lower density and biomass of the three earthworm groups. Acari, Collembola, nematodes, protozoans, fungi and bacteria were also reduced in landfill sites (nearly 1-2 times more in uncontaminated forest and rangeland sites). Lumbricus terrestris earthworms exhibited a clear presence in all the studied sites, and this demonstrates the ability of this earthworm species to be active in severe pollution conditions. The spatial pattern of soil cadmium and lead changes indicates the high variance of these characteristics under the influence of landfills in the study sites. Finally, the soil health indicators (according to soil physical, chemical, and biological parameters) decreased from forest unpolluted sites in 2008 to rangeland landfill sites in 2023, which is linked to the release of landfill leachate. These results are noteworthy for all countries and governments that rely on natural ecosystems for waste management without engineering operations or technical intervention. Furthermore, both governments and stakeholders must implement effective waste management systems. The research offers valuable information that can assist decision-makers engaged in sustainable solid waste management in Iran and comparable areas. Besides that, it is highly recommended to prioritize recycling and phytoremediation processes. Ultimately, worldwide efforts to achieve environmental sustainability need a significant focus on the effective management of hazardous waste. Consequently, investigations covering this topic should be continued, as they allow the evaluation of the environmental effects of the gradual accumulation of pollution in soils surrounding uncontrolled municipal solid waste landfills., Competing Interests: Declaration of competing interest The authors declare that they have no conflict of interest., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Municipal solid waste (MSW) management is a major concern for Bangladesh, given its high population density and increasing waste production rate. Conventional waste management methods, such as landfilling, result in high carbon emissions for the environment. With over 70% of MSW being organic, hydrothermal carbonization (HTC) has emerged as a promising technology for recovering energy and nutrients from such heterogeneous waste streams. This study aimed to compare the environmental effects of HTC coupled with electricity generation (HTC-EG) from MSW with traditional landfilling using life cycle assessment in the context of Bangladesh. The HTC-EG scenario showed lower environmental impacts in three out of five impact categories, specifically reducing climate change, freshwater ecotoxicity, and photochemical ozone formation. For a functional unit of 6000-ton MSW, HTC-EG reduces the climate change impact by 7.7 × 10 6  kg CO 2 eq. Additionally, HTC-EG has 46.77% less impact on freshwater ecotoxicity compared to landfilling and reduces the photochemical ozone formation impact by 1.86 × 10 4 NMVOC eq. However, the HTC-EG scenario leads to increased particulate matter formation and marine water eutrophication due to SO 2 , SO 3 , and PM2.5 emissions during hydrochar combustion and nitrate release from the liquid stream of the HTC reactor, respectively. Addressing these challenges through appropriate post-processing of flue gas from hydrochar combustion and HTC liquid streams could make HTC-EG a viable alternative to landfilling for MSW management in Bangladesh., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Sorting out plastic waste (PW) from municipal solid waste (MSW) by material type is crucial for reutilization and pollution reduction. However, current automatic separation methods are costly and inefficient, necessitating an advanced sorting process to ensure high feedstock purity. This study introduces a Swin Transformer-based model for effectively detecting PW in real-world MSW streams, leveraging both morphological and material properties. And, a dataset comprising 3560 optical images and infrared spectra data was created to support this task. This vision-based system can localize and classify PW into five categories: polypropylene (PP), polyethylene (PE), polyethylene terephthalate (PET), polyvinyl chloride (PVC), and polystyrene (PS). Performance evaluations reveal an accuracy rate of 99.75% and a mean Average Precision (mAP 50 ) exceeding 91%. Compared to popular convolutional neural network (CNN)-based models, this well-trained Swin Transformer-based model offers enhanced convenience and performance in five-category PW detection task, maintaining a mAP 50 over 80% in the real-life deployment. The model's effectiveness is further supported by visualization of detection results on MSW streams and principal component analysis of classification scores. These results demonstrate the system's significant effectiveness in both lab-scale and real-life conditions, aligning with global regulations and strategies that promote innovative technologies for plastic recycling, thereby contributing to the development of a sustainable circular economy., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

The biological stability of solid waste is one of the main problems related to the environmental impact of landfills and their long-term emission potential. Current European legislation (European Landfill Directive, EC/99/31) introduced the need to reduce biodegradable organic compounds deposited in landfills; however, it set neither official parameters nor methods to define the stability of such a waste. In Spain, biodegradability is generally evaluated using the biological oxygen demand/chemical oxygen demand (BOD 5 /COD) ratio, measuring it on the leachate, thus not considering the non-soluble fraction and therefore creating false negatives. To solve this problem, the biodegradability of hazardous industrial waste has been determined by measuring its respirometric activity (AT 4 ). Our results show that the measure of the AT 4 is independent of the enrichment with a microbial inoculum, and a sample size no higher than 20 g could be a reasonable value for a sensitive biodegradability determination. The highest respirometric index is obtained in waste with pH values between 6.5 and 10.5. Furthermore, respirometric biodegradability values are independent of traditional parameters of organic matter characterization such as BOD 5 /COD ratio, volatile content, and total and dissolved organic carbon. Consequently, the AT 4 parameter provides new information on the composition and stability of organic matter in hazardous industrial waste. Its incorporation into pre-disposal waste characterization protocols allows to identify waste that exceeds recommended biodegradability thresholds. This approach ensures that only waste meeting specified biodegradability standards is deposited, avoiding landfill emissions and related environmental impacts, and thereby improving the overall effectiveness and sustainability of waste management practices., (© 2024 The Author(s). Journal of Environmental Quality published by Wiley Periodicals LLC on behalf of American Society of Agronomy, Crop Science Society of America, and Soil Science Society of America.)

Municipal solid waste (MSW) is a major anthropogenic contributor to climate change due to the substantial quantities of greenhouse gas (GHG) emitted by landfills and incineration. Circular waste management has shown promise in reducing GHG emissions; however, it is still in its early stages and requires further optimization. In this study, support vector machine models were developed to determine the compositional dynamics of MSW, which were then integrated to examine the interactions among composition, disposal routes, and GHG emissions. The results from analyzing large-scale transitions from traditional to circular waste management practices showed that GHG mitigation potential will be significantly enhanced as the coverage of circular waste management increases from 35% in 2025 to 100% in 2035 in China. However, these reductions will eventually decrease as waste quantities decline in response to population shrinkage. The results reveal both the GHG mitigation potential and limitations of the circular waste management mode, assisting policymakers and researchers in maximizing its mitigation potential., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Plastic waste has become a major contributor to global environmental pollution. Some of the environmental impacts of plastic waste include littering, the formation of plastic debris in oceans and the contamination of freshwater and terrestrial habitats. Policymakers face great challenges in mitigating plastic waste. Indonesia is considered the second largest contributor of plastic waste in the world. However, existing policies have not addressed this issue. Policies, such as bans on single-use plastic bags and fees on plastic bags, have recently been implemented in some pilot cities, but the results remain unclear. Thus, this study proposes feasible policies to mitigate plastic waste in Indonesia using system dynamics. Specifically, this study seeks to develop a dynamic model of plastic waste mitigation and to propose a policy scenario for plastic waste mitigation. The proposed policies consist of a plastic bag ban, a plastic bag fee, a recycling centre and extended producer responsibility (EPR). The analysis demonstrates that an effective mixed policy instrument for reducing plastic waste depends on the plastic waste type. Regarding plastic bottles, the effective mixed policy is a combination of a recycling centre and EPR. For plastic bags, the effective mixed policies include the following combinations: a plastic bag fee and plastic bag ban, a plastic bag fee and recycling centre and a plastic bag ban and recycling centre., Competing Interests: Declaration of conflicting interestsThe authors declared no potential conflicts of interest with respect to the research, authorship, and/or publication of this article.

This study evaluated the anaerobic digestion suitability of bio-waste from different sources by comparing their biochemical methane potential (BMP), biodegradability (BI), and content of contaminants (heavy metals and physical impurities) - an often-overlooked factor but one of particular concern in bio-waste. Predominant heavy metals included Cu and Zn, while recurring physical impurities comprised plastics and organic non-biodegradable matter. Food waste from food processing plants were most suitable, exhibiting low contamination and high biogas conversion (BMP > 549 NmLCH 4 /gVS and BI > 86 %). Conversely, organic fractions from mechanical biological treatment were highly contaminated, while green waste displayed low biogas conversion (BMP < 368 NmLCH 4 /gVS and BI < 72 %). Food waste from households and medium/large-sized producers also demonstrated high biogas conversion, but variable contamination levels could compromise their suitability. Assessing contaminants alongside BMP and BI provides a comprehensive approach for selecting suitable bio-waste feedstocks that can be introduced in biogas plants., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

To evaluate the potential of compost based on municipal solid waste (MSW) and 20% legume pruning under a pyrolysis process, generated products, including solids (biochar), liquids (bio-oil), and gases (non-condensable gases), through experimentation in a pilot plant with a fluidized bed reactor at 450°C and gas chromatography/mass spectrometry have been analysed. In addition, the compost kinetic behaviour by thermogravimetric analysis (TGA), using the Flynn-Wall-Ozawa (FWO) method, has been investigated. Four different reaction zones, associated with lignocellulosic materials (hemicellulose, cellulose, and lignin) with a first step for water evaporation, in TGA curve have been observed. A biochar with low stability and aromaticity, considering high and low O/C and H/C ratios, respectively, has been obtained. The obtained pyrolytic liquids contain a high concentration of phenolic compounds because of a significant presence of lignins and other high molecular weight compounds in the original material. Moreover, the generated non-condensable gases consist mainly of short-chain compounds, such as alcohols, aldehydes, and alkenes produced from hemicellulose, cellulose, and proteins., Competing Interests: Declaration of conflicting interestsThe authors declared no potential conflicts of interest with respect to the research, authorship, and/or publication of this article.

The anaerobic digestion of the organic fraction of municipal solid waste (OFMSW) has shown to be a viable alternative since it allows energy recovery in the form of methane and generates a residue (digestate) that can be applied effectively as a soil improver or fertiliser. The potential for methane production and the digestates' characteristics depend on the substrate characteristics and the process variables such as temperature, solids retention time, and organic load. This study dealt with OFMSW anaerobic digestion under different organic loading rates and temperatures and the characteristics of the resulting digestates. Three semi-continuous reactors were operated at 20, 35, and 55°C and fed daily with ground, fresh OFMSW from Mexico City. The inoculum was temperature-adapted UASB granular sludge. The main results indicate that the anaerobic digestion was adequate, as the pH values were slightly alkaline, which is sufficient for methanization, and the alkalinity was not a limiting factor. Potassium and PO 4 -P increased with the organic load, and Kjeldahl nitrogen decreased. At 20°C, total organic carbon (TOC) increased substantially with the organic load; at 35°C, it remained without significant changes; and at 55°C, TOC slightly decreased with the organic load. The C/N ratio changed accordingly to TOC variations. At 20°C, the residual biogas potential increased with the organic load; at 35 and 55°C, it decreased with increasing organic load; the residual biogas potential increased with residual fatty acids concentrations. To comply with international standards for agricultural use, the digestates need only dewatering and supplementing with PO 4 -P.

In Sri Lanka, the management of Construction & Demolition (C&D) waste poses a major problem, leading to environmental degradation and depletion of resources. This study aims to tackle these issues by examining the implementation of Circular Economy (CE) strategies within the construction industry of Sri Lanka. The focus is on reducing waste generation and maximizing resource utilization during the demolitions and repurpose, as well as material recovery and production stages of the building project life cycle. These stages are crucial in terms of waste generation and resource consumption. A qualitative approach was employed in this research, utilizing the Delphi technique to gather insights through a series of three rounds of expert interviews. In the first round, 17 experts were involved, followed by 15 in the second round, and 12 in the final round. The data collected from these interviews were analysed using manual content analysis methods. Based on the research findings, a total of 14 C&D Waste Management (WM) issues were identified specifically in the Demolitions and Repurpose Stage in Sri Lanka. For each issue, suitable strategies were proposed to overcome them effectively. Furthermore, the study examined the impact of CE strategies on minimizing these issues within the context of the project management iron triangle. Similarly, the Material Recovery and Production Stage of the building presented eight C&D WM issues, each accompanied by corresponding strategies to address them. The research also explored the influence of CE strategies in mitigating these issues, considering the project management iron triangle. During the demolitions and repurpose stage, CE strategies focus on reducing waste generation and optimizing resource utilization. This involves carefully deconstructing buildings to salvage and recover materials that can be reused or repurposed., Competing Interests: Declaration of conflicting interestsThe authors declared no potential conflicts of interest with respect to the research, authorship, and/or publication of this article.

This study is a critical review of municipal solid waste (MSW) hydraulic conductivity that includes investigation of the influence of vertical stress, dry unit weight and degradation. A total of 56 studies were compiled that included laboratory-, pilot- and landfill-scale hydraulic conductivity experiments. Compacting waste and increasing vertical stress reduce MSW hydraulic conductivity via reshaping the pore networks throughout the waste matrix, reducing the void ratio and increasing tortuosity. However, the magnitude of reduction in hydraulic conductivity is dependent on stress, waste composition and decomposition. Solid waste decomposition can have opposing effects on hydraulic conductivity. Some studies have indicated that an increase in MSW decomposition results in particle size reduction and settlement that reduces the void ratio and decreases hydraulic conductivity. Conversely, some studies indicate that waste decomposition reduces the solid mass, which increases the void ratio and creates larger flow paths that increase hydraulic conductivity. The data compilation, observations and key findings from this study are beneficial for solid waste practitioners to improve design, analysis and operation of MSW landfills., Competing Interests: Declaration of conflicting interestsThe authors declared no potential conflicts of interest with respect to the research, authorship, and/or publication of this article.

This article reports on how management approaches influence methane emissions from landfills. The project team created various landfill operational scenarios for different regions of the planet with respect to waste composition, organic waste reduction and landfill gas recovery timing. These scenarios were modelled by applying a basic gas generation model according to the United Nations Intergovernmental Panel on Climate Change (IPCC) recommendations. In general, the IPCC's recommended modelling parameters and default values were used. Based on the modelling undertaken, two options stand out as being the most effective methane mitigation measures in a wide range of conditions throughout the world: (a) early gas recovery and (b) reduction of the amount of biodegradable organic waste accepted in a landfill. It is noted that reduction of organic input to any given landfill can take many years to realize. Moreover, suitable alternative processing or disposal options for the organic waste can be unaffordable for a significant percentage of the planet's population. Although effective, organic waste reduction cannot therefore be the only landfill methane mitigation measure. Early landfill gas recovery can be very effective by applying basic technologies that can be deployed relatively quickly, and at modest cost. Policymakers and regulators from around the globe can significantly reduce adverse environmental impacts from landfill gas emissions by stimulating both the early capture and flaring and/or energy recovery of landfill gas and programmes to reduce the inflow of organic waste into landfills., Competing Interests: Declaration of conflicting interestsThe authors declared no potential conflicts of interest with respect to the research, authorship, and/or publication of this article.

Discharge from unrestricted tobacco products with filters (TPF) causes environmental damage. To reduce TPF litter quantities, Directive (EU) 2019/904 requires TPF producers to proportionally contribute to the costs of discarding their products in public waste collection systems, including litter waste ones. An appropriate output-based cost model requires assessing TPF quantities in relevant waste streams. Currently, there is no comprehensive data available on TPF quantities in municipal solid waste (MSW). Therefore, a case study was conducted to quantify TPF in MSW. This study aimed to determine TPF quantities (1) in residual waste from four German district types and (2) in waste from public collection systems for three settlement structures within Trier City. Relevant waste streams from public collection systems, namely waste from public waste receptacles, street-cleaning waste and sinkhole residues, were identified. For both sampling campaigns, consideration was given to extrapolating the results to a larger scale. The results showed that the average specific TPF quantities in residual waste were 277.7, 271.8, 193.3 and 204.5 gi - 1 a - 1 in the selected city district, urban district, densely populated rural district and sparsely populated rural district, respectively. Extrapolation of these results to Germany yielded a specific TPF quantity in residual waste of 250.3 gi -1 a -1 . The average specific TPF quantities in waste from public waste receptacles, street-cleaning waste and sinkhole residues were 12.2, 47.4 and 9.9 gi -1 a - 1 , respectively. The results could contribute to cost model development based on Directive (EU) 2019/904., Competing Interests: Declaration of conflicting interestsThe authors declared the following potential conflicts of interest with respect to the research, authorship, and/or publication of this article: This publication was prepared using data from contract research. pbo was commissioned to carry out an open-ended and objective scientific study on the subject of ‘Tobacco filters in municipal waste’ based on the guidelines of scientific practice. The contract research was commissioned by the Association of the Tobacco Industry and Novelty Products (Bundesverband der Tabakwirtschaft und neuartiger Erzeugnisse (BVTE)), the German Cigarette Association (Deutscher Zigarettenverband (DZV)), Philip Morris GmbH (PMG), the Association of the Cigarette Paper Processing Industry (Verband der Zigarettenpapier verarbeitenden Industrie (VZI)) and the Association of the Cigar Industry (Bundesverband der Zigarrenindustrie (BdZ)) to the Institute for Tobacco Research (Institut für Tabakforschung GmbH (IfT)) as project sponsor. In this context, pbo was commissioned by the Institute for Tobacco Research (Institut für Tabakforschung GmbH (IfT)). The Chair of Anthropogenic Material Cycles (ANTS) was commissioned via a subcontract from PBO.

Semi-aerobic aged refuse biofilters (SAARB) are commonly-used biotechnologies for treating landfill leachate. In actual operation, SAARB often faces harsh conditions characterized by high concentrations of chemical oxygen demand (COD) and Cl - , as well as a low carbon-to-nitrogen ratio (C/N), which can disrupt the microbial community within SAARB, leading to operational instability. Maintaining the stable operation of SAARB is crucial for the efficient treatment of landfill leachate. However, the destabilization mechanism of SAARB under harsh conditions remains unclear. To address this, the study simulated the operation of SAARB under three harsh conditions, namely, high COD loading (H-COD), high chloride ion (Cl - ) concentration environment (H-Cl - ), and low C/N ratio environment (L-C/N). The aim is to reveal the destabilization mechanism of SAARB under harsh conditions by analyzing the fluorescence characteristics of effluent DOM and the microbial community in aged refuse. The results indicate that three harsh conditions have different effects on SAARB. H-COD leads to the accumulation of proteins; H-Cl - impedes the reduction of nitrite nitrogen; L-C/N inhibits the degradation of humic substances. These outcomes are attributed to the specific effects of different factors on the microbial communities in different zones of SAARB. H-COD and L-C/N mainly affect the degradation of organic matter in aerobic zone, while H-Cl - primarily impedes the denitrification process in the anaerobic zone. The abnormal enrichment of Corynebacterium, Castellaniella, and Sporosarcina can indicate the instability of SAARB under three harsh conditions, respectively. To maintain the steady operation of SAARB, targeted acclimation of the microbial community in SAARB should be carried out to cope with potentially harsh operating conditions. Besides, timely mitigation of loads should be implemented when instability characteristics emerge, and carbon sources and electron donors should be provided to restore treatment performance effectively., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier B.V. All rights reserved.)

The present study examines the current practices for managing construction and demolition waste (CDW) in two tier-2 cities of Karnataka state: Hubli-Dharwad and Davanagere. The research highlights the quantification, characterization, and effective management strategies for CDW. CDW dumping sites were identified through field visits conducted across all wards of the cities and recorded using a mobile-based app. At each site, data were collected on the types of vehicles dumping CDW, the frequency of dumping, the volume of waste in the vehicles, and the quantity of CDW removed for reuse. The dumping sites were categorized into large, medium, and small based on the area and volume of waste. In total, 130 unauthorised dumping sites were identified in Hubli-Dharwad and 62 in Davanagere. The study estimated that Hubli-Dharwad generates approximately 607 tonnes per day (TPD) of CDW, while Davanagere produces around 287 TPD. The characterization of CDW revealed that in Hubli-Dharwad, CDW consists of 14.4% concrete, 25.5% brick and mortar, 39.1% soil and aggregates, and 20% other materials. In Davanagere, the composition includes 19% concrete, 29% brick and mortar, 38% soil, and 14% other materials. Based on these findings, the study proposes a system for the collection and transportation of CDW and recommends suitable recycling technologies. While the approach outlined in this paper is well-suited for urban local bodies to assess CDW, the data on CDW reuse and recycling is primarily based on informal practices. This makes accurate quantification challenging and subject to variation over time due to a lack of regulatory oversight. Additionally, the study provides only a snapshot of CDW generation and management at a specific point in time, potentially missing seasonal variations or long-term trends in waste handling., (© 2024. The Author(s), under exclusive licence to Springer Nature Switzerland AG.)

In recent years, the substantial increase in municipal solid waste incineration fly ash (MSWIFA) production has made its treatment a critical issue. However, the high toxicity of MSWIFA makes its utilization still in the exploratory stage. In this study, the heavy metal leaching rate, particle size distribution and activity index of MSWIFA were tested to investigate the detoxification and activation effects of Bacillus mucilaginosus on MSWIFA by introducing rhamnolipid. The results show that the microbial treatment can greatly increase the leaching rate of heavy metals in MSWIFA and its 28-day and 90-day activity indexes, especially by the synergistic treatment. For the Bacillus mucilaginosus and rhamnolipid treated MSWIFA (BR-MSWIFA), the maximum leaching rates follow the order from high to low of 85.57% Cr, 78% Cu, 76.38% Zn, 62.78% Pb and 37.65% Mn, while having a low mass loss of less than 5%, which is important for its reuse. Moreover, compared with the untreated MSWIFA (U-MSWIFA), the average particle sizes of Bacillus mucilaginosus treated MSWIFA (B-MSWIFA) and BR-MSWIFA decrease from 8.39 μm to 7.80 μm and 4.31 μm, and the 28-day activity indexes increase from 80.19% to 101.59% and 110.61%. The effect mechanism is that rhamnolipid not only can promote the growth, reproduction, and metabolic acid production of Bacillus mucilaginosus, but also disperse the extracellular polymeric substance (EPS) and MSWIFA particles, thus increase their contact area and the bioleaching. This study provided a theoretical foundation for the harmless treatment and resource utilization of solid wastes containing heavy metals., Competing Interests: Declaration of competing interest The authors declare the following financial interests/personal relationships which may be considered as potential competing interests:If there are other authors, they declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

This study aimed to optimize the solid waste collection and transportation system using ArcGIS Network Analyst and location-allocation tools. The generated solid waste was characterized by proximate analysis. The generation rate and composition were determined according to standard methods. The average solid waste generation rates for households, commercial sites, institutions, and recreational places were 0.48 kg/c/day, 15.03 kg/fac/day, 9.32 kg/fac/day, and 22.8 kg/fac/day, respectively. The estimated total generation rate of the sub-city is 207,004.03 kg/day and 712.13 m 3 /day as discarded base. Composition analysis revealed that food waste is the major component of municipal solid waste, with estimated weight and volume of 134,696.08 kg and 299.46 m 3 , respectively. Proximate analysis indicated that food and textile wastes have relatively high moisture content and fixed carbon. Candidate pre-collection bin allocations were optimized based on factors such as road network, distribution of solid waste generators, and existing temporary dumping sites, resulting in 1052 potential bin locations. Transfer station allocation was optimized by considering land use-land cover, slope, and geology. Twelve transfer routes and four transport routes were established to efficiently serve the bins and final waste destinations. In conclusion, the study demonstrates that ArcGIS Network Analyst and location-allocation tools can effectively optimize the municipal solid waste collection and transportation system, providing a robust framework for improving waste management efficiency. However, further research is recommended to validate these findings through field application., (© 2024. The Author(s), under exclusive licence to Springer-Verlag GmbH Germany, part of Springer Nature.)

Food-waste solid residue is the remaining solid after food waste treatment, with high yield, high solid content, high protein and fiber content. Effective pretreatment is necessary to improve the efficiency of hydrolysis and acidification for anaerobic digestion of food-waste solid residue. In this study, fluorescence spectroscopy coupled with parallel factor analysis were used to insight into the mechanism of food-waste solid residue during three pretreatments (alkali, thermal and alkali-thermal). Pretreatments increased the solubility of lignocellulosic substrate and destroyed structure of starch, while lignocellulosic analogs were effectively cracked, changing the composition and improving the degradability. Soluble chemical oxygen demand, soluble protein and soluble polysaccharide concentrations were increased by 144.60%, 350.57% and 138.72% after pretreatment under the condition of 120 °C + 2% CaO, respectively. Three-dimensional fluorescence spectra showed the region of maximum fluorescence intensity under alkali-thermal pretreatments, indicating chemical bonds (such as OC-C) were easier broken and the solubility of organic substances were increased. Three main fluorescence components were obtained by parallel factor analysis, which were humic acid-like, lignocellulose-like and protein-like, respectively, while the lignocellulose-like had the maximum Fmax value. The fluorescence intensity of samples under alkali-thermal pretreatment varied in the range from 59.48 × 10 5 to 13.18 × 10 6 , which was an increase of 174.27%-507.74% over the control (21.68 × 10 5 ), indicating that alkali-thermal pretreatment observably accelerated the breaking of chemical bonds, and thus promoted the dissolution of organic matter. This study deeply revealed the mechanism of alkali-thermal pretreatment of food-waste solid residue, which is of great significance for efficient resource utilization of food waste and food-waste solid residue., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

This article investigates the pivotal role of non-hazardous waste landfills in achieving greenhouse gas (GHG) reduction objectives within the European Union (EU). 1 This study leverages the experience of key stakeholders in the European landfilling, assesses the efficacy of 'best-in-class' landfill installations, evaluates their potential impact on GHG reduction, and offers concrete recommendations for operators and policymakers. 'Best-in-class' landfills exceed the commonly accepted best practices by implementing all the following practices: (1) an anticipated capture system during the operating phase, (2) prompt installation of the final cover and capture system, with use of an impermeable cover, (3) operated as bioreactor, keeping optimal humidity, (4) adequate maintenance and reporting, (5) recovery of captured gas and (6) treatment of residual methane emissions throughout the waste decomposition process. The main finding is that switching from the actual mix of practices to 'best in class' practices would reduce by ~21 MtCO 2eq (-36%) the emissions due to the degradation of waste landfilled between 2024 and 2035, compared to the 'business-as-usual scenario', while also providing a renewable energy source, bringing potential avoided emissions and energy sovereignty. The findings underscore that in addition to implementing the organics diversion and waste reduction targets of the EU, adopting 'best-in class' landfill practices has the potential to bolster energy recovery, mitigate emissions and stimulate biomethane production, thereby advancing the EU environmental goals., Competing Interests: Declaration of conflicting interestsThe authors declared no potential conflicts of interest with respect to the research, authorship, and/or publication of this article.

The annual increase in global organic waste generation emphasises the need to develop a sustainable management platform to address environmental concerns. This study aims to explore sustainable treatments for the conversion of organic waste into energy in pursuit of zero-waste. The organic waste generated from the animal feed industry (referred to as WF) was used for the model compound in this study. 8.5 wt% of lipids were extracted from the WF, which contained unidentified impurities. Acid-catalysed transesterification yielded less than 80 wt% biodiesel might be due to the reversible reaction. In contrast, non-catalytic transesterification resulted in a significantly higher biodiesel yield (95.6 wt%), suggesting that this method was more effective at converting impure lipids into biodiesel compared to acid-catalysed transesterification. These results indicate the potential advantages of the non-catalytic approach, particularly when dealing with impure lipid sources. To minimise the generation of waste in the process, the WF residue produced after lipid extraction was converted into combustible gas (syngas) through pyrolysis. CO 2 was used as a reactive medium in pyrolysis. In one-stage pyrolysis, the gas yield under CO 2 was comparable to that under N 2 , indicating that CO 2 did not react effectively with the volatiles derived from the WF residue. Enhanced CO 2 reactivity was achieved via catalytic pyrolysis using a nickel-impregnated catalyst. Consequently, the combustible gas yield under CO 2 was much higher than that under N 2 . This approach might contribute to maximising the efficiency of converting organic waste into renewable energy while simultaneously consuming CO 2 during pyrolysis, thereby enhancing the sustainability of this approach., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Biochar modification is an effective approach to enhance its ability to promote anaerobic digestion (AD). Focusing on the physical properties of biochar, the impact of different particle sizes of biochar on AD of food waste (FW) at high organic loading rate (OLR) was investigated. Four biochar with different sizes (40-200 mesh) were prepared and used in AD systems at OLR 30 g VS/L. The research results found that biochar with a volume particle size of 102 μm (RBC-P140) had top-performance in promoting cumulative methane production, increasing by 13.20% compared to the control group. The analysis results of the variety in volatile acids and alkalinity in the system did not show a correlation with the size of biochar, but small size has the potential to improve the environmental tolerance of the system to high acidity. Microbial community analysis showed that the abundance of aceticlastic methanogen and the composition of zoogloea were optimized through relatively small-sized biochar. Through revealing the effect of biochar particle size on AD system at high OLR, this work provided theoretical guidance for regulating fermentation systems using biochar., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Legacy waste dumpsites have been a significant environmental concern in India for many years. These dumpsites are characterized by the uncontrolled disposal of Municipal Solid Waste (MSW) and have led to various types of pollution and disease outbreaks. As India faces the challenges of rapid urbanization and increased waste generation and with over 3000 legacy waste dumpsites in the country, the need to address these legacy waste dumpsites has become paramount. As we continue to struggle extensively for waste management as well as space, landfill mining has been recognized as a promising way of recovering resources in our country by employing various technological and engineering advancements to extract valuable materials and energy from legacy waste streams. Unlike existing waste management approaches, this review explores the application of a novel Recovery Potential Index (RPI) for legacy waste dumpsites in India, which evaluates the feasibility of waste treatment facilities based on waste compositions and recovered material quantities. Depending on the RPI, recovered fine fractions can be sold as city compost or used as fill material, while recyclable, combustible, and inert fractions could be directed towards appropriate recycling or landfill uses. Unscientific and uncontrolled landfill mining practices could lead to unanticipated impacts on the nearby environment in the form of heavy contamination, thereby presenting this practice as a challenge in addition to the immense opportunities it provides., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Landfill is a significant source of atmospheric CH 4 and CO 2 emissions. In this study, four landfill reactor systems were constructed to investigate the effects of different ventilation methods, including continuous aeration (20 h d -1 ) and intermittent aeration (continuous aeration for 4 h d -1 and 2 h of aeration every 12 h, twice a day), on properties of landfilled waste and emissions of CH 4 and CO 2 , in comparison to a traditional landfill. Compared with continuous aeration, intermittent aeration could reduce the potential global warming effect of the CH 4 and CO 2 emissions, especially multiple intermittent aeration. The CH 4 and CO 2 emissions could be predicted by the multiple linear regression model based on the contents of carbon, sulfur and/or pH during landfill stabilization. Both intermittent and continuous aeration could enhance the methane oxidation activity of landfilled waste. The aerobic methane oxidation activity of landfilled waste reached the maximums of 50.77-73.78 μg g -1 h -1 after aeration for 5 or 15 d, which was higher than the anaerobic methane oxidation activity (0.45-1.27 μg g -1 h -1 ). CO 2 was the predominant form of organic carbon loss in the bioreactor landfills. Candidatus Methylomirabilis, Methylobacter, Methylomonas and Crenothrix were the main methane-oxidating microorganisms (MOM) in the landfills. Total, NO 2 - -N, pH and Fe 3+ were the main environmental variables influencing the MOM community, among which NO 2 - -N and pH had the significant impact on the MOM community. Partial least squares path modelling indicated that aeration modes mainly influenced the emissions of CH 4 and CO 2 by affecting the degradation of landfilled waste, environmental variables and microbial activities. The results would be helpful for designing aeration systems to reduce the emissions of CH 4 and CO 2 , and the cost during landfill stabilization., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

To upcycle the nutrients from kitchen waste (KW), an integrated system consisting of anaerobic digestion (AD) reactor and microbial protein (MP) production reactor was established in this study. The subsystem I (AD system) demonstrated an efficient bio-energy production (282.37 mL CH 4 /g VS), with 553.54 mg/L of NH 4 + -N remained in the digestate. The subsystem II (MP production system) utilized the nitrogenous constituents of the digestate, with 2.04 g/L MP production. In order to further enhance the recovery efficiency, C/N ratio in the subsystem II was studied. NH 4 + -N recovery efficiency was 23.08% higher after C/N ratio optimization along with 0.24 g/L increment on MP production. Over 0.7 g/L of essential amino acids was obtained, according with the qualitative necessary for the feeds. Also, the key enzyme abundance of CO 2 releasing and amino acid biosynthesis was obviously increased with max. 55.21%. Meanwhile, the integrated system was profitable via a simplified economic assessment., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

The Saltstone Disposal Facility on the Savannah River Site in South Carolina disposes of Low-Level Waste in a reducing-grout waste form. Reducing grout is presently being evaluated as a subsurface disposal waste form at several other locations in the United States, as well as in Europe and Asia. The objective of this study was to collect core samples directly from the Saltstone Disposal Facility and measure desorption distribution coefficients (K d ; radionuclide concentration ratio of saltstone:liquid; (Bq/kg)/Bq/L)) and desorption apparent solubility values (k sp ; radionuclide aqueous concentration (moles/L)). An important attribute of this study was that these tests were conducted with actual aged, grout waste form materials, not small-volume simulants prepared in a laboratory. The reducing grout is comprised of blast furnace slag, Class F fly ash, ordinary portland cement, and a radioactive salt waste solution generated during nuclear processing. The grout sample used in this study underwent hydrolyzation in the disposal facility for 30 months prior to measuring radionuclide leaching. Leaching experiments were conducted either in an inert (no oxygen) atmosphere to simulate conditions within the saltstone monolith prior to aging (becoming oxidized) or they were exposed to atmosphere conditions to simulate conditions of an aged saltstone. Importantly, these experiments were designed not to be diffusion limited, that is, the saltstone was ground finely and the suspensions were under constant agitation during the equilibration period. Under oxidized conditions, measured Tc K d values were 10 mL/g, which was appreciably greater than the historical best-estimate value of 0.8 mL/g. This difference is likely the result of a fraction of the Tc remaining in the less soluble Tc(IV) form, even after extensive oxidation during the experiment. Under oxidized and reducing conditions, the measured Ba and Sr (both divalent alkaline earth metals) K d value were more than an order of magnitude greater than historical best-estimate values of 100 mL/g. The unexpectedly high Ba and Sr K d values were attributed to these radionuclides having sufficient time to age (form strong bonds) in the sulfur-rich saltstone sample. Apparent k sp values under reducing conditions were 10 -9  mol/L Tc and 10 -13  mol/L Pu, consistent with values measured with surrogate materials. Measured apparent Ba, Sr, and Th k sp values were significantly greater than historical best-estimates. The implications of the generally greater K d values and lower k sp values in these measurements is that these cementitious waste forms have greater radionuclide retention than was previously estimated based on laboratory studies using surrogate materials. This work represents the first leaching study performed with an actual aged, reducing-grout sample and as such provides an important comparison to studies conducted with surrogate materials, and provides high pedigree data for other programs around the world evaluating reducing grouts as a wasteform for subsurface nuclear waste disposal., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Composting presents a viable management solution for lignocellulose-rich municipal solid waste. However, our understanding about the microbial metabolic mechanisms involved in the biodegradation of lignocellulose, particularly in industrial-scale composting plants, remains limited. This study employed metaproteomics to compare the impact of upgrading from aerated static pile (ASP) to agitated bed (AB) systems on physicochemical parameters, lignocellulose biodegradation, and microbial metabolic pathways during large-scale biowaste composting process, marking the first investigation of its kind. The degradation rates of lignocellulose including cellulose, hemicellulose, and lignin were significantly higher in AB (8.21%-32.54%, 10.21%-39.41%, and 6.21%-26.78%) than those (5.72%-23.15%, 7.01%-33.26%, and 4.79%-19.76%) in ASP at three thermal stages, respectively. The AB system in comparison to ASP increased the carbohydrate-active enzymes (CAZymes) abundance and production of the three essential enzymes required for lignocellulose decomposition involving a mixture of bacteria and fungi (i.e., Actinobacteria, Bacilli, Sordariomycetes and Eurotiomycetes). Conversely, ASP primarily produced exoglucanase and β-glucosidase via fungi (i.e., Ascomycota). Moreover, AB effectively mitigated microbial stress caused by acetic acid accumulation by regulating the key enzymes involved in acetate conversion, including acetyl-coenzyme A synthetase and acetate kinase. Overall, the AB upgraded from ASP facilitated the lignocellulose degradation and fostered more diverse functional microbial communities in large-scale composting. Our findings offer a valuable scientific basis to guide the engineering feasibility and environmental sustainability for large-scale industrial composting plants for treating lignocellulose-rich waste. These findings have important implications for establishing green sustainable development models (e.g., a circular economy based on material recovery) and for achieving sustainable development goals., Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2023. Published by Elsevier B.V.)

The incineration of municipal solid waste (MSW) produces byproducts known as MSW incineration (MSWI) ash. The reuse of MSWI ash as a construction material prevails in several areas of the world, namely Europe and Asia, however, reuse in the United States (US) lags due to regulatory requirements for disposal practices. Developing a recycling program for MSWI ash provides an alternative end-of-life disposal scenario for material currently landfilled and supplements the reliability of mining of natural aggregates. This study provides a programmatic review of the past decade of challenges and opportunities a local government in the US has experienced to implement a recycling program for their MSWI bottom ash (BA) as a construction aggregate in road materials, such as hot mix asphalt, concrete pavement, and road base. The regulatory and practical challenges in the U.S. are presented, including meeting mechanical and environmental performance requirements (e.g., strength and leaching-to-groundwater). The novel approach to overcoming these challenges include blending MSWIBA from two facilities with common aggregates, creating suitable construction materials. Interfacing with local and state agencies, such as the Department of Environmental Protection and Transportation resulted in additional testing to establish the MSWIBA as a beneficial use material and obtain essential approvals for advancing reuse opportunities. This paper synthesizes available data regarding the challenges, opportunities, and implementation of this recycling program by reviewing the experiences of an MSWI facility in the US to provide fundamental guidance to those considering similar applications. Implications: The reuse of municipal solid waste incinerator bottom ash (MSWIBA) lags in the United States (US) due to regulatory limitations and lack of precedence. This manuscript details the steps of a local government in the US to establishing a novel recycling program for their MSWIBA, including performance evaluation, regulatory interfacing, and outreach. This critical review provides a comprehensive document containing appropriate considerations required to implement similar MSWIBA recycling programs in the US and offers lawmakers, policymakers, and MSWI operators knowledge regarding opportunities and challenges associated with pursuing this avenue.

The municipal solid waste (MSW) management is significantly contributing to global greenhouse gas (GHG) emissions. Analyzing the emission pattern of GHGs from MSW is essential for formulating appropriate carbon mitigation policies. Based on IPCC Models, GHG emissions from MSW were calculated in Chinese provinces from 2004 to 2021 by landfilling and incineration operations, separately. Landfilling and incineration generated approximately 1271 MtCO 2 -eq and 198 MtCO 2 -eq from 2004 to 2021, respectively. GHG emissions from landfilling increased from 2004 to 2020 and declined in 2021, while GHG emissions from incineration demonstrated an increasing trend with three distinct growth stages. A panel regression model was then employed to identify the key factors influencing GHG emissions. GDP and population are positively related to GHG emissions from landfills, while PCCE is negatively related to GHG emissions from landfills. GDP and PCCE have a positive impact on GHG emissions from incineration, while population showed no significant impact. Multi-expression programming was used to develop an explicit model, forecasting GHG emissions from MSW by 2030. From 2022 to 2024, GHG emissions from landfills will quickly decrease, while GHG emissions from incineration will rapidly increase. Subsequently, the GHG emission rate of incineration will slow down, and GHGs from landfilling will slowly decrease due to no MSW for landfill disposal. The methods and results provide insightful information for policy-makers and waste management sector., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Whether it be to measure their value before a trade, to calculate yields and optimize the recycling process or to check for the presence of harmful substances, Waste Electronic and Electric Equipments (WEEE) need to be characterized. Sampling can give an accurate assessment of the grade of a batch of WEEE, but quantifying the uncertainty around this estimate can be delicate. Pierre Gy's sampling theory of particulate matter studies how the latter is affected by the physical and chemical properties of the studied objects. However, its application requires a deep understanding of the correlations existing between their size, shape, volume, density, mass and grade, which are still unclear for WEEE fragments. Although average information is typically available on batches of WEEE, a more detailed description would be necessary to gain insight into such relationships. To start filling the gap, this paper focuses on the fine characterization of two different batches of waste printed circuit boards, crushed into pieces of about 10 mm. One by one, over 5,000 fragments were sampled, photographed and analyzed. Their individual mass, density, volume, thickness, surface, width and length were all measured separately. Based on their appearance, they were also sorted into four heuristic categories: plastic, metal, circuit boards and electronic components. Descriptive statistics of this novel granulometric database are shown here, throwing light on the unique correlations between the studied parameters and exhibiting a peculiar mass-size law. They point to new avenues on how to adapt Gy's sampling model to WEEE., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Chemical pretreatment is a common method to enhance the cumulative methane yield (CMY) of lignocellulosic waste (LW) but its effectiveness is subject to various factors, and accurate estimation of methane production of pretreated LW remains a challenge. Here, based on 254 LW samples, a machine learning (ML) model to predict the methane production performance of pretreated feedstock was constructed using two automated ML platforms (tree-based pipeline optimization tool and neural network intelligence). Furthermore, the interactive effects of pretreatment conditions, feedstock properties, and digestion conditions on methane production of pretreated LW were studied through model interpretability analysis. The optimal ML model performed well on the validation set, and the digestion time, pretreatment agent, and lignin content (LC) were found to be key factors affecting the methane production of pretreated LW. If the LC in the raw LW was lower than 15%, the maximum CMY might be achieved using the NaOH, KOH, and alkaline hydrogen peroxide (AHP) with concentrations of 3.8%, 4.4%, and 4.5%, respectively. On the other hand, if LC was higher than 15%, only high concentrations of AHP exceeding 4% could significantly increase methane production. This study provides valuable guidance for optimizing pretreatment process, comparing different chemical pretreatment approaches, and regulating the operation of large-scale biogas plants., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Numbers do matter; the Intergovernmental Panel on Climate Change (IPCC)'s 2010 data that the waste sector is responsible for just 3% of global greenhouse gas (GHG) emissions has led to the misperception that solid waste management (SWM) has little to contribute to climate mitigation. Global efforts to control methane emissions and divert organic waste from landfills had already reduced direct emissions. But end-of-pipe SWM has also been evolving into more circular waste and resource management, with indirect GHG savings from the 3Rs (reduce, reuse, recycle) which IPCC accounts for elsewhere in the economy. The evidence compiled here on both direct emissions and indirect savings demonstrates with high confidence that better waste and resource management can make a significant contribution to climate mitigation, and must form a core part of every country's nationally determined contribution. Even the most advanced countries can still achieve much from the 3Rs. In the Global South, the challenge of extending waste collection to all and stopping open dumping and burning (sustainable development goal 11.6.1), essential to improve public health, can be turned into a huge opportunity. Moving early to divert waste from landfill by separation at source and collecting clean organic and dry recycling fractions, will mitigate global GHG emissions, slash ocean plastics and create decent livelihoods. But this can only happen with targeted climate, plastics and extended producer responsibility finance; and help to local communities to help themselves., Competing Interests: Declaration of conflicting interestsThe authors declared no potential conflicts of interest with respect to the research, authorship and/or publication of this article.

Appropriate stocking density plays an important role in ensuring the stability and improving the overall efficiency of the vermicomposting system. Although some studies have shown that earthworms can degrade lignocellulosic materials, relatively few studies have been conducted on the effect of earthworm stocking density on the degradation of a single green waste (GW) with high lignocellulosic content. Therefore, this study investigated the degradation effect of earthworms on GW at different stocking densities, and assessed the stability and maturity of the whole vermicomposting by comprehensively analysing the changes in physicochemical and biological properties of earthworms during vermicomposting, and by combining the growth of earthworms with a multi-dimensional assessment of the stability and maturity of the whole vermicomposting. In this study, six stocking densities (CK-T5) were set up, namely, no earthworms, 10, 20, 30, 40, and 50 worms/kg. The results showed that compared with the CK (without earthworms), when there were 30 earthworms per kg of GW (i.e. T3), the total nitrogen, total phosphorus, total potassium, organic matter decomposition, bacterial and fungal numbers, and germination index of earthworm compost products increased by 14 %, 29 %, 32 %, 35 %, 42 %, 94 %, and 125 %, respectively. T3 also enhanced the activities of cellulase and alkaline phosphatase. The results were further supported by principal component analysis. Finally, we conclude that when the stocking density of earthworms is appropriate (T3), it not only favours the growth of earthworms, but also positively affects the physicochemical properties of the vermicomposting process, which in turn significantly improves the biodegradation efficiency of GW., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

Plastic waste poses a critical environmental challenge for the world. The proliferation of waste plastic coffee pods exacerbates this issue. Traditional disposal methods such as incineration and landfills are environmentally unfriendly, necessitating the exploration of alternative management strategies. One promising avenue is the pyrolysis in-line reforming process, which converts plastic waste into hydrogen. However, traditional pyrolysis methods are costly due to inefficiencies and heat losses. To address this, for the first time, our study investigates the use of microwave to enhance the pyrolysis process. We explored microwave pyrolysis for polypropylene (PP), high-density polypropylene (HDPE), and waste coffee pods, with the latter primarily comprising polypropylene. Additionally, catalytic ex-situ pyrolysis of coffee pod pyrolysis over a nickel-based catalyst was investigated to convert the evolved gas into hydrogen. The single-stage microwave pyrolysis results revealed the highest gas yield at 500 °C for HDPE, and 41 % and 58 % (by mass) for waste coffee pods and polypropylene at 700 °C, respectively. Polypropylene exhibited the highest gaseous yield, suggesting its readiness for pyrolytic degradation. Waste coffee pods uniquely produced carbon dioxide and carbon monoxide gases because of the oxygen present in their structure. Catalytic reforming of evolved gas from waste coffee pods using a 5 % nickel loaded activated carbon catalyst, yielded 76 % (by volume) hydrogen at 900 °C. These observed results were supported by elemental balance analysis. These findings highlight that two-stage microwave and catalysis assisted pyrolysis could be a promising method for the efficient management of waste coffee pods, particularly for producing clean energy., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 The Author(s). Published by Elsevier Ltd.. All rights reserved.)

Pharmaceuticals have been detected at high concentrations in landfill leachate and refuse, which may pose potential long-term environmental impacts. The interaction of pharmaceuticals between leachate and refuse contributes to their retention through in situ sorption, thereby mitigating this impact. However, limited efforts have been made to describe the distribution characteristics of pharmaceuticals in the refuse-leachate phase. In this study, two refuse and three leachate samples were used to obtain partitioning coefficients (K d ) for two typical pharmaceuticals, carbamazepine (CBZ) and sulfadiazine (SD), with campus soil as a comparison. Landfill refuse exhibited higher K d values (12.36 ± 0.90 and 19.76 ± 1.96 mL/g for CBZ and 1.90 ± 0.34 and 6.27 ± 0.58 mL/g for SD in two samples, respectively) than campus soil (3.73 ± 1.31 mL/g for CBZ and 0.81 ± 0.26 mL/g for SD), influenced by refuse properties such as higher organic matter (OM) content and specific surface area (SSA). The influence of leachate pH on K d values depended on the electrostatic interaction between the species of target pollutants and negatively charged refuse. The effect of humic acid (HA) was related to its binding with target pollutants in solution and its competition with them for sorption sites. Electrostatic repulsion, hydrogen bonding and π-π interaction were the proposed mechanisms in SD sorption on refuse, while hydrogen bonding participated in the sorption of CBZ. The results will help aid the understanding of the distribution of pharmaceuticals in the refuse-leachate system and improve corresponding management strategies., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

With the rapid advancement of photopolymerization-based 3D printing technology, the volume of PCW has experienced a sharp increase. The potential environmental ramifications of PCW disposal demand careful consideration, especially given its current practice of being incineration alongside MSW. In this study, the TG-MS/FTIR system was carried out to probe the thermogravimetric characteristics and volatile byproducts during combustion. Various product compositions resulting from different mixing ratios of PCW incineration with MSW were investigated. It was observed that fluorene (C 13 H 10 ) and triphenylene (C 18 H 12 ) produced by PCW combustion 0.52 mg/g and 0.43 mg/g respectively, which are twice as abundant as those generated from normal plastic. When PCW incineration along with MSW, compounds such as naphthalene (C 10 H 8 ), cyclohexane (C 6 H 12 ), and heptane (C 7 H 16 ) were generated in concentrations of 1.25 mg/g, 1.05 mg/g, and 0.95 mg/g respectively, which are at least twice as much as with MSW incineration alone. The incineration of PCW with rubber and textiles resulted in the production of 2.34 mg/g to 3.76 mg/g more PAHs compared to PCW combustion alone. The incineration of PCW with paper resulted in the production of 3.12 mg/g to 5.15 mg/g more heptane, nonane, cyclohexane, pyrene, and anthracene than PCW combustion alone. Incineration of PCW with wood proved to be the cleanest method, with product contents primarily below 0.10 mg/g. When incinerated with food residues or normal plastic, most of the product content remained below 0.05 mg/g. Considering the environmental pollution resulting from PCW combustion, the disposal of PCW warrants careful consideration and management., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

This study tackles the growing global concern about municipal waste management, particularly in cities like the Grand Guayaquil Metropolitan Area (GGA). Through realistic field studies on in situ household waste generation and geographic information system (GIS) tools, this work offers a framework to predict the quantities and types of recyclable household waste for any metropolitan area in Latin America. Over 4 weeks, students collected, sorted and weighed recyclable waste types, including plastic, paper, metal, glass and fabric, from 776 sampled household of the GGA. ArcGIS survey tool identified household locations and allowed to survey different socio-demographic features. With the help of ArcGIS interpolation method, the total household waste generation for GGA was predicted, and the classification of the different types of recyclable waste was also spatially distributed for the study area. The report identified notable trends in plastic waste, specifically polyethylene terephthalate waste's steady prevalence and 42% growth rate, emphasizing the importance of enhanced recycling techniques. Spatial density maps showed a heterogeneous waste distribution across the GGA, emphasizing locations with higher waste output. This study demonstrates that improving recyclable waste collection can be accomplished with a moderately cheap expenditure by collaborating with academia to overcome knowledge gaps. This strategy provides opportunities to mitigate the environmental impacts of poor waste management., Competing Interests: Declaration of conflicting interestsThe authors declared no potential conflicts of interest with respect to the research, authorship, and/or publication of this article.

The optimization of alternative materials in concrete production continues to garner considerable attention in order to meet sustainability goals and supplement natural materials. Portland limestone cement (PLC) and municipal solid waste incineration (MSWI) bottom ash (BA) have been proposed separately as green cement and coarse aggregate supplement in low-strength concrete production, creating sustainable products and alternative disposal scenario for a waste material. This study discusses the impact of advanced ash processing techniques on aggregates and presents the performance of concrete incorporating both of these products with PLC for the first time. Two sources of MSWI BA were investigated, one as-produced (TMR) and one processed with novel advanced metals recovery (AMR). The AMR process reduced total Al content in ash compared to TMR (20,500 vs 17,000 mg/kg), though not aluminum oxide content, as the AMR process targets metallic aluminum. A composition study on both aggregates supports a reduction in ferrous and non-ferrous metals following the AMR process. All control and test mixes met 28-day compressive strength requirements (17 Mpa). Both AMR and TMR MSWI BA-amended concretes yielded compressive strengths below control specimens (no ash) ranging from 17 to 23 MPa, with little to no difference observed dependent on MSWI BA processing. The life-cycle discussion supports benefits deriving from supplementing naturally mined materials and recovering ferrous and nonferrous metals with the AMR process., Competing Interests: Declaration of competing interest The authors declare the following financial interests/personal relationships which may be considered as potential competing interests: Timothy G. Townsend, Christopher C. Ferraro, Kate D. Weiksnar, Ethan J. Marks, Margaret J. Deaderick, Isabella Mejia-Ruiz report financial support was provided by Solid Waste Authority of Palm Beach County. If there are other authors, they declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 Elsevier Ltd. All rights reserved.)

This mini-review emphasises the role of municipal solid waste (MSW) as the biggest contributor to climate change, as well as the need for more grounded climate action. The UN Framework Convention on Climate Change (UNFCCC) 2023 Synthesis Report by the co-facilitators on the technical dialogue Key Finding 3 of applying the 'whole-of-society' approach in this article is interpreted as a cultural approach in MSW management planning and implementation process. Using anthropological critiques of development, the cultural approach is frequently considered an obstacle or a justification for a project's failure rather than an important aspect of the people being developed. Therefore, the goal of this mini-review is to showcase the findings and explore the practical application of UNFCCC Key Finding 3, emphasising its importance in every phase of the solid waste management process for climate action. This mini-review argues that applying a cultural perspective presents both opportunities and challenges. More importantly, without careful acknowledgement and consideration, opportunities can become challenges, if not vice versa. The discussion section explores the ways in which religious and economic conditions might offer a contextual understanding and effective techniques for managing MSW at the local level. To apply Key Finding 3 in practice, academia needs to move away from generality and embrace multiple 'modernities', while practitioners also need to include cultural perspectives to complement scientific knowledge., Competing Interests: Declaration of conflicting interestsThe author declared no potential conflicts of interest with respect to the research, authorship, and/or publication of this article.

Desiccation-induced cracks in a compacted clay liner significantly deteriorate the hydraulic barrier performance of landfill covers. The present study explores the effects of polypropylene (PP) fiber reinforcement on the hydrological response and crack resistance of compacted steel slag (SS; 90 wt%) - bentonite (10 wt%) mixtures under drying and wetting cycles. Comprehensive tests were conducted to explore the impact of different fiber lengths (6-12 mm) and contents (0-0.4 % wt.%), including hydraulic conductivity tests for measuring the saturated hydraulic conductivity (k s ), unconfined-penetration tests for measuring the tensile strength, small-sized plate tests for quantifying crack development, and large-sized bucket tests for studying the hydrological response and crack characteristics. Higher fiber contents and longer fiber lengths increased the k s -value of the specimens. For a 0.3 % fiber content, the tensile strength peaked for the 9-mm fiber. Consistently, the specimen reinforced with the 9-mm fibers exhibited significantly fewer cracks than those reinforced with the 6-mm and 12-mm fibers. It was because the 6-mm fibers had a shorter anchorage length, while the 12-mm fibers tended to agglomerate. The large-sized bucket tests showed that fiber reinforcement limited crack development significantly under wetting and drying cycles, reducing the rainfall infiltration by 40 % and enhancing the soil water retention capacity. Finally, a 0.3 wt% of 9-mm PP was recommended to reinforce the compacted SS-bentonite mixtures., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024. Published by Elsevier Ltd.)

The increasing use of synthetic biodegradable polymers, such as aliphatic polyesters, has led to a greater need to understand their behavior in an end-of-life scenario as food packaging materials. The aim of this work was to investigate the effect on composting of high to 10 wt% concentration of commercial polylactide packaging in food waste during a 98-day pilot-scale test. Members of the genera Bacillus, Geobacillus, Caldibacillus, Compostibacillus, Novibacillus, Planifilum and Aeribacillus accounted for 77 % of the bacterial community at the initial stage. Significant fragmentation of the polylactide packaging was observed after 14 days, and the appearance of low-molecular weight (approximately 5.4 kDa) hydrolytic degradation products led to an increase in biodiversity and a prolongation of the thermophilic stage by 12 days. The results obtained show the possibility of efficient disposal of food waste with high concentration of polylactide packaging under industrial composting conditions., Competing Interests: Declaration of competing interest The authors declare the following financial interests/personal relationships which may be considered as potential competing interests: Vladimir Mironov reports financial support was provided by Russian Science Foundation. Vladimir Mironov reports a relationship with Russian Science Foundation that includes: funding grants. If there are other authors, they declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024. Published by Elsevier Ltd.)

Anaerobic digestion (AD) has the potential to catalyse the shift from a linear to a circular economy. However, effective treatment and management of both solid (DSF) and liquid (DLF) digestate fraction treatment and management require adopting sustainable technologies to recover valuable by-products like energy, biofuels, biochar, and nutrients. This study reviews state-of-the-art advanced technologies for DSF and DLF treatment and valorisation, using life cycle assessment (LCA) and techno-economic analysis (TEA) in integrated digestate management (IDM). Key findings highlight these technologies' potential in mitigating environmental impacts from digestate management, but there's a need to improve process efficiency, especially at larger scales. Future research should prioritize cost-effective and eco-friendly IDM technologies. This review emphasizes how LCA and TEA can guide decision-making and promote sustainable agricultural practices. Ultimately, sustainable IDM technologies can boost resource recovery and advance circular economy principles, enhancing the environmental and economic sustainability of AD processes., Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper., (Copyright © 2024 The Author(s). Published by Elsevier Ltd.. All rights reserved.)

The Pew Charitable Trust's 2020 report 'Breaking the Plastic Wave', indicates that existing technologies could support an 80% reduction in plastic leakage relative to business as usual by 2040. Therefore, South Africa became the first country to work with the Pew Charitable Trust and Oxford University to test and apply 'Pathways', a modelling framework and software tool which stemmed and evolved from the Pew report, at country level. The tool calculates the flows of plastics in the economy and the impact of various strategies to reduce future plastic pollution. The Scenario Builder within the Pathways tool allows the user to optimise flows in the plastics value chain to satisfy a set of defined objectives in order to achieve an optimal solution. Three major findings have emerged from the application of Pathways at country level for South Africa. Firstly, plastic pollution is set to almost double by 2040 if no interventions are implemented. Secondly, meeting the newly legislated extended producer responsibility (EPR) targets set for plastic packaging can avoid 33% of projected total pollution over the period of 2023-2040. Lastly, an optimal system change can avoid 63% of total plastic pollution over the period 2023-2040. Thus, applying Pathways at country level in South Africa has proven to be valuable by setting a baseline against which progress towards reducing plastic pollution can be measured; determining the outcome of meeting the legislated EPR targets over time, and informing policy decisions by allowing users to model different scenarios towards an optimal system change scenario., Competing Interests: Declaration of conflicting interestsThe authors declared no potential conflicts of interest with respect to the research, authorship, and/or publication of this article.