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The conversion of coal to a hydrophilic state presents a significant challenge for process engineers, especially when treating oxidized coals in flotation-based beneficiation plants. Flotation of oxidized coal often requires a substantial consumption of oily collectors, resulting in unacceptably low yields. To address this, several pre-processing methods have emerged for coal deoxidation, including mild grinding, surface activation, and ultrasonic or microwave treatment. However, their effective application depends on a thorough understanding of the degree of oxidation in the coals. Therefore, it is crucial to gain insights into the nature of oxidized coal before initiating the deoxidation process. This present study provides various characterization techniques such as XRD, SEM-EDS, FTIR Spectroscopy, Raman Spectroscopy, TGA, and Zeta Potential Analysis employed on oxidized low-grade coals. The study revealed that the proximate analysis of low-grade coals KC, DC, RC, and PC contains varying ash percentages of 32.65%, 44.47%, 25.44%, and 37.53%, respectively, with SiO2 and Al2O3 comprising over 80% of the total ash. XRD characterizations identified quartz and kaolinite as major mineral phases in all samples, while SEM-EDS confirmed rough coal surfaces with peeling, off-white aggregations, and surface pores. HGI value ranging from 80 to 91 was attributed to partial decomposition and surface cracking due to oxidation. FTIR spectra revealed pronounced oxidation behavior, with strong −OH peaks in the 3600–3700 cm−1 range. Zeta potential analysis affirmed the oxidized nature of the coals with a pH below 3.1 and an extremely negative zeta potential beyond 3.1. The findings mentioned above showcase the distinct characteristics of oxidized low-grade coals, which serve as crucial indicators for exploring coal beneficiation, especially through the flotation process. [ABSTRACT FROM AUTHOR]

Understanding past glaciation and deglaciation is vital for assessing present-day glacier dynamics and response to climate change. We focus on reconstructing past glacier fluctuations in Lahaul, north-west India, a region located between arid Ladakh and the humid the Pir-Panjal range. We focus specifically on six glaciers in the Miyar and Thirot catchments of varying size, aspect and debris cover. To reconstruct past terminus fluctuations of these glaciers, we used repeat terrestrial photography and historical archives as data sets and mapped the terminus positions and latero-terminal moraines in the field along with glacier terminus mapping from high to medium resolution satellite images (e.g. Corona, Hexagon, Landsat and LISS IV). Results show that since the little ice age, all the studied glaciers have experienced terminus retreat and area loss, with average values of 1.46 and 0.9 km2, respectively. Precipitation data show a statistically significant decreasing trend during the last century with an increasing trend in annual average maximum (Tmax) and minimum (Tmin) temperature. This warming trend is more statistically significant for Tmin. Although total ice loss at the six studied glaciers is considerable (5.48 km2), this varies both spatially (i.e. from glacier to glacier) and temporally. We attribute this variability to topographic controls such as glacier hypsometry and another non-climatic factor, i.e. varying degree of debris cover. [ABSTRACT FROM AUTHOR]