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In order to reduce greenhouse gas emissions associated with power generation, the replacement of fossil fuels with renewables must be accompanied by the availability of dispatchable sources needed to balance electricity demand and production. Combined cycle (CC) power plants adopting post-combustion capture (PCC) can serve this purpose, ensuring near-zero CO2 emissions at the stack, as well as high efficiency and load flexibility. In particular, the chemical absorption process is the most established approach for industrial-scale applications, although widespread implementation is lacking. In this study, different natural gas combined cycle (NGCC) configurations were modeled to estimate the burden of retrofitting the capture process to existing power plants on thermodynamic performance. Simulations under steady-state conditions covered the widest possible load range, depending on the gas turbine (GT) model. Attention was paid to the net power loss and net efficiency penalty attributable to PCC. The former can be mitigated by lowering the GT air–fuel ratio to increase the CO2 concentration (XCO2) in the exhaust, thus decreasing the regeneration energy. The latter is reduced when the topping cycle is more efficient than the bottoming cycle for a given GT load. This is likely to be the case in the less-complex heat recovery units.

In this study, thermodynamic modeling and simulations were used to optimize the design point performance of the Allam cycle. The topic fits perfectly with the strategies for power sector decarbonization toward net zero emission. In fact, it offers an environmentally friendlier alternative to natural gas combined cycle (NGCC) plants. The focus is on oxyfuel combustion that, combined with supercritical CO2 (sCO2) stream as working fluid, produces high-purity CO2, electricity, and water by means of a highly recuperated Brayton cycle. The former is ready for sequestration, pipeline injection, or other applications, such as enhanced oil recovery or industrial processes. Being designed within the last decade, large-scale plants are poorly documented in the published literature and not yet ready for operation. Accordingly, a thermodynamic model was developed for a net power (Pn) output of 300 MW. After validation against the little data available from academic studies, simulation sets were conceived to assess the impact of main process parameters on cycle efficiency. To that end, operating conditions of the compressor, turbine, and air separation unit (ASU) were varied in a parametric analysis, preparatory to performance optimization. For the chosen layout, the maximum net electric efficiency (ηel,n) was found to be 50.4%, without thermal recovery from ASU.

District energy is undergoing a deep transformation towards higher efficiency and greater flexibility through the promotion of renewable energy and waste energy sources [...]

Micro gas turbines fit perfectly with the energy roadmap to 2050: on-site, small scale power generation, combined with heat recovery from exhaust gas, offers an opportunity to deploy primary energy saving and pollutant emission reduction. Moreover, their flexibility enables fuel switching from natural gas (NG) to carbon-free fuels such as hydrogen and ammonia. This study aims to explore the potential of direct combustion of ammonia in a micro gas turbine (MGT), from a thermodynamic point of view. A modeling procedure was developed to simulate the behavior of a 100 kW MGT operating at full and part-load. After validation with NG as fuel, an increasing fraction of ammonia was fed to the combustor to predict performance variations in terms of electric, thermal and total efficiency, as well as exhaust gas composition, for a load range between 40% and 100%. Additional relevant details, related to the interaction between compressor and turbine in the single-shaft arrangement, were discussed through performance maps. Full replacement of NG with ammonia was found to reduce electric efficiency by about 0.5 percentage points (pp), whatever the power output, with a consequent improvement in exhaust gas heat recovery. Thus, total efficiency is maintained at a high level, with values ranging from 74.5% to 79.1% over the investigated load range. The benefit of zero CO2 emissions can be achieved provided that compressor–turbine matching is adjusted to compensate for the reduction in fuel calorific value: at rated power, when the largest fuel input is required, flow rates of air and flue gas decrease by 4.3% and 2.8%, respectively, with an increase in Brayton cycle pressure ratio of 2%.